Chemistry - Modified MasteringChemistry
7th Edition
ISBN: 9780133892321
Author: McMurry
Publisher: PEARSON
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Chapter 4, Problem 4.12P
Interpretation Introduction
To determine:
Whether a precipitation reaction will occur in each of given situations and complete the given chemical equations.
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-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
What would be the best choices for the missing reagents 1 and 3 in this synthesis?
1. PPh3
3
1
2
2. n-BuLi
• Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like.
• Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is.
• Note: if one of your reagents needs to contain a halogen, use bromine.
Explanation
Check
Click and drag to start drawing a structure.
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Chapter 4 Solutions
Chemistry - Modified MasteringChemistry
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2ACh. 4 - Prob. 4.3PCh. 4 - Prob. 4.4PCh. 4 - Prob. 4.5ACh. 4 - Prob. 4.6PCh. 4 - APPLY 4.7 Sulfuric acid is normally purchased at a...Ch. 4 - Prob. 4.8PCh. 4 - Conceptual APPLY 4.9 Three different substances,...Ch. 4 - Prob. 4.10P
Ch. 4 - Prob. 4.11ACh. 4 - Prob. 4.12PCh. 4 - APPLY 4.13 How might you use a precipitation...Ch. 4 - Conceptual PRACTICE 4.14 An aqueous solution...Ch. 4 - Conceptual APPLY 4.15 A solution containing the...Ch. 4 - Prob. 4.16PCh. 4 - APPLY 4.17 Give likely chemical formulas...Ch. 4 - PRACTICE 4.18 Write a balanced ionic equation and...Ch. 4 - Prob. 4.19ACh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21ACh. 4 - Prob. 4.22PCh. 4 - Prob. 4.23ACh. 4 - PRACTICE 4.24 Assign an oxidation number to each...Ch. 4 - APPLY 4.25 Chlorine can have several different...Ch. 4 - Prob. 4.26PCh. 4 - APPLY 4.27 Police often use a Breathalyzer test to...Ch. 4 - PRACTICE 4.28 Predict whether the following...Ch. 4 - Prob. 4.29ACh. 4 - Prob. 4.30PCh. 4 - Prob. 4.31ACh. 4 - Prob. 4.32PCh. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38CPCh. 4 - Prob. 4.39CPCh. 4 - Prob. 4.40CPCh. 4 - Assume that an aqueous solution Of a cation,...Ch. 4 - The following pictures represent aqueous solutions...Ch. 4 - Prob. 4.43CPCh. 4 - The concentration of an aqueous solution of NaOCl...Ch. 4 - Assume that the electrical conductivity of a...Ch. 4 - Based on the positions in the periodic table,...Ch. 4 - The following two redox reactions occur between...Ch. 4 - Prob. 4.48SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - How many milliliters of a 0.45 M BaCl2 solution...Ch. 4 - How many milliliters of a 0.350 M KOH solution...Ch. 4 - The sterile saline solution used to rinse contact...Ch. 4 - Prob. 4.53SPCh. 4 - Copper reacts with dilute nitric acid according to...Ch. 4 - Prob. 4.55SPCh. 4 - Prob. 4.56SPCh. 4 - Prob. 4.57SPCh. 4 - Prob. 4.58SPCh. 4 - Prob. 4.59SPCh. 4 - Prob. 4.60SPCh. 4 - Prob. 