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Chapter 40.5, Problem 40.5TYU
To determine

The system in which photon absorbed by first excited state has longer wavelength than that of photon absorbed in ground state.

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Chemists use infrared absorption spectra to identify chemicals in a sample. In one sample, a chemist finds that light of wavelength 5.8 mm is absorbed when a molecule makes a transition from its ground harmonic oscillator level to its first excited level. (a) Find the energy of this transition. (b) If the molecule can be treated as a harmonic oscillator with mass                       5.6 * 10-26 kg, find the force constant.
Solid metals can be modeled as a set of uncoupled harmonic oscillators of the same frequency with energy levels given by En = ħwn n = 0, 1, 2,... where the zero-point energy (the lowest energy state) of each oscillator has been adjusted to zero for simplicity. In this model, the harmonic oscillators represent the motions of the metal atoms relative to one another. The frequency of these oscillators is low so that ħw = = 224 KB and the system vibrational partition function is given by 3N Z ² = la₁ - (1 1 e-0/T). (a) If the system contains one mole of atoms, find the average energy (in J) of this system at T= 172 K. (You can use = BkB.) T (b) What is the absolute entropy (in J/K) for this system? You can use either the Gibbs expression for S, or the system partition function to make this evaluation (they are equivalent, as your reading assignment indicates).

Chapter 40 Solutions

University Physics with Modern Physics, Books a la Carte Edition; Modified MasteringPhysics with Pearson eText -- ValuePack Access Card -- for ... eText -- Valuepack Access Card (14th Edition)

Ch. 40 - If a panicle is in a stationary state, does that...Ch. 40 - Prob. 40.6DQCh. 40 - Prob. 40.7DQCh. 40 - Prob. 40.8DQCh. 40 - Prob. 40.9DQCh. 40 - Prob. 40.10DQCh. 40 - Prob. 40.11DQCh. 40 - Prob. 40.12DQCh. 40 - Prob. 40.13DQCh. 40 - Prob. 40.14DQCh. 40 - Prob. 40.15DQCh. 40 - Prob. 40.16DQCh. 40 - Prob. 40.17DQCh. 40 - Prob. 40.18DQCh. 40 - Prob. 40.19DQCh. 40 - Prob. 40.20DQCh. 40 - Prob. 40.21DQCh. 40 - Prob. 40.22DQCh. 40 - Prob. 40.23DQCh. 40 - Prob. 40.24DQCh. 40 - Prob. 40.25DQCh. 40 - Prob. 40.26DQCh. 40 - Prob. 40.27DQCh. 40 - Prob. 40.1ECh. 40 - Prob. 40.2ECh. 40 - Prob. 40.3ECh. 40 - Prob. 40.4ECh. 40 - Prob. 40.5ECh. 40 - Prob. 40.6ECh. 40 - Prob. 40.7ECh. 40 - Prob. 40.8ECh. 40 - Prob. 40.9ECh. 40 - Prob. 40.10ECh. 40 - Prob. 40.11ECh. 40 - Prob. 40.12ECh. 40 - Prob. 40.13ECh. 40 - Prob. 40.14ECh. 40 - Prob. 40.15ECh. 40 - Prob. 40.16ECh. 40 - Prob. 40.17ECh. 40 - Prob. 40.18ECh. 40 - Prob. 40.19ECh. 40 - Prob. 40.20ECh. 40 - Prob. 40.21ECh. 40 - Prob. 40.22ECh. 40 - Prob. 40.23ECh. 40 - Prob. 40.24ECh. 40 - Prob. 40.25ECh. 40 - Prob. 40.26ECh. 40 - Prob. 40.27ECh. 40 - Prob. 40.28ECh. 40 - Prob. 40.29ECh. 40 - Prob. 40.30ECh. 40 - Prob. 40.31ECh. 40 - Prob. 40.32ECh. 40 - Prob. 40.33ECh. 40 - Prob. 40.34ECh. 40 - Prob. 40.35ECh. 40 - Prob. 40.36ECh. 40 - Prob. 40.37ECh. 40 - Prob. 40.38ECh. 40 - Prob. 40.39ECh. 40 - Prob. 40.40ECh. 40 - Prob. 40.41ECh. 40 - Prob. 40.42PCh. 40 - Prob. 40.43PCh. 40 - Prob. 40.44PCh. 40 - Prob. 40.45PCh. 40 - Prob. 40.46PCh. 40 - Prob. 40.47PCh. 40 - Prob. 40.48PCh. 40 - Prob. 40.49PCh. 40 - Prob. 40.50PCh. 40 - Prob. 40.51PCh. 40 - Prob. 40.52PCh. 40 - Prob. 40.53PCh. 40 - Prob. 40.54PCh. 40 - Prob. 40.55PCh. 40 - Prob. 40.56PCh. 40 - Prob. 40.57PCh. 40 - Prob. 40.58PCh. 40 - Prob. 40.59PCh. 40 - Prob. 40.60PCh. 40 - Prob. 40.61PCh. 40 - Prob. 40.62PCh. 40 - Prob. 40.63PCh. 40 - Prob. 40.64CPCh. 40 - Prob. 40.65CPCh. 40 - Prob. 40.66CPCh. 40 - Prob. 40.67PPCh. 40 - Prob. 40.68PPCh. 40 - Prob. 40.69PPCh. 40 - Prob. 40.70PP
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