The authenticity of the given statement, “The larger is the Q , the larger is the Δ G 0 ”. Solution: The given statement is false. Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false. Conclusion: The given statement is false.

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Answer 1

Question

Chapter 4, Problem 71E

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The larger is the Q , the larger is the ΔG0 ”.

Solution: The given statement is false.

Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false.

Conclusion:

The given statement is false.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

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Answer 2

Question

Chapter 4, Problem 71E

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The larger is the Q , the larger is the ΔG0 ”.

Solution: The given statement is false.

Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false.

Conclusion:

The given statement is false.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

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Answer 3

Question

Chapter 4, Problem 71E

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The larger is the Q , the larger is the ΔG0 ”.

Solution: The given statement is false.

Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false.

Conclusion:

The given statement is false.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

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Answer 4

Question

Chapter 4, Problem 71E

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The larger is the Q , the larger is the ΔG0 ”.

Solution: The given statement is false.

Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false.

Conclusion:

The given statement is false.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

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Answer 5

Chapter 4, Problem 71E

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The larger is the Q , the larger is the ΔG0 ”.

Solution: The given statement is false.

Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false.

Conclusion:

The given statement is false.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

Answer 6

Chapter 4, Problem 71E

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The larger is the Q , the larger is the ΔG0 ”.

Solution: The given statement is false.

Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false.

Conclusion:

The given statement is false.

Answer 7

Chapter 4, Problem 71E

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The larger is the Q , the larger is the ΔG0 ”.

Solution: The given statement is false.

Explanation: The standard free energy change for a reaction is constant at all the values of Q . Therefore, the change in the value of Q does not affect the value of standard free energy change. Thus, the given statement is false.

Conclusion:

The given statement is false.

Answer 8

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

Answer 9

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

Answer 10

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

Answer 11

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

Answer 12

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

Answer 13

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

Answer 14

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

Answer 15

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

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To determine: The authenticity of the given statement, “If Q=0 , the system is at equilibrium”.

To determine: The authenticity of the given statement, “If a reaction is spontaneous under standard conditions, it is spontaneous under all conditions”.

To determine: The authenticity of the given statement, “The free energy change for a reaction is independent of temperature”.

To determine: The authenticity of the given statement, “If Q>1 , ΔG>ΔG0 ”.

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Chapter 4 Solutions