Solution Manual for Quantitative Chemical Analysis
Solution Manual for Quantitative Chemical Analysis
9th Edition
ISBN: 9781464175633
Author: Daniel Harris
Publisher: Palgrave Macmillan Higher Ed
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Chapter 4, Problem 4.37P

(a)

Interpretation Introduction

Interpretation:

A graph of log(current) versus log(concentration) has to be drawn and also the range at the log-log calibration gets linear has to be given.

Concept Introduction:

Calibration curves:

The response of an analytical methods to the known quantities of an analyte is shown by a calibration curve.

Standard solution are solutions that contains a known concentrations of analyte.

Blank solutions are solutions that has all the reagents and solvents used in analysis, but will not contain added analyte.

(b)

Interpretation Introduction

Interpretation:

A equation of line in the form of log(current)=m×log(concentration)+b has to be found out.

Concept Introduction:

Calibration curves:

The response of an analytical methods to the known quantities of an analyte is shown by a calibration curve.

Standard solution are solutions that contains a known concentrations of analyte.

Blank solutions are solutions that has all the reagents and solvents used in analysis, but will not contain added analyte.

Linear Calibration Curve:

The equation of linear calibration line is:

y(±sy)=[m(±um)]x+[b(±ub)]

(c)

Interpretation Introduction

Interpretation:

The concentration of p-nitrophenol corresponding to a signal of 99.9 nA has to be found out.

Concept Introduction:

Linear Calibration Curve:

The equation of linear calibration line is:

y(±sy)=[m(±um)]x+[b(±ub)]

Where,

m is the slope

y is the intercept

(d)

Interpretation Introduction

Interpretation:

Using propagation of uncertainty from chapter 3, the uncertainty in concentration has to be found out.

Concept Introduction:

Exponents and logarithm:

Consider, y=logx .

Here, the absolute uncertainty in y(ey) is proportional to the relative uncertainty in x, which is ex/x

Uncertainty for logarithm:        y =1ogxey =1ln 10 xexx 0.43429 exx

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