Study Guide for Chemistry: Structure and Properties
2nd Edition
ISBN: 9780134460680
Author: Nivaldo Tro
Publisher: PEARSON
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Question
Chapter 4, Problem 48E
Interpretation Introduction
To determine:
The formula for the ionic compound that forms between given pair of elements
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and
gives compound A.
?
NH2
Br
Br
Propose a structural formula for compound A.
You do not have to explicitly draw H atoms.
You do not have to consider stereochemistry.
In cases where there is more than one answer, just draw one.
R3N
C14H19NO2
+ 2 R3NH*Br
A
Chapter 4 Solutions
Study Guide for Chemistry: Structure and Properties
Ch. 4 - How do the properties of compounds compare to the...Ch. 4 - What is a chemical bond? Why do chemical bonds...Ch. 4 - Explain the difference between an ionic bond and a...Ch. 4 - List and describe the different ways to represent...Ch. 4 - What is the difference between an empirical...Ch. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - How can you use Lewis structures to determine the...Ch. 4 - What is lattice energy?
Ch. 4 - Why is the formation of solid sodium chloride from...Ch. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - How does the Lewis model for covalent bonding...Ch. 4 - Explain howto nans molecular inorganic compounds.Ch. 4 - Prob. 20ECh. 4 - What is the formula mass for a compound? Why is it...Ch. 4 - Explain how the information in a chemical formula...Ch. 4 - What is mass percent composition? Why is it...Ch. 4 - Which kinds of conversion factors are inherent in...Ch. 4 - Which kind of chemical formula can be obtained...Ch. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Determine the empirical formula for the compound...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Write a chemical formula for each molecular model....Ch. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Write an electron configuration for Ne. Then write...Ch. 4 - Prob. 39ECh. 4 - Write a Lewis symbol for each atom or ion. a. S2-...Ch. 4 - Prob. 41ECh. 4 - Write the Lewis symbols that represent the ions in...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - The lattice energy of CsF is -744 kJ/mol, whereas...Ch. 4 - Rubidium iodide has a lattice energy of-617...Ch. 4 - Prob. 47ECh. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Prob. 53ECh. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Use covalent Lewis structures to explain why each...Ch. 4 - Use covalent Lewis structures to explain why the...Ch. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Name each compound. (Refer to the nomenclature...Ch. 4 - Prob. 68ECh. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Calculate the formula mass for each compound. NO2...Ch. 4 - Prob. 72ECh. 4 - Calculate the number of moles in each sample 72.5...Ch. 4 - Calculate the mass of each sample 15.7 mol HNO3...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - How many molecules are in each sample? 6.5 g H2O...Ch. 4 - Prob. 78ECh. 4 - Calculate the mass (in g) of each sample. 5.94 x...Ch. 4 - Calculate the mass (in g) of each sample 4.5 x...Ch. 4 - A sugar crystal contains approximately 1.8 x 1017...Ch. 4 - A salt crystal has a mass of 0.12 mg. How many...Ch. 4 - Calculate the mass percent composition of carbon...Ch. 4 - Calculate the mass percent composition of nitrogen...Ch. 4 - Most fertilizers consist of nitrogen-containing...Ch. 4 - Iron in the earth is in the form of iron ore....Ch. 4 - Copper(ll) fluoride contains 37.42% F by mass....Ch. 4 - Silver chloride, often used in silver plating,...Ch. 4 - The iodide ion is a dietary mineral essential to...Ch. 4 - The American Dental Association recommends that an...