
Laboratory Experiments for Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134566207
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, John H. Nelson, Kenneth C. Kemp
Publisher: PEARSON
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Question
Chapter 4, Problem 80E
Step 1:
Interpretation Introduction
To determine: The number of moles of
Step 2:
Interpretation Introduction
To determine: The mass of
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Consider the Grignard reaction below to answer the following questions.
A
Mgar
1. ether
+
MyC
CH3
2H3O
C
B
a. The electrophile in this reaction is:
b. The nucleophile in this reaction is:
c. The alcohol product can be classified as a:
a.
1° alcohol
b. 2° alcohol
C.
3° alcohol
d. 4° alcohol
HO
CH3
CH
Give the major organic product(s) for each of the following reactions or sequences of reactions. Show
all relevant stereochemistry
A.
CH₂OH
PCC
CH2Cl2
HOO
B.
H
KCN
HCN
of b
C.
1. CH,MgBr, ether
2 HO*
D. Choose the BEST reagent for carrying out each of the following conversions.
CO₂CH3
CO₂CH3
OH
CO₂H
сон
ن نے
a.
LiAlH4, ether at abinayo iss c
b. NaBH4, ethanol
C.
CrO3, pyridine
d. H₂/Pd d
notsiol
Choose the best reagent for carrying out the following reactions from the list below. Place the letter of
the reagent(s) in the box over the reaction arrow. Use only one letter per box.
OH
OH
CH
CH
CH3
CHS
CH3
f
OH
OCH 3
H
A.
NaH, then CHI
B.
C.
m-ClC6H4COзH
D.
E.
warm H2SO4/H₂O
F.
G.
H₂/Pd
H.
I.
Cl₂, H₂O
J.
NaOCH3, CH3OH
CH3MgBr in ether, then H3O+
Hg(O2CCF3)2, CH3OH
PCC, CH2Cl2
LiAlH4 in ether, then H3O+
Chapter 4 Solutions
Laboratory Experiments for Chemistry: The Central Science (14th Edition)
Ch. 4.1 - If you have an aqueous solution that contains 1.5...Ch. 4.1 - If you were to draw diagrams representing aqueous...Ch. 4.2 - Prob. 4.2.1PECh. 4.2 - Classify the following compounds as soluble or...Ch. 4.2 - Yes or No: Will a precipitate form when solutions...Ch. 4.2 - a. What compound precipitates when aqueous...Ch. 4.2 - What happens when you mix an aqueous solution of...Ch. 4.2 -
Write the net ionic equation for the...Ch. 4.3 - Prob. 4.5.1PECh. 4.3 -
Imagine a diagram showing 10 Na + ions and 10 OH-...
Ch. 4.3 -
Which of these substances, when dissolved in...Ch. 4.3 - Consider solutions in which 0.1 mol of each of the...Ch. 4.3 -
Which is the correct ionic equation for the...Ch. 4.3 - For the reaction of phosphorous acid (H3PO3) and...Ch. 4.4 - Prob. 4.8.1PECh. 4.4 - What is the oxidation state of the boldfaced...Ch. 4.4 - Which of the following statements is true about...Ch. 4.4 - Prob. 4.9.2PECh. 4.4 - Which of these metals is the easiest to oxidize?...Ch. 4.4 - Which of the following metals will be oxidized by...Ch. 4.5 - Prob. 4.11.1PECh. 4.5 - Calculate the molarity of a solution made by...Ch. 4.5 - Prob. 4.12.1PECh. 4.5 - What is the molar concentration of K+ions in a...Ch. 4.5 - Prob. 4.13.1PECh. 4.5 -
How many grams of Na2SO4 are there in 15 mL of...Ch. 4.5 - Prob. 4.14.1PECh. 4.5 - What volume of 2.50 M lead(II) nitrate solution...Ch. 4.6 - How many milligrams of sodium sulfide are needed...Ch. 4.6 -
How many grams of NaOH are needed to neutralize...Ch. 4.6 - Prob. 4.16.1PECh. 4.6 - Prob. 4.16.2PECh. 4.6 - Practice Exercise 1 A mysterious white powder is...Ch. 4.6 - Prob. 4.17.2PECh. 4 - Prob. 1DECh. 4 - Prob. 1ECh. 4 - Aqueous solutions of three different substances,...Ch. 4 -
4 3 Use the molecular representations shown here...Ch. 4 - The concept of chemical equilibrium is very...Ch. 4 -
4 5 You are presented with a white solid and told...Ch. 4 - Which of the following ions will always be a...Ch. 4 - The labels have fallen off three bottles...Ch. 4 - Explain how a redox reaction involves electrons in...Ch. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 -
4.11 Which data set, of the two graphed here,...Ch. 4 - You are titrating an acidic solution with a basic...Ch. 4 - State whether each of the following statements is...Ch. 4 - State whether each of the following statements is...Ch. 4 -
