Introduction to Chemistry
4th Edition
ISBN: 9781259288722
Author: BAUER
Publisher: MCG
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Chapter 4, Problem 60QP
Which compound,
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 4 Solutions
Introduction to Chemistry
Ch. 4 - Prob. 1QCCh. 4 - Prob. 2QCCh. 4 - Prob. 3QCCh. 4 - Prob. 4QCCh. 4 - Prob. 1PPCh. 4 - Prob. 2PPCh. 4 - Prob. 3PPCh. 4 - Prob. 4PPCh. 4 - Prob. 5PPCh. 4 - Prob. 6PP
Ch. 4 - Prob. 7PPCh. 4 - Prob. 8PPCh. 4 - Prob. 9PPCh. 4 - Prob. 10PPCh. 4 - Prob. 11PPCh. 4 - Prob. 12PPCh. 4 - Prob. 13PPCh. 4 - Prob. 14PPCh. 4 - Prob. 15PPCh. 4 - Prob. 16PPCh. 4 - Prob. 17PPCh. 4 - Prob. 18PPCh. 4 - Prob. 19PPCh. 4 - Prob. 20PPCh. 4 - Prob. 21PPCh. 4 - Prob. 22PPCh. 4 - Prob. 23PPCh. 4 - Prob. 1QPCh. 4 - Prob. 2QPCh. 4 - Prob. 3QPCh. 4 - Prob. 4QPCh. 4 - Prob. 5QPCh. 4 - Prob. 6QPCh. 4 - Lithium carbonate, Li2CO3 , contains 18.8 lithium...Ch. 4 - Prob. 8QPCh. 4 - Prob. 9QPCh. 4 - Prob. 10QPCh. 4 - Prob. 11QPCh. 4 - Prob. 12QPCh. 4 - Prob. 13QPCh. 4 - Prob. 14QPCh. 4 - Prob. 15QPCh. 4 - Prob. 16QPCh. 4 - Prob. 17QPCh. 4 - Prob. 18QPCh. 4 - Prob. 19QPCh. 4 - Prob. 20QPCh. 4 - Prob. 21QPCh. 4 - Prob. 22QPCh. 4 - Prob. 23QPCh. 4 - Prob. 24QPCh. 4 - Prob. 25QPCh. 4 - Prob. 26QPCh. 4 - Prob. 27QPCh. 4 - Calculate the molar mass of each of the following...Ch. 4 - Prob. 29QPCh. 4 - Prob. 30QPCh. 4 - Prob. 31QPCh. 4 - Prob. 32QPCh. 4 - Prob. 33QPCh. 4 - Prob. 34QPCh. 4 - Prob. 35QPCh. 4 - Prob. 36QPCh. 4 - Prob. 37QPCh. 4 - Prob. 38QPCh. 4 - Prob. 39QPCh. 4 - Prob. 40QPCh. 4 - Prob. 41QPCh. 4 - Prob. 42QPCh. 4 - Prob. 43QPCh. 4 - Calculate the mass of 0.750 mol of the following...Ch. 4 - Prob. 45QPCh. 4 - Prob. 46QPCh. 4 - A sample of ammonia, NH3 , weights 30.0 g....Ch. 4 - Prob. 48QPCh. 4 - Which of these substance has the most atoms per...Ch. 4 - Which of these substances has the atoms per mole?...Ch. 4 - A raindrop weighs 0.050 g. How many molecules of...Ch. 4 - A gain of sand weighs 7.7104g . How many formula...Ch. 4 - How many formula units are in 250.0 g of the...Ch. 4 - How many formula units are in 375.0 g of the...Ch. 4 - How many atoms (or ions) of each element are in...Ch. 4 - How many atoms (or ions) of each element are in...Ch. 4 - What is the mass of 6.41022 molecules of SO2?Ch. 4 - What is the mass of 1.81021 molecules of H2SO4?Ch. 4 - Which compound, NH3,NH4Cl,NO2,orN203, contains the...Ch. 4 - Which compound, NaCl,PC13,CaC12,orHCIO2, contains...Ch. 4 - You