
INTRODUCTORY CHEMISTRY-W/MOD.MASTERING.
6th Edition
ISBN: 9780134809922
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 4, Problem 4E
What are the main ideas in the nuclear theory of the atom?
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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a.
CH3
Ph
OEt
هد
Ph
CH3
Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
containing a single 9-
membered ring
the expected product,
containing two fused rings
H3C-I
(H3C)2CuLi
an enolate
b.
H3C
CH3
1.
2. H3O+
H3C
MgBr
H3C
Chapter 4 Solutions
INTRODUCTORY CHEMISTRY-W/MOD.MASTERING.
Ch. 4 - Q1. Which statement is not part of Dalton’s...Ch. 4 - Q2. Which statement best summarizes the nuclear...Ch. 4 - Q3. An ion composed of which of these particles...Ch. 4 - Which element is a maingroup metal with an even...Ch. 4 - Which element is a halo0gen? a. Ne b. O c. Ca d. ICh. 4 - Prob. 6SAQCh. 4 - Q7. Which element is a row 4 noble gas?
a. Ne
b....Ch. 4 - How many element does the predictable (most...Ch. 4 - Q9. How many neutrons does the Fe-56 isotope...Ch. 4 - Q10. Determine the number of protons, neutrons,...
Ch. 4 - Q11. What is the charge of the Cr ion that...Ch. 4 - An element has four naturally occurring isotopes;...Ch. 4 - What did Democritus contribute to our modern...Ch. 4 - 2. What are three man ideas in Dalton’s atomic...Ch. 4 - Describe Rutherfords gold foil experiment and the...Ch. 4 - What are the main ideas in the nuclear theory of...Ch. 4 - List the three subatomic particles and their...Ch. 4 - What is electrical charge?Ch. 4 - Is matter usually charge-neutral? How would be...Ch. 4 - 8. What does the atomic number of an element...Ch. 4 - What is a chemical symbol?Ch. 4 - Prob. 10ECh. 4 - What Dmitri Mendeleevs main contribution to our...Ch. 4 - What is the man idea in the periodic law?Ch. 4 - How is the periodic table organized?Ch. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - What is a family or group of elements?Ch. 4 - Locate each group of elements on the periodic...Ch. 4 - 19. What is an ion?
Ch. 4 - Prob. 20ECh. 4 - 21. Locate each group on the periodic table and...Ch. 4 - 22. What are isotopes?
Ch. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - What notations are commonly used to specify...Ch. 4 - What is the atomic mass of an element?Ch. 4 - 27. Which statement are inconsistent with Dalton’s...Ch. 4 - Which statements are consistent with Daltons...Ch. 4 - Which statements are inconsistent with Rutherfords...Ch. 4 - 30. Which statement are consistent with...Ch. 4 - Prob. 31ECh. 4 - 32. Rutherford’s experiment indicated that matter...Ch. 4 - 33. Which statement about electrons is true?
a....Ch. 4 - 34. Which statement about electrons is false?
a....Ch. 4 - 35. Which statement about protons is true?
a....Ch. 4 - 36. Which statement about protons is false?
a....Ch. 4 - 37. How many electrons would it take to equal the...Ch. 4 - A helium nucleus has two has two neutrons. How...Ch. 4 - What mass of electrons is required to neutralize...Ch. 4 - 40. What mass of protons is required to neutralize...Ch. 4 - Find the atomic number (Z) for each element. a. Fr...Ch. 4 - Prob. 42ECh. 4 - 43. How many protons are in the nucleus of an atom...Ch. 4 - How many protons are in the nucleus of an atom of...Ch. 4 - 45. List the symbol and atomic number of each...Ch. 4 - 46. List the symbol and atomic number of each...Ch. 4 - List the name and the atomic number of each...Ch. 4 - List the name and the atomic number of each...Ch. 4 - Fill in the blanks to complete the table. Element...Ch. 4 - Fill in the blanks to complete the table. Element...Ch. 4 - Classify each element as a metal, nonmetal, or...Ch. 4 - Classify each element as a metal, nonmetal, or...Ch. 4 - Which elements would you expect to lose electrons...Ch. 4 - 54. Which elements would you expect to gain...Ch. 4 - 55. Which elements are main group elements?
a....Ch. 4 - Which elements are not main-group elements? a. AI...Ch. 4 - 57. Which elements are alkaline earth metals?
a....Ch. 4 - Which elements are alkaline earth metal? a....Ch. 4 - 59. Which elements are alkali metals?
a. barium
b....Ch. 4 - Which elements are alkali metals? a. scandium b....Ch. 4 - Classify each element as a halogen, a noble gas,...Ch. 4 - Prob. 62ECh. 4 - 63. To what group number does each element...Ch. 4 - Prob. 64ECh. 4 - Which element do you expect to be most like...Ch. 4 - Which element do you expect to be most like...Ch. 4 - Which pair of elements do you expect to be most...Ch. 4 - Prob. 68ECh. 4 - 69. Which element is a main – group nonmetal?
a....Ch. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Determine the change of each ion. a. oxygen ion...Ch. 4 - 76. Determine the charge of each ion.
a. tungsten...Ch. 4 - Determine the number of protons and electrons in...Ch. 4 - 78. Determine the number of protons and electrons...Ch. 4 - Prob. 79ECh. 4 - Determine whether each statement is true or false....Ch. 4 - Predict the ion formed by each element. a. Rb b. K...Ch. 4 - 82. Predict ion formed by each element.