4.15 We have learned in this chapter that many...Ch. 4 - Prob. 16ECh. 4 -
4.17 Specify what ions are present in solution...Ch. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Acetone. CH3COCH3, is a nonelectrolyte;...Ch. 4 -
4.21 Using solubility guidelines, predict whether...Ch. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Which ions remain in solution, unreacted, after...Ch. 4 - Write balanced net ionic equations for the...Ch. 4 -
4.27 Separate samples of a solution of an unknown...Ch. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - State whether each of the following statements is...Ch. 4 - State whether each of the following statements is...Ch. 4 -
4.35 Label each of the following substances as an...Ch. 4 - An aqueous solution of an unknown solute is tested...Ch. 4 - Prob. 37ECh. 4 - Classify each of the following aqueous solutions...Ch. 4 - Complete and balance the following molecular...Ch. 4 - Write the balanced molecular and net ionic...Ch. 4 - Write balanced molecular and net ionic equations...Ch. 4 -
4.42 Because the oxide ion is basic, metal oxides...Ch. 4 -
4.43 Magnesium carbonate, magnesium oxide, and...Ch. 4 -
4.44 As K20 dissolves in water, the oxide ion...Ch. 4 - True or false: If a substance is oxidized, it is...Ch. 4 - Prob. 46ECh. 4 - Which region of the periodic table shown here...Ch. 4 - Determine the oxidation number of sulfur in each...Ch. 4 - Determine the oxidation number for the indicated...Ch. 4 - Determine the oxidation number for the indicated...Ch. 4 - Which element is oxidized, and which is reduced in...Ch. 4 - Which of the following are redox reactions? For...Ch. 4 -
4.53 Write balanced molecular and net ionic...Ch. 4 - Write balanced molecular and net ionic equations...Ch. 4 - Using the activity series (Table 4.5), write...Ch. 4 - Using the activity series (Table 4.5), write...Ch. 4 - The metal cadmium tends to form Cd2+ ions. The...Ch. 4 -
4.58 The following reactions (note that the...Ch. 4 - Is the concentration of a solution an intensive or...Ch. 4 - Prob. 60ECh. 4 - Calculate the molarity of a solution that contains...Ch. 4 -
4.62
Calculate the molarity of a solution made by...Ch. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 -
4.66 The average adult male has a total blood...Ch. 4 -
4.67
How many grams of ethanol, CH2CH2OH should...Ch. 4 - Prob. 68ECh. 4 - Which will have the highest concentration of...Ch. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - Prob. 78ECh. 4 - Prob. 79ECh. 4 - Prob. 80ECh. 4 - Prob. 81ECh. 4 - Prob. 82ECh. 4 - Some sulfuric acid is spilled on a lab bench You...Ch. 4 -
4.84 The distinctive odor of vinegar is due to...Ch. 4 - A 4.36-g sample of an unknown alkali metal...Ch. 4 -
4.86 An 8.65-g sample of an unknown group 2A...Ch. 4 - A solution of 100.0 mL of 0.200 M KOH is mixed...Ch. 4 -
4.88 A solution is made by mixing 15.0 g of...Ch. 4 - Prob. 89ECh. 4 - A 1.248-9 sample of limestone rock is pulverized...Ch. 4 - 4.91 Uranium hexafluoride, UF6, is processed to...Ch. 4 - The accompanying photo shows the reaction between...Ch. 4 - Prob. 93AECh. 4 -
4.94 You choose to investigate some of the...Ch. 4 -
4 95 Antacids are often used to relieve pain and...Ch. 4 -
4 96 The commercial production of nitric acid...Ch. 4 - Consider the following reagents: zinc, copper,...Ch. 4 - 98 Bronze is a solid solution of Cu(s) and Sn(s);...Ch. 4 - Prob. 99AECh. 4 - Prob. 100AECh. 4 -
4.101 Hard water contains Ca2+ , Mg2 + , and Fe2+...Ch. 4 - Tartaric acid. H2C4H4O6, has two acidic hydrogens....Ch. 4 - Prob. 103AECh. 4 - A solid sample of Zn(OH)2 is added to 0.350 L of...Ch. 4 - Prob. 105IECh. 4 - Prob. 106IECh. 4 - Prob. 107IECh. 4 - A fertilizer railroad car carrying 34,300 gallons...Ch. 4 - Prob. 109IECh. 4 - Prob. 110IECh. 4 - Prob. 111IECh. 4 - Prob. 112IECh. 4 - Prob. 113IECh. 4 - Prob. 114IECh. 4 -
4.115 Federal regulations set an upper limit of...
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