The initial molarity of MCHM in the river. Concept introduction: Molarity is used as concentration unit and defined as the ratio of number of moles of solute to the volume of the solution in liter. The unit of molarity is mol/L M = Number of mole of MCHM Volume of the solution
The initial molarity of MCHM in the river. Concept introduction: Molarity is used as concentration unit and defined as the ratio of number of moles of solute to the volume of the solution in liter. The unit of molarity is mol/L M = Number of mole of MCHM Volume of the solution
Interpretation: The initial molarity of MCHM in the river.
Concept introduction: Molarity is used as concentration unit and defined as the ratio of number of moles of solute to the volume of the solution in liter. The unit of molarity is mol/L
M=NumberofmoleofMCHMVolumeofthesolution
(b)
Interpretation Introduction
Interpretation: The required volume of water to make the solution of 1.00×10−10M .
Concept introduction: Volume of the river is calculated by the formula,
V=Lentgh×Width×Depth
By putting this value of volume in the formula of molarity, we get,
M=NumberofmoleofMCHMLength×Width×Depth
Now, from this formula we can calculate the depth of the river,
Calculate the free energy of formation of 1 mol of Cu in cells where the electrolyte is 1 mol dm-3 Cu2+ in sulfate solution, pH 0. E° for the Cu2+/Cu pair in this medium is +142 mV versus ENH.Assume the anodic reaction is oxygen evolution.Data: EH2 = -0.059 pH (V) and EO2 = 1.230 - 0.059 pH (V); 2.3RT/F = 0.059 V
If the normal potential for the Fe(III)/Fe(II) pair in acid at zero pH is 524 mV Hg/Hg2Cl2 . The potential of the saturated calomel reference electrode is +246 mV versus the NHE. Calculate E0 vs NHE.
Given the galvanic cell whose scheme is: (-) Zn/Zn2+ ⋮⋮ Ag+/Ag (+). If we know the normal potentials E°(Zn2+/Zn) = -0.76V and E°(Ag+/Ag) = 0.799 V. Indicate the electrodes that are the anode and the cathode and calculate the E0battery.
Chapter 4 Solutions
Laboratory Experiments For Chemistry: The Central Science, Si Edition