CHEMISTRY:STRUCTURE+PROP.-W/MOD.ACCESS
2nd Edition
ISBN: 9780134783093
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 4, Problem 9E
How can you use Lewis structures to determine the formula of ionic compounds? Give an example.
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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment?
a) the heat capacity of the calorimeter
b) Mass of sample
c) Ti
d) The molarity of the HCl
e) Tf
Predict products for the Following organic rxn/s by
writing the structurels of the correct products. Write
above the line provided"
your answer
D2
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Spark
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4 CH 3 11
3 CH 3 (CH2) 4 C-H + CH3OH
CH2 CH3 + CH3 CH2OH
0
CH3
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KMnDy→
C43
+ 2 KMn Dy→→
C-OH
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C-OH
1110
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=C
CH3
+ HNO 3
0
+ Heat>
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CH2CH3
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2
+ D Heat H
3
CH 3 CH₂ CH₂ C = CH + 2 H₂ →
2
2
Chapter 4 Solutions
CHEMISTRY:STRUCTURE+PROP.-W/MOD.ACCESS
Ch. 4 - How do the properties of compounds compare to the...Ch. 4 - What is a chemical bond? Why do chemical bonds...Ch. 4 - Explain the difference between an ionic bond and a...Ch. 4 - List and describe the different ways to represent...Ch. 4 - What is the difference between an empirical...Ch. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - How can you use Lewis structures to determine the...Ch. 4 - What is lattice energy?
Ch. 4 - Why is the formation of solid sodium chloride from...Ch. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - How does the Lewis model for covalent bonding...Ch. 4 - Explain howto nans molecular inorganic compounds.Ch. 4 - Prob. 20ECh. 4 - What is the formula mass for a compound? Why is it...Ch. 4 - Explain how the information in a chemical formula...Ch. 4 - What is mass percent composition? Why is it...Ch. 4 - Which kinds of conversion factors are inherent in...Ch. 4 - Which kind of chemical formula can be obtained...Ch. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Determine the empirical formula for the compound...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Write a chemical formula for each molecular model....Ch. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Write an electron configuration for Ne. Then write...Ch. 4 - Prob. 39ECh. 4 - Write a Lewis symbol for each atom or ion. a. S2-...Ch. 4 - Prob. 41ECh. 4 - Write the Lewis symbols that represent the ions in...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - The lattice energy of CsF is -744 kJ/mol, whereas...Ch. 4 - Rubidium iodide has a lattice energy of-617...Ch. 4 - Prob. 47ECh. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Prob. 53ECh. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Use covalent Lewis structures to explain why each...Ch. 4 - Use covalent Lewis structures to explain why the...Ch. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Name each compound. (Refer to the nomenclature...Ch. 4 - Prob. 68ECh. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Calculate the formula mass for each compound. NO2...Ch. 4 - Prob. 72ECh. 4 - Calculate the number of moles in each sample 72.5...Ch. 4 - Calculate the mass of each sample 15.7 mol HNO3...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - How many molecules are in each sample? 6.5 g H2O...Ch. 4 - Prob. 78ECh. 4 - Calculate the mass (in g) of each sample. 5.94 x...Ch. 4 - Calculate the mass (in g) of each sample 4.5 x...Ch. 4 - A sugar crystal contains approximately 1.8 x 1017...Ch. 4 - A salt crystal has a mass of 0.12 mg. How many...Ch. 4 - Calculate the mass percent composition of carbon...Ch. 4 - Calculate the mass percent composition of nitrogen...Ch. 4 - Most fertilizers consist of nitrogen-containing...Ch. 4 - Iron in the earth is in the form of iron ore....Ch. 4 - Copper(ll) fluoride contains 37.42% F by mass....Ch. 4 - Silver chloride, often used in silver plating,...Ch. 4 - The iodide ion is a dietary mineral essential to...Ch. 4 - The American Dental Association recommends that an...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Determine the number of moles of hydrogen atoms in...Ch. 4 - Determine the number of moles of oxygen atoms in...Ch. 4 - Calculate mass (in grams) of sodium in 8.5 g of...Ch. 4 - Calculate the mass (in kilograms) of chlorine in...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - Calculate the empirical formula for each stimulant...Ch. 4 - Calculate the empirical formula for each natural...Ch. 4 - The elemental mass percent composition of...Ch. 4 - The elemental mass percent composition of ascorbic...Ch. 4 - A 0.77-mg sample of nitrogen reacts with chlorine...Ch. 4 - A 45.2-mg sample of phosphorus reacts with...Ch. 4 - The empirical formula and molar mass of several...Ch. 4 - The malar mass and empirical formula of several...Ch. 4 - Combustion analysis of a hydrocarbon produced...Ch. 4 - Combustion analysis of naphthalene, a hydrocarbon...Ch. 4 - The foul odor of rancid butter is due largely to...Ch. 4 - Tartaric acid is the white, powdery substance that...Ch. 4 - Prob. 111ECh. 4 - Prob. 112ECh. 4 - Prob. 113ECh. 4 - Prob. 114ECh. 4 - How many molecules of ethanol (C2H5OH) (the...Ch. 4 - A drop of water has a volume of approximately 0.05...