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Determine the number of moles of hydrogen atoms in...Ch. 4 - Determine the number of moles of oxygen atoms in...Ch. 4 - Calculate mass (in grams) of sodium in 8.5 g of...Ch. 4 - Calculate the mass (in kilograms) of chlorine in...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - Calculate the empirical formula for each stimulant...Ch. 4 - Calculate the empirical formula for each natural...Ch. 4 - The elemental mass percent composition of...Ch. 4 - The elemental mass percent composition of ascorbic...Ch. 4 - A 0.77-mg sample of nitrogen reacts with chlorine...Ch. 4 - A 45.2-mg sample of phosphorus reacts with...Ch. 4 - The empirical formula and molar mass of several...Ch. 4 - The malar mass and empirical formula of several...Ch. 4 - Combustion analysis of a hydrocarbon produced...Ch. 4 - Combustion analysis of naphthalene, a hydrocarbon...Ch. 4 - The foul odor of rancid butter is due largely to...Ch. 4 - Tartaric acid is the white, powdery substance that...Ch. 4 - Prob. 111ECh. 4 - Prob. 112ECh. 4 - Prob. 113ECh. 4 - Prob. 114ECh. 4 - How many molecules of ethanol (C2H5OH) (the...Ch. 4 - A drop of water has a volume of approximately 0.05...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - A Freon™ leak in the air conditioning system of an...Ch. 4 - Prob. 120ECh. 4 - A metal (M) forms a compound with the formula...Ch. 4 - A metal (M) forms an oxide with the formula M2O....Ch. 4 - Estradiol is a female sexual hormone that causes...Ch. 4 - Fructose is a common sugar found in fruit....Ch. 4 - Combustion analysis of a 13.42-g sample of equilin...Ch. 4 - Prob. 126ECh. 4 - Epsom salts is a hydrated ionic compound with the...Ch. 4 - A hydrate of copper(ll) chloride has the following...Ch. 4 - A compound of molar mass 177 g/mol contains only...Ch. 4 - Researchers obtain the following data from...Ch. 4 - Find the total number of atoms in a sample of...Ch. 4 - Vanadium forms four different oxides in which the...Ch. 4 - The chloride of an unknown metal is believed to...Ch. 4 - Prob. 134ECh. 4 - A chromium-containing compound has the formula...Ch. 4 - Prob. 136ECh. 4 - Prob. 137ECh. 4 - Prob. 138ECh. 4 - A mixture of NaCI and NaBr has a mass of 2.00 g...Ch. 4 - Three pure compounds form when 1.00-g samples of...Ch. 4 - A mixture of CaCO3 and (NH4)2CO3is 61.9% CO3 by...Ch. 4 - A mixture of 50.0 g of S and 1.00 x 102 g of CI2...Ch. 4 - Because of increasing evidence of damage to the...Ch. 4 - A particular coal contains 2.55% sulfur by mass....Ch. 4 - Lead is found in Earth’s crust as several...Ch. 4 - A 2.52-g sample of a compound containing only...Ch. 4 - Prob. 147ECh. 4 - The elements X and Y form a compound that is 40% X...Ch. 4 - A compound of X and Y is 13 X by mass. The atomic...Ch. 4 - A mixture of carbon and sulfur has a mass of 9.0...Ch. 4 - When molecules are represented by molecular...Ch. 4 - Prob. 152ECh. 4 - Explain the problem with this statement and...Ch. 4 - Without doing any calculations, arrange the...Ch. 4 - Prob. 155ECh. 4 - Prob. 156ECh. 4 - Prob. 157ECh. 4 - A compound isolated from the rind of lemons is...Ch. 4 - Prob. 159ECh. 4 - What is the empirical formula of the compound with...Ch. 4 - Which substance is an ionic compound? He N2O4 CCl4...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - What is the correct Lewis symbol for S?Ch. 4 - How many CH2Cl2 molecules are there in 25.0 g of...Ch. 4 - List the elements in the compound CF2Cl2 in order...Ch. 4 - Determine the mass of potassium in 35.5 g of KBr....Ch. 4 - A compound is 52.14% C, 13.13% H, and 34.73% O by...Ch. 4 - A compound has the empirical formula CH2O and a...Ch. 4 - Combustion of 30.42 g of a compound containing...
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