Atkins' Physical chemistry
Atkins' Physical chemistry
11th Edition
ISBN: 9780198814740
Author: ATKINS, P. W. (peter William), 1940- (author.)
Publisher: Oxford University Press,
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Chapter 4, Problem 4B.8P
Interpretation Introduction

Interpretation: The final temperature of the liquid has to be calculated.

Concept introduction: The Clausius-Clapeyron’s equation shows the correlation between the temperature and pressure.  The Clausius-Clapeyron’s equation is shown below.

    ln(p2p1)=ΔHvaporizationR(1T21T1)

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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