Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134564586
Author: Timberlake
Publisher: PEARSON
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Chapter 4, Problem 4.107APP
Interpretation Introduction
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Question 5: Name the following compound in two ways
using side chain and using prefix amine (Common name
and IUPAC name both)
CH3NH2
CH3CH2NHCH3
CH₂CH₂N(CH3)2
Draw the structure of diethyl methyl amine
Question 6. Write the balanced combustion reaction
for:
a. Hexane
b. Propyne
c. 2-pentene
Question 7: Write the following electrophilic
substitution reactions of benzene:
Hint: Use notes if you get confused
a. Halogenation reaction:
b. Nitration reaction :
c. Sulphonation reaction:
d. Alkylation reaction:
e. Aceylation reaction:
Question 4. Name the following structures
○
CH3-C-N-H
H
CH3CH2-C-N-H
H
CH3CH2-C-N-CH3
H
A. Add Water to below compound which 2-methyl 2-butene (addition Reaction)
H₂C
CH₂
CH,
+ H₂O-> ?
Major product?
Minor product?
B. Add Bromine to the compound which 2-methyl 2-butene (addition Reaction)
CH₂
CH₂
+ Br₂→ ?
Major product and Minor product both are same in this?
C. Add Hydrogen Bromide to the compound which 2-methyl 2-butene (addition
Reaction)
H,C
CH₂
CH₂
+ HBr
Major product?
Minor product?
D. Add Hydrogen to the compound which 2-methyl 2-butene (addition Reaction)
CH₂
CH₂
+ H₂
Major product and Minor product both are same in this?
Chapter 4 Solutions
Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
Ch. 4.1 - Write the symbols for the following elements. a....Ch. 4.1 - Prob. 4.2PPCh. 4.1 - 4.3 Write the name for the symbol of each of the...Ch. 4.1 - Prob. 4.4PPCh. 4.1 - Prob. 4.5PPCh. 4.1 - Prob. 4.6PPCh. 4.2 - 4.7 Identify the group or period number described...Ch. 4.2 - 4.8 Identify the group or period number described...Ch. 4.2 - Prob. 4.9PPCh. 4.2 - 4.10 Give the symbol of the element described by...
Ch. 4.2 - Prob. 4.11PPCh. 4.2 - Identify each of the following elements as a...Ch. 4.2 - Prob. 4.13PPCh. 4.2 - 4.14 Using TABLE 4.4, identify the function of...Ch. 4.2 - Prob. 4.15PPCh. 4.2 - Prob. 4.16PPCh. 4.3 - Identify each of the following as describing...Ch. 4.3 - 4.18 Identify each of the following as describing...Ch. 4.3 - What did Rutherford determine about the structure...Ch. 4.3 - 4.20 How did Thomson determine that the electrons...Ch. 4.3 - Prob. 4.21PPCh. 4.3 - Is each of the following statements true or false?...Ch. 4.3 - Prob. 4.23PPCh. 4.3 - 4.24 Sometimes clothes cling together when...Ch. 4.4 - 4.25 Would you use the atomic number, mass...Ch. 4.4 - 4.26 Identify the type of subatomic particles...Ch. 4.4 - Prob. 4.27PPCh. 4.4 - Prob. 4.28PPCh. 4.4 - Prob. 4.29PPCh. 4.4 - Prob. 4.30PPCh. 4.4 - Complete the following table for atoms of...Ch. 4.4 - Prob. 4.32PPCh. 4.5 - What are the number of protons, neutrons, and...Ch. 4.5 - 4.34 What are the number of protons, neutrons, and...Ch. 4.5 - Write the atomic symbol for the isotope with each...Ch. 4.5 - Prob. 4.36PPCh. 4.5 - Argon has three naturally occurring isotopes, with...Ch. 4.5 - Strontium has four naturally occurring isotopes,...Ch. 4.5 - Prob. 4.39PPCh. 4.5 - 4.40 Two isotopes of rubidium occur naturally, ...Ch. 4.5 - Prob. 4.41PPCh. 4.5 - Prob. 4.42PPCh. 4.5 - There are two naturally occurring isotopes of...Ch. 4.5 - There are five naturally occurring isotopes of...Ch. 4.6 - Electrons can move to higher energy levels when...Ch. 4.6 - Prob. 4.46PPCh. 4.6 - Prob. 4.47PPCh. 4.6 - Prob. 4.48PPCh. 4.6 - Prob. 4.49PPCh. 4.6 - 4.50 Write the electron arrangement for each of...Ch. 4.6 - Prob. 4.51PPCh. 4.6 - Prob. 4.52PPCh. 4.7 - What is the group number and number of valence...Ch. 4.7 - 4.54 What is the group number and number of...Ch. 4.7 - Prob. 4.55PPCh. 4.7 - Write