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - A Freon™ leak in the air conditioning system of an...Ch. 4 - Prob. 120ECh. 4 - A metal (M) forms a compound with the formula...Ch. 4 - A metal (M) forms an oxide with the formula M2O....Ch. 4 - Estradiol is a female sexual hormone that causes...Ch. 4 - Fructose is a common sugar found in fruit....Ch. 4 - Combustion analysis of a 13.42-g sample of equilin...Ch. 4 - Prob. 126ECh. 4 - Epsom salts is a hydrated ionic compound with the...Ch. 4 - A hydrate of copper(ll) chloride has the following...Ch. 4 - A compound of molar mass 177 g/mol contains only...Ch. 4 - Researchers obtain the following data from...Ch. 4 - Find the total number of atoms in a sample of...Ch. 4 - Vanadium forms four different oxides in which the...Ch. 4 - The chloride of an unknown metal is believed to...Ch. 4 - Prob. 134ECh. 4 - A chromium-containing compound has the formula...Ch. 4 - Prob. 136ECh. 4 - Prob. 137ECh. 4 - Prob. 138ECh. 4 - A mixture of NaCI and NaBr has a mass of 2.00 g...Ch. 4 - Three pure compounds form when 1.00-g samples of...Ch. 4 - A mixture of CaCO3 and (NH4)2CO3is 61.9% CO3 by...Ch. 4 - A mixture of 50.0 g of S and 1.00 x 102 g of CI2...Ch. 4 - Because of increasing evidence of damage to the...Ch. 4 - A particular coal contains 2.55% sulfur by mass....Ch. 4 - Lead is found in Earth’s crust as several...Ch. 4 - A 2.52-g sample of a compound containing only...Ch. 4 - Prob. 147ECh. 4 - The elements X and Y form a compound that is 40% X...Ch. 4 - A compound of X and Y is 13 X by mass. The atomic...Ch. 4 - A mixture of carbon and sulfur has a mass of 9.0...Ch. 4 - When molecules are represented by molecular...Ch. 4 - Prob. 152ECh. 4 - Explain the problem with this statement and...Ch. 4 - Without doing any calculations, arrange the...Ch. 4 - Prob. 155ECh. 4 - Prob. 156ECh. 4 - Prob. 157ECh. 4 - A compound isolated from the rind of lemons is...Ch. 4 - Prob. 159ECh. 4 - What is the empirical formula of the compound with...Ch. 4 - Which substance is an ionic compound? He N2O4 CCl4...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - What is the correct Lewis symbol for S?Ch. 4 - How many CH2Cl2 molecules are there in 25.0 g of...Ch. 4 - List the elements in the compound CF2Cl2 in order...Ch. 4 - Determine the mass of potassium in 35.5 g of KBr....Ch. 4 - A compound is 52.14% C, 13.13% H, and 34.73% O by...Ch. 4 - A compound has the empirical formula CH2O and a...Ch. 4 - Combustion of 30.42 g of a compound containing...
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- When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.arrow_forwardQ6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of the two bases shown (on the -NH2). Include curved arrows to show the mechanism. O₂N- O₂N. -NH2 -NH2 a) Which of the two Bronsted bases above is the stronger base? Why? b) Identify the conjugate acids and conjugate bases for the reactants. c) Identify the Lewis acids and bases in the reactions.arrow_forwardQ5: For the two reactions below: a) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. b) Label Bronsted acids and bases in the left side of the reactions. c) For reaction A, which anionic species is the weakest base? Which neutral compound is the stronger acid? Is the forward or reverse reaction favored? d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the reactions. A. 용 CH3OH я хон CH3O OH B. HBr CH3ONa NaBr CH3OHarrow_forward
- potential energy Br b) Translate the Newman projection below to its wedge-and-dash drawing. F H. OH CH3 CI c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw a Newman projection of six conformations about the C2-C3 bond of isopentane. On the curve of potential energy versus angle of internal rotation for isopentane, label each energy maximum and minimum with one of the conformations. 0° 。 F A B D C angle of internal rotation E F 360° (=0°) JDownlarrow_forwardQ7: Identify the functional groups in these molecules a) CH 3 b) Aspirin: HO 'N' Capsaicin HO O CH3 CH 3arrow_forwardQ2: Name the following alkanesarrow_forward
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- Q5: Conformations of Alkanes a) Draw a Newman Projection of the compound below about the C2-C3 bond. H3C Cli... H IIIH Br CH3arrow_forwardThe ability of atoms to associate with each other depends ona) the electronic structure and its spatial orientation.b) the electron affinity.c) The other two answers are correct.arrow_forwardWhat is the final volume after you reach the final temperature? I put 1.73 but the answer is wrong not sure why The initial volume of gas is 1.60 LL , the initial temperature of the gas is 23.0 °C°C , and the system is in equilibrium with an external pressure of 1.2 bar (given by the sum of a 1 bar atmospheric pressure and a 0.2 bar pressure due to a brick that rests on top of the piston). Then, as you did in Exercise 1, you heat the gas slowly until the temperature reaches 48.2 °Carrow_forward
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