Chemistry: A Molecular Approach, Books a la Carte Edition; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Chemistry: A Molecular Approach, 4/e
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Chapter 4, Problem 27E
Interpretation Introduction
To determine: The number of moles of
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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B
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 4 Solutions
Chemistry: A Molecular Approach, Books a la Carte Edition; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card -- for Chemistry: A Molecular Approach, 4/e
Ch. 4 - Prob. 1SAQCh. 4 - Q2. Sodium and chlorine react to form sodium...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - Prob. 8SAQCh. 4 - Prob. 9SAQCh. 4 - Q10. What is the net ionic equation for the...
Ch. 4 - Q11. What is the net ionic equation for the...Ch. 4 - Q12. What is the net ionic equation for the...Ch. 4 - Prob. 13SAQCh. 4 - Prob. 14SAQCh. 4 - Prob. 15SAQCh. 4 - 1. What is reaction stoichiometry? What is the...Ch. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - 5. What is molarity? How is it useful?
Ch. 4 - 6. Explain how a strong electrolyte, a weak...Ch. 4 - 7. Explain the difference between a strong acid...Ch. 4 - Prob. 8ECh. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - 15. What is an acid–base reaction? Give an...Ch. 4 - 16. Explain the principles behind an acid–base...Ch. 4 - 17. What is a gas-evolution reaction? Give an...Ch. 4 - 18. What reactant types give rise to gas-evolution...Ch. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - 23. In a redox reaction, which reactant is the...Ch. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - 27. Calculate how many moles of NO2 form when each...Ch. 4 - 28. Calculate how many moles of NH3 form when each...Ch. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - 33. For each of the reactions, calculate the mass...Ch. 4 - 34. For each of the reactions, calculate the mass...Ch. 4 - 35. For each of the acid–base reactions, calculate...Ch. 4 - Prob. 36ECh. 4 - 37. Find the limiting reactant for each initial...Ch. 4 - 38. Find the limiting reactant for each initial...Ch. 4 - 39. Consider the reaction:
4 HCl(g) + O2(g) → 2...Ch. 4 - Prob. 40ECh. 4 - Prob. 41ECh. 4 - Prob. 42ECh. 4 - 43. Zinc sulfide reacts with oxygen according to...Ch. 4 - 44. Iron(II) sulfide reacts with hydrochloric acid...Ch. 4 - Prob. 45ECh. 4 - Prob. 46ECh. 4 - 47. Iron(III) oxide reacts with carbon monoxide...Ch. 4 - Prob. 48ECh. 4 - 49. Lead ions can be precipitated from solution...Ch. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - 53. Calculate the molarity of each solution.
a....Ch. 4 - Prob. 54ECh. 4 - 55. What is the molarity of NO3– in each...Ch. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - 58. What volume of 0.200 M ethanol solution...Ch. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - 61. If 123 mL of a 1.1 M glucose solution is...Ch. 4 - 62. If 3.5 L of a 4.8 M SrCl2 solution is diluted...Ch. 4 - 63. To what volume should you dilute 50.0 mL of a...Ch. 4 - 64. To what volume should you dilute 25 mL of a...Ch. 4 - Prob. 65ECh. 4 - 66. Consider the reaction:
Li2S(aq) + Co(NO3)2(aq)...Ch. 4 - 67. What is the minimum amount of 6.0 M H2SO4...Ch. 4 - Prob. 68ECh. 4 - 69. A 25.0-mL sample of a 1.20 M potassium...Ch. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - 76. Complete and balance each equation. If no...Ch. 4 - Write a molecular equation for the precipitation...Ch. 4 - 78. Write a molecular equation for the...Ch. 4 - Prob. 79ECh. 4 - 80. Write balanced complete ionic and net ionic...Ch. 4 - Prob. 81ECh. 4 - Prob. 82ECh. 4 - 83. Write balanced molecular and net ionic...Ch. 4 - Prob. 84ECh. 4 - Prob. 85ECh. 4 - Prob. 86ECh. 4 - Prob. 87ECh. 4 - 88. Write balanced complete ionic and net ionic...Ch. 4 - Prob. 89ECh. 4 - 90. A 30.00-mL sample of an unknown H3PO4 solution...Ch. 4 - Prob. 91ECh. 4 - Prob. 92ECh. 4 - Prob. 93ECh. 4 - Prob. 94ECh. 4 - Prob. 95ECh. 4 - Prob. 96ECh. 4 - Prob. 97ECh. 4 - Prob. 98ECh. 4 - Prob. 99ECh. 4 - Prob. 100ECh. 4 - Prob. 101ECh. 4 - Prob. 102ECh. 4 - 103. People sometimes use sodium bicarbonate as an...Ch. 4 - 104. Toilet bowl cleaners often contain...Ch. 4 - Prob. 105ECh. 4 - Prob. 106ECh. 4 - Prob. 107ECh. 4 - Prob. 108ECh. 4 - Prob. 109ECh. 4 - 110. A hydrochloric acid solution will neutralize...Ch. 4 - 111. Predict the products and write a balanced...Ch. 4 - 112. Predict the products and write a balanced...Ch. 4 - Prob. 113ECh. 4 - Prob. 114ECh. 4 - Prob. 115ECh. 4 - Prob. 116ECh. 4 - 117. The nitrogen in sodium nitrate and in...Ch. 4 - 118. Find the volume of 0.110 M hydrochloric acid...Ch. 4 - Prob. 119ECh. 4 - 120. We prepare a solution by mixing 0.10 L of...Ch. 4 - Prob. 121ECh. 4 - Prob. 122ECh. 4 - Prob. 123ECh. 4 - 124. An important reaction that takes place in a...Ch. 4 - 125. A liquid fuel mixture contains 30.35% hexane...Ch. 4 - 126. Titanium occurs in the magnetic mineral...Ch. 4 - Prob. 127ECh. 4 - Prob. 128ECh. 4 - Prob. 129ECh. 4 - Prob. 130ECh. 4 - 131. Recall from Section 4.6 that sodium carbonate...Ch. 4 - 132. Lead poisoning is a serious condition...Ch. 4 - Prob. 133ECh. 4 - Prob. 134ECh. 4 - Prob. 135ECh. 4 - Prob. 136ECh. 4 - Prob. 137ECh. 4 - Prob. 138ECh. 4 - Prob. 139ECh. 4 - Prob. 140ECh. 4 - Prob. 141QGWCh. 4 - Prob. 142QGWCh. 4 - Prob. 143QGWCh. 4 - 144. Define and give an example of each of the...Ch. 4 - Prob. 145QGWCh. 4 - Prob. 146DIA
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
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