4.61SPCh. 4 - Prob. 4.62SPCh. 4 - Prob. 4.63SPCh. 4 - Prob. 4.64SPCh. 4 - Is it possible for a molecular substance to be a...Ch. 4 - Prob. 4.66SPCh. 4 - Prob. 4.67SPCh. 4 - Prob. 4.68SPCh. 4 - Prob. 4.69SPCh. 4 - Prob. 4.70SPCh. 4 - Prob. 4.71SPCh. 4 - Prob. 4.72SPCh. 4 - Prob. 4.73SPCh. 4 - Prob. 4.74SPCh. 4 - Prob. 4.75SPCh. 4 - Prob. 4.76SPCh. 4 - Prob. 4.77SPCh. 4 - Prob. 4.78SPCh. 4 - Prob. 4.79SPCh. 4 - Prob. 4.80SPCh. 4 - Prob. 4.81SPCh. 4 - Prob. 4.82SPCh. 4 - Prob. 4.83SPCh. 4 - Prob. 4.84SPCh. 4 - Prob. 4.85SPCh. 4 - Assume that you are given a solution of an unknown...Ch. 4 - Prob. 4.87SPCh. 4 - Prob. 4.88SPCh. 4 - Prob. 4.89SPCh. 4 - Prob. 4.90SPCh. 4 - Prob. 4.91SPCh. 4 - Prob. 4.92SPCh. 4 - Prob. 4.93SPCh. 4 - Prob. 4.94SPCh. 4 - Prob. 4.95SPCh. 4 - Prob. 4.96SPCh. 4 - Prob. 4.97SPCh. 4 - Prob. 4.98SPCh. 4 - Prob. 4.99SPCh. 4 - Prob. 4.100SPCh. 4 - Where in the periodic table are the most easily...Ch. 4 - In each of the following instances, tell whether...Ch. 4 - Tell for each of the following substances whether...Ch. 4 - Prob. 4.104SPCh. 4 - Prob. 4.105SPCh. 4 - Prob. 4.106SPCh. 4 - Prob. 4.107SPCh. 4 - Nitrogen can have several different oxidation...Ch. 4 - Phosphorus can have several different oxidation...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - 4.111 Which element is oxidized and which is...Ch. 4 - Use the activity series of metals (Table 4.5) to...Ch. 4 - Prob. 4.113SPCh. 4 - Prob. 4.114SPCh. 4 - Prob. 4.115SPCh. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Iodine, I2, reacts with aqueous thiosulfate ion in...Ch. 4 - Dichromate ion, Cr2O72 , reacts with aqueous...Ch. 4 - Prob. 4.119SPCh. 4 - Prob. 4.120SPCh. 4 - Standardized solutions Of KBrO3are frequently used...Ch. 4 - Prob. 4.122SPCh. 4 - Prob. 4.123SPCh. 4 - Prob. 4.124SPCh. 4 - Calcium levels in blood can be determined by...Ch. 4 - Prob. 4.126CPCh. 4 - Prob. 4.127CPCh. 4 - Prob. 4.128CPCh. 4 - Prob. 4.129CPCh. 4 - Prob. 4.130CPCh. 4 - Prob. 4.131CPCh. 4 - Prob. 4.132CPCh. 4 - Prob. 4.133CPCh. 4 - Prob. 4.134CPCh. 4 - Prob. 4.135CPCh. 4 - Prob. 4.136CPCh. 4 - Prob. 4.137CPCh. 4 - Prob. 4.138CPCh. 4 - Prob. 4.139CPCh. 4 - Prob. 4.140CPCh. 4 - Prob. 4.141CPCh. 4 - Prob. 4.142CPCh. 4 - Prob. 4.143CPCh. 4 - Prob. 4.144CPCh. 4 - Prob. 4.145CPCh. 4 - Prob. 4.146CPCh. 4 - Prob. 4.147CPCh. 4 - Prob. 4.148CPCh. 4 - Prob. 4.149CPCh. 4 - Prob. 4.150CPCh. 4 - Prob. 4.150MPCh. 4 - Prob. 4.151CPCh. 4 - Prob. 4.151MPCh. 4 - Prob. 4.152CPCh. 4 - Prob. 4.152MPCh. 4 - Prob. 4.153CPCh. 4 - Prob. 4.153MPCh. 4 - Prob. 4.154CPCh. 4 - Prob. 4.154MPCh. 4 - Prob. 4.155CPCh. 4 - Prob. 4.155MPCh. 4 - Prob. 4.156CPCh. 4 - Prob. 4.156MPCh. 4 - Prob. 4.157CPCh. 4 - Prob. 4.157MPCh. 4 - Prob. 4.158CPCh. 4 - Prob. 4.158MPCh. 4 - Prob. 4.159CPCh. 4 - Prob. 4.159MPCh. 4 - Prob. 4.160CPCh. 4 - Prob. 4.160MPCh. 4 - Prob. 4.161MPCh. 4 - Prob. 4.162MP
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