have two colorless gases, each made of sulfur...Ch. 4 - Describe some uses for the percent composition of...Ch. 4 - What is the difference between an empirical...Ch. 4 - Why do we normally use an empirical formula...Ch. 4 - Which of the following molecules have an empirical...Ch. 4 - Which of the following substances have an...Ch. 4 - Prob. 67QPCh. 4 - What is the empirical formula of each of the...Ch. 4 - Prob. 69QPCh. 4 - Prob. 70QPCh. 4 - Which of the following compounds of nitrogen and...Ch. 4 - Which of the following compounds of carbon and...Ch. 4 - What are the empirical formulas of the compounds...Ch. 4 - What are the empirical formulas of the compounds...Ch. 4 - Eugenol, a chemical substance with the flavor of...Ch. 4 - One of the compounds in cement has the following...Ch. 4 - The explosive trinitrotoluene (TNT) has the...Ch. 4 - Strychnine (rat poison) has the composition...Ch. 4 - An unknown organic compound was determined to have...Ch. 4 - Prob. 80QPCh. 4 - Prob. 81QPCh. 4 - Prob. 82QPCh. 4 - Prob. 83QPCh. 4 - Prob. 84QPCh. 4 - Prob. 85QPCh. 4 - Prob. 86QPCh. 4 - What is the percent composition of each of the...Ch. 4 - Prob. 88QPCh. 4 - Prob. 89QPCh. 4 - Prob. 90QPCh. 4 - Prob. 91QPCh. 4 - Prob. 92QPCh. 4 - Prob. 93QPCh. 4 - Prob. 94QPCh. 4 - Prob. 95QPCh. 4 - Prob. 96QPCh. 4 - Prob. 97QPCh. 4 - Prob. 98QPCh. 4 - Prob. 99QPCh. 4 - Prob. 100QPCh. 4 - Prob. 101QPCh. 4 - Prob. 102QPCh. 4 - Prob. 103QPCh. 4 - Prob. 104QPCh. 4 - Prob. 105QPCh. 4 - Prob. 106QPCh. 4 - Prob. 107QPCh. 4 - Prob. 108QPCh. 4 - Prob. 109QPCh. 4 - Prob. 110QPCh. 4 - Prob. 111QPCh. 4 - Prob. 112QPCh. 4 - Prob. 113QPCh. 4 - Prob. 114QPCh. 4 - Prob. 115QPCh. 4 - Prob. 116QPCh. 4 - Prob. 117QPCh. 4 - How many molecules are present in 15.43 g of butyl...Ch. 4 - Prob. 119QPCh. 4 - Prob. 120QPCh. 4 - Prob. 121QPCh. 4 - Prob. 122QPCh. 4 - Prob. 123QPCh. 4 - Prob. 124QPCh. 4 - Prob. 125QPCh. 4 - Prob. 126QPCh. 4 - Prob. 127QPCh. 4 - Prob. 128QPCh. 4 - Prob. 129QPCh. 4 - Prob. 130QPCh. 4 - Prob. 131QPCh. 4 - Prob. 132QPCh. 4 - Prob. 133QPCh. 4 - Prob. 134QPCh. 4 - Prob. 135QPCh. 4 - Prob. 136QPCh. 4 - Prob. 137QPCh. 4 - Prob. 138QPCh. 4 - Prob. 139QPCh. 4 - Prob. 140QPCh. 4 - Prob. 141QPCh. 4 - Prob. 142QPCh. 4 - Prob. 143QPCh. 4 - Prob. 144QPCh. 4 - Prob. 145QPCh. 4 - Prob. 146QPCh. 4 - Prob. 147QPCh. 4 - Prob. 148QPCh. 4 - Prob. 149QPCh. 4 - Prob. 150QPCh. 4 - Prob. 151QPCh. 4 - Prob. 152QP
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