EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 8220100547508
Author: CRACOLICE
Publisher: Cengage Learning US
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Chapter 4, Problem 9E
Interpretation Introduction

Interpretation: The expansion of balloons in all the directions when blown up, unlike the balloon filled with water, which expands just at the bottom, is to be interpreted in terms of kinetic molecular theory of gases.

Concept introduction:

The pressure is defined as the force per unit area.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³
fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Chapter 4 Solutions

EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L

Ch. 4 - Prob. 11ECh. 4 - The density of liquid oxygen is about 1.4 g/cm3....Ch. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Many common liquids have boiling points that are...Ch. 4 - Hydrogen cyanide is the deadly gas used in some...Ch. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - Prob. 33ECh. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - A sample of carbon dioxide gas at a pressure of...Ch. 4 - Prob. 39ECh. 4 - A sample of krypton gas at a pressure of 905 torr...Ch. 4 - Prob. 41ECh. 4 - A sample of krypton gas occupies a volume of 6.68...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - If 1 cubic foot-28.3 L-of air at common room...Ch. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - A container with a volume of 56.2 L holds helium...Ch. 4 - At STP, a sample of neon fills a 4.47-L container....Ch. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Prob. 61ECh. 4 - Air in a steel cylinder is heated from 19 0C to 42...Ch. 4 - A gas storage tank is designed to hold a fixed...Ch. 4 - Prob. 64ECh. 4 - If 1.62 m3 of air at 120C and 738 torr is...Ch. 4 - Prob. 66ECh. 4 - The compression ratio in an automobile engine is...Ch. 4 - Target check For each of the macroscopic...Ch. 4 - Prob. 4.2TCCh. 4 - Prob. 4.3TCCh. 4 - Prob. 4.4TCCh. 4 - Prob. 1CLECh. 4 - Prob. 2CLECh. 4 - Prob. 3CLECh. 4 - Prob. 4CLECh. 4 - Prob. 5CLECh. 4 - Prob. 1PECh. 4 - Prob. 2PECh. 4 - Prob. 3PECh. 4 - Prob. 4PECh. 4 - Prob. 5PECh. 4 - Prob. 6PE
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