Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 4, Problem 19E
Explain howto nans molecular inorganic compounds.
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C
This question shows how molecular orbital (MO) theory can be used to understand the chemical
properties of elemental oxygen O₂ and its anionic derivative superoxide Oz.
a)
Draw the MO energy diagram for both O2 and O2. Clearly label your diagram with atomic orbital names
and molecular orbital symmetry labels and include electrons.
Draw the Lewis structure of O2. How does the MO description of O2 differ from the Lewis structure, and
how does this difference relate to the high reactivity and magnetic properties of oxygen?
) Use the MO diagram in (a) to explain the difference in bond length and bond energy between superoxide
ion (Oz, 135 pm, 360 kJ/mol) and oxygen (O2, 120.8 pm, 494 kJ/mol).
Please draw
-Page: 8
nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]".
What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry
of [Co(H2O)]?
b)
Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron
configurations of [Co(H2O)]:
Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance
or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of
[Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1
kJ/mol)
Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange
an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low
in configuration vs in the high spin configuration? What can you say about the importance of exchange energy
07
Chapter 4 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 4 - How do the properties of compounds compare to the...Ch. 4 - What is a chemical bond? Why do chemical bonds...Ch. 4 - Explain the difference between an ionic bond and a...Ch. 4 - List and describe the different ways to represent...Ch. 4 - What is the difference between an empirical...Ch. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - How can you use Lewis structures to determine the...Ch. 4 - What is lattice energy?
Ch. 4 - Why is the formation of solid sodium chloride from...Ch. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - How does the Lewis model for covalent bonding...Ch. 4 - Explain howto nans molecular inorganic compounds.Ch. 4 - Prob. 20ECh. 4 - What is the formula mass for a compound? Why is it...Ch. 4 - Explain how the information in a chemical formula...Ch. 4 - What is mass percent composition? Why is it...Ch. 4 - Which kinds of conversion factors are inherent in...Ch. 4 - Which kind of chemical formula can be obtained...Ch. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Determine the empirical formula for the compound...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Write a chemical formula for each molecular model....Ch. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Write an electron configuration for Ne. Then write...Ch. 4 - Prob. 39ECh. 4 - Write a Lewis symbol for each atom or ion. a. S2-...Ch. 4 - Prob. 41ECh. 4 - Write the Lewis symbols that represent the ions in...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - The lattice energy of CsF is -744 kJ/mol, whereas...Ch. 4 - Rubidium iodide has a lattice energy of-617...Ch. 4 - Prob. 47ECh. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Prob. 53ECh. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Use covalent Lewis structures to explain why each...Ch. 4 - Use covalent Lewis structures to explain why the...Ch. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Name each compound. (Refer to the nomenclature...Ch. 4 - Prob. 68ECh. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Calculate the formula mass for each compound. NO2...Ch. 4 - Prob. 72ECh. 4 - Calculate the number of moles in each sample 72.5...Ch. 4 - Calculate the mass of each sample 15.7 mol HNO3...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - How many molecules are in each sample? 6.5 g H2O...Ch. 4 - Prob. 78ECh. 4 - Calculate the mass (in g) of each sample. 