a. F
b....Ch. 4 - Predict how many electrons each element will most...Ch. 4 - Predict how many electrons each element will most...Ch. 4 - 85. Fill in the blanks to compele the...Ch. 4 - Fill in the blacks to complete the table. Symbol...Ch. 4 - 87. Determine the atomic number and mass number...Ch. 4 - 88. How many neutrons are in an atom each atomic...Ch. 4 - 89. Write isotopic symbols in the form for each...Ch. 4 - Write isotopic symbol in the form X-A (for...Ch. 4 - Write the symbol for each isotope in the form XZA....Ch. 4 - Write the symbol for each isotope in the form XZA....Ch. 4 - 93. Determine the number of protons and neutrons...Ch. 4 - Determine the number of protons and neutrons in...Ch. 4 - Carbon 14, present within living organisms and...Ch. 4 - Plutonium-239 is used in nuclear bombs. Determine...Ch. 4 - Rubidium has two naturally occurring isotopes:...Ch. 4 - 98. Silicon has three naturally occurring...Ch. 4 - Bromine has two naturally occurring isotopes...Ch. 4 - Silver has two naturally occurring isotopes...Ch. 4 - 101. An element has two naturally occurring...Ch. 4 - Copper has two naturally occurring isotopes. Cu-63...Ch. 4 - Electrical charge is sometimes reported in...Ch. 4 - 104. How many excess protons are in a charged...Ch. 4 - 105. The hydrogen atom contains 1 proton 1...Ch. 4 - 106. Carbon-12 contains 6 protons and 6 neutrons....Ch. 4 - Prepare a table like Table 4.2 for the four...Ch. 4 - 108. Determine the number of protons and neutrons...Ch. 4 - Fill in the blanks to complete the table. Symbol Z...Ch. 4 - 110. Fill in the blanks to complete the...Ch. 4 - Europium has two naturally occurring isotopes:...Ch. 4 - Rhenium has two naturally occurring isotopes:...Ch. 4 - Chapter 1 describes the difference between...Ch. 4 - 114. Chapter1 describes the difference between...Ch. 4 - The atomic mass of fluorine is 19. 00 amu, and all...Ch. 4 - 116. The atomic mass of germanium is 72.61 amu. Is...Ch. 4 - Prob. 117ECh. 4 - Gallium has only two naturally occurring isotopes,...Ch. 4 - 119. The figure shown here is a representation of...Ch. 4 - 120. Neutron stars are believed to be composed of...Ch. 4 - 121. Complete the following...Ch. 4 - Prob. 122QGWCh. 4 - Prob. 123QGWCh. 4 - Prob. 124QGWCh. 4 - 125. The graph at the right shows the atomic...
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- Predict the major products of this reaction: excess H+ NaOH ? A Note that the first reactant is used in excess, that is, there is much more of the first reactant than the second. If there won't be any products, just check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privarrow_forward1. For each of the reaction "railroads" below, you are either asked to give the structure(s) of the starting material(s) or product(s), or provide reagents/conditions to accomplish the transformation, as indicated by the boxes. a. NaOMe H+ .CO,H HO₂C MeOH (excess) MeOH H3C Br يع CH3 1. LiAlH4 2. H3O+ 3. PBг3 H3C 1. Et-Li 2. H3O+ -CO₂Me -CO₂Me OH CH3 CH3 ল CH3arrow_forwardPredict the intermediate 1 and final product 2 of this organic reaction: NaOMe ག1, ད།་, - + H You can draw 1 and 2 in any arrangement you like. 2 work up Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center. Explanation Check Click and drag to start drawing a structure. Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Parrow_forward
- What is the total energy cost associated with the compound below adopting the shown conformation? CH3 HH DH CH3arrow_forwardΗΝ, Draw Final Product C cyclohexanone pH 4-5 Edit Enamine H3O+ CH3CH2Br THF, reflux H Edit Iminium Ionarrow_forwardHow many hydrogen atoms are connected to the indicated carbon atom?arrow_forward
- Identify the compound with the longest carbon - nitrogen bond. O CH3CH2CH=NH O CH3CH2NH2 CH3CH2C=N CH3CH=NCH 3 The length of all the carbon-nitrogen bonds are the samearrow_forwardIdentify any polar covalent bonds in epichlorohydrin with S+ and 8- symbols in the appropriate locations. Choose the correct answer below. Η H's+ 6Η Η Η Η Η Ηδ Η Ο Ο HH +Η Η +Η Η Η -8+ CIarrow_forwardH H:O::::H H H HH H::O:D:D:H HH HH H:O:D:D:H .. HH H:O:D:D:H H H Select the correct Lewis dot structure for the following compound: CH3CH2OHarrow_forward
- Rank the following compounds in order of decreasing boiling point. ннннн -С-С-Н . н-с- ННННН H ΗΤΗ НННН TTTĪ н-с-с-с-с-о-н НННН НН C' Н н-с-с-с-с-н НН || Ш НННН H-C-C-C-C-N-H ННННН IVarrow_forwardRank the following compounds in order of decreasing dipole moment. |>||>||| ||>|||>| |>|||>|| |||>||>| O ||>>||| H F H F H c=c || H c=c F F IIIarrow_forwardchoose the description that best describes the geometry for the following charged species ch3-arrow_forward
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