the group number and draw the Lewis symbol...Ch. 4.7 - Prob. 4.57PPCh. 4.7 - Prob. 4.58PPCh. 4.7 - Prob. 4.59PPCh. 4.7 - Prob. 4.60PPCh. 4.7 - Prob. 4.61PPCh. 4.7 - 4.62 Select the element in each pair with the...Ch. 4.7 - Prob. 4.63PPCh. 4.7 - Prob. 4.64PPCh. 4.7 - Prob. 4.65PPCh. 4.7 - Prob. 4.66PPCh. 4.7 - Prob. 4.67PPCh. 4.7 - Prob. 4.68PPCh. 4.7 - Prob. 4.69PPCh. 4.7 - 4.70 Fill in the following blanks using higher or...Ch. 4.7 - Prob. 4.71PPCh. 4.7 - Prob. 4.72PPCh. 4.7 - Prob. 4.73PPCh. 4.7 - 4.74 Which statements completed with a to e will...Ch. 4.7 - a. What is the group number and name of the group...Ch. 4.7 - a. How many neutrons are in K-41? b. Write the...Ch. 4 - Prob. 4.77UTCCh. 4 - Use Rutherford’s gold-foil experiment to answer...Ch. 4 - Prob. 4.79UTCCh. 4 - Prob. 4.80UTCCh. 4 - Prob. 4.81UTCCh. 4 - Prob. 4.82UTCCh. 4 - Prob. 4.83UTCCh. 4 - Prob. 4.84UTCCh. 4 - Prob. 4.85UTCCh. 4 - Prob. 4.86UTCCh. 4 - Match the spheres A through D with atoms of Li,...Ch. 4 - Prob. 4.88UTCCh. 4 - Prob. 4.89UTCCh. 4 - Of the elements Sn, Xe, Te, Sr, I, and Rb,...Ch. 4 - Prob. 4.91APPCh. 4 - Prob. 4.92APPCh. 4 - Prob. 4.93APPCh. 4 - Prob. 4.94APPCh. 4 - Prob. 4.95APPCh. 4 - Prob. 4.96APPCh. 4 - Prob. 4.97APPCh. 4 - Write the name and symbol of the element with the...Ch. 4 - Prob. 4.99APPCh. 4 - Prob. 4.100APPCh. 4 - Prob. 4.101APPCh. 4 - Prob. 4.102APPCh. 4 - Prob. 4.103APPCh. 4 - Prob. 4.104APPCh. 4 - Prob. 4.105APPCh. 4 - Prob. 4.106APPCh. 4 - Prob. 4.107APPCh. 4 - Prob. 4.108APPCh. 4 - Why is the ionization energy of Ca higher than K,...Ch. 4 - Prob. 4.110APPCh. 4 - Prob. 4.111APPCh. 4 - Of the elements F, Br, Cl, and I, which (4.7) a....Ch. 4 - Prob. 4.113CPCh. 4 - Prob. 4.114CPCh. 4 - Prob. 4.115CPCh. 4 - Prob. 4.116CP
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- 36) Complete the following multi-step reactions showing applications of enolate ions arising from ketones, esters, malonic ester, and keto ester, etc. (30 pts) (1) A NaOH, H₂O+ heat A NaOEt EtO OEt (11) EOH, H+ H. B LDA, H₂O+ -78°C B (i) NaOMe, Et-Br (ii) H₂O+, heat EtOOC (III) COOEt B A (i) NaOEt LiAlH 4-bromo-2-butene H₂O+ (ii) H3O+, heat Write the mechanism for Aldol Condensation (I A or B), and Claisen Condensation (II A).arrow_forward31) Complete two sets of reactions involving (R)-4-methyl-pent-2-ol producing racemic mixture of tertiary alcohols (D) and ketone derivative (C). Illustrate the mechanism of B and C or D. (25 pts) O OH 0 K2Cr2O7 Ph-CH2-Br, Mg, H2SO4 THF, H3O* (A) (D) Racemic mixture TsCl, Py (B) KCN, DMSO Ph-CH2-Br, Mg, THF, H3O+ (C) Mechanism for reactions B and C:arrow_forwardManoharan Mariappan, Ph.D., Dept. of Natur. Sci., NFC, Tallahassee, FL 33) Synthesize the aromatic compound containing para-substituted carbonyl compound starting from benzene. Illustrate the mechanism for reaction A. 1) NU (25 pts) A FeCl B (i) HNO3, H2SO4 (II) Sn, HCl(aq) NH₂ NO₂-D NH₂ (i) MeCO2Me, heat C (ii) K2Cr2O7/H2SO4 D (ii) SOCl2 (iii) 2 Et-NH2 Mechanism for reaction for the nitration of alkyl benzene (B-i): Characterize the product compound arising from the reaction D by IR and IH NMR spectral data: IR data (cm): 'H NMR data: Draw the structure and assign the chemical shift with the spin-splitting.arrow_forward
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- Draw the mechanism to make the alcohol 2-hexanol. Draw the Mechanism to make the alcohol 1-hexanol.arrow_forwardDraw the mechanism for the formation of diol by starting with 1-pentanal in... basic conditions then acidic conditions then draw the mechanism for the formation of a carboxylic acid from your product.arrow_forwardIdentify each chiral carbon as either R or S. Identify the overall carbohydrates as L or Darrow_forward
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