5.94 x...Ch. 4 - Calculate the mass (in g) of each sample 4.5 x...Ch. 4 - A sugar crystal contains approximately 1.8 x 1017...Ch. 4 - A salt crystal has a mass of 0.12 mg. How many...Ch. 4 - Calculate the mass percent composition of carbon...Ch. 4 - Calculate the mass percent composition of nitrogen...Ch. 4 - Most fertilizers consist of nitrogen-containing...Ch. 4 - Iron in the earth is in the form of iron ore....Ch. 4 - Copper(ll) fluoride contains 37.42% F by mass....Ch. 4 - Silver chloride, often used in silver plating,...Ch. 4 - The iodide ion is a dietary mineral essential to...Ch. 4 - The American Dental Association recommends that an...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Determine the number of moles of hydrogen atoms in...Ch. 4 - Determine the number of moles of oxygen atoms in...Ch. 4 - Calculate mass (in grams) of sodium in 8.5 g of...Ch. 4 - Calculate the mass (in kilograms) of chlorine in...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - Calculate the empirical formula for each stimulant...Ch. 4 - Calculate the empirical formula for each natural...Ch. 4 - The elemental mass percent composition of...Ch. 4 - The elemental mass percent composition of ascorbic...Ch. 4 - A 0.77-mg sample of nitrogen reacts with chlorine...Ch. 4 - A 45.2-mg sample of phosphorus reacts with...Ch. 4 - The empirical formula and molar mass of several...Ch. 4 - The malar mass and empirical formula of several...Ch. 4 - Combustion analysis of a hydrocarbon produced...Ch. 4 - Combustion analysis of naphthalene, a hydrocarbon...Ch. 4 - The foul odor of rancid butter is due largely to...Ch. 4 - Tartaric acid is the white, powdery substance that...Ch. 4 - Prob. 111ECh. 4 - Prob. 112ECh. 4 - Prob. 113ECh. 4 - Prob. 114ECh. 4 - How many molecules of ethanol (C2H5OH) (the...Ch. 4 - A drop of water has a volume of approximately 0.05...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - A Freon™ leak in the air conditioning system of an...Ch. 4 - Prob. 120ECh. 4 - A metal (M) forms a compound with the formula...Ch. 4 - A metal (M) forms an oxide with the formula M2O....Ch. 4 - Estradiol is a female sexual hormone that causes...Ch. 4 - Fructose is a common sugar found in fruit....Ch. 4 - Combustion analysis of a 13.42-g sample of equilin...Ch. 4 - Prob. 126ECh. 4 - Epsom salts is a hydrated ionic compound with the...Ch. 4 - A hydrate of copper(ll) chloride has the following...Ch. 4 - A compound of molar mass 177 g/mol contains only...Ch. 4 - Researchers obtain the following data from...Ch. 4 - Find the total number of atoms in a sample of...Ch. 4 - Vanadium forms four different oxides in which the...Ch. 4 - The chloride of an unknown metal is believed to...Ch. 4 - Prob. 134ECh. 4 - A chromium-containing compound has the formula...Ch. 4 - Prob. 136ECh. 4 - Prob. 137ECh. 4 - Prob. 138ECh. 4 - A mixture of NaCI and NaBr has a mass of 2.00 g...Ch. 4 - Three pure compounds form when 1.00-g samples of...Ch. 4 - A mixture of CaCO3 and (NH4)2CO3is 61.9% CO3 by...Ch. 4 - A mixture of 50.0 g of S and 1.00 x 102 g of CI2...Ch. 4 - Because of increasing evidence of damage to the...Ch. 4 - A particular coal contains 2.55% sulfur by mass....Ch. 4 - Lead is found in Earth’s crust as several...Ch. 4 - A 2.52-g sample of a compound containing only...Ch. 4 - Prob. 147ECh. 4 - The elements X and Y form a compound that is 40% X...Ch. 4 - A compound of X and Y is 13 X by mass. The atomic...Ch. 4 - A mixture of carbon and sulfur has a mass of 9.0...Ch. 4 - When molecules are represented by molecular...Ch. 4 - Prob. 152ECh. 4 - Explain the problem with this statement and...Ch. 4 - Without doing any calculations, arrange the...Ch. 4 - Prob. 155ECh. 4 - Prob. 156ECh. 4 - Prob. 157ECh. 4 - A compound isolated from the rind of lemons is...Ch. 4 - Prob. 159ECh. 4 - What is the empirical formula of the compound with...Ch. 4 - Which substance is an ionic compound? He N2O4 CCl4...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - What is the correct Lewis symbol for S?Ch. 4 - How many CH2Cl2 molecules are there in 25.0 g of...Ch. 4 - List the elements in the compound CF2Cl2 in order...Ch. 4 - Determine the mass of potassium in 35.5 g of KBr....Ch. 4 - A compound is 52.14% C, 13.13% H, and 34.73% O by...Ch. 4 - A compound has the empirical formula CH2O and a...Ch. 4 - Combustion of 30.42 g of a compound containing...
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