Chemistry with Access Code, Hybrid Edition
9th Edition
ISBN: 9781285188492
Author: Steven S. Zumdahl
Publisher: CENGAGE L
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Textbook Question
Chapter 4, Problem 109AE
The blood alcohol (C2H5OH) level can be determined by titrating a sample of blood plasma with an acidic potassium di-chromate solution, resulting in the production of Cr3+ (aq) and carbon dioxide. The reaction can be monitored because the dichromate ion (Cr2O72–) is orange in solution, and the Cr3+ ion is green. The balanced equations is
16H+(aq) + 2Cr2O72–(aq) + C2H5OH(aq) → 4Cr4+(aq) + 2CO2(g) + 11H2O(l)
This reaction is an oxidation–reduction reaction. What species is reduced, and what species is oxidized? How many electrons are transferred in the balanced equation above?
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Chapter 4 Solutions
Chemistry with Access Code, Hybrid Edition
Ch. 4 - The (aq) designation listed after a solute...Ch. 4 - Characterize strong electrolytes versus weak...Ch. 4 - Distinguish between the terms slightly soluble and...Ch. 4 - Molarity is a conversion factor relating moles of...Ch. 4 - What is a dilution? What stays constant in a...Ch. 4 - When the following beakers are mixed, draw a...Ch. 4 - Differentiate between the formula equation, the...Ch. 4 - What is an acid-base reaction? Strong bases are...Ch. 4 - Define the terms oxidation, reduction, oxidizing...Ch. 4 - Prob. 10RQ
Ch. 4 - Assume you have a highly magnified view of a...Ch. 4 - You have a solution of table salt in water. What...Ch. 4 - You have a sugar solution (solution A) with...Ch. 4 - You add an aqueous solution of lead nitrate to an...Ch. 4 - Order the following molecules from lowest to...Ch. 4 - Why is it that when something gains electrons, it...Ch. 4 - Consider separate aqueous solutions of HCl and...Ch. 4 - Prob. 8ALQCh. 4 - Prob. 9ALQCh. 4 - The exposed electrodes of a light bulb are placed...Ch. 4 - Differentiate between what happens when the...Ch. 4 - A typical solution used in general chemistry...Ch. 4 - Prob. 15QCh. 4 - A student wants to prepare 1.00 L of a 1.00-M...Ch. 4 - List the formulas of three soluble bromide salts...Ch. 4 - When 1.0 mole of solid lead nitrate is added to...Ch. 4 - What is an acid and what is a base? An acid-base...Ch. 4 - A student had 1.00 L of a 1.00-M acid solution....Ch. 4 - Differentiate between the following terms. a....Ch. 4 - How does one balance redox reactions by the...Ch. 4 - Prob. 23ECh. 4 - Match each name below with the following...Ch. 4 - Calcium chloride is a strong electrolyte and is...Ch. 4 - Commercial cold packs and hot packs are available...Ch. 4 - Calculate the molarity of each of these solutions....Ch. 4 - A solution of ethanol (C2H5OH) in water is...Ch. 4 - Calculate the concentration of all ions present in...Ch. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - Prob. 33ECh. 4 - If 10. g of AgNO3 is available, what volume of...Ch. 4 - A solution is prepared by dissolving 10.8 g...Ch. 4 - A solution was prepared by mixing 50.00 mL of...Ch. 4 - Calculate the sodium ion concentration when 70.0...Ch. 4 - Suppose 50.0 mL of 0.250 M CoCl2 solution is added...Ch. 4 - Prob. 41ECh. 4 - A stock solution containing Mn2+ ions was prepaned...Ch. 4 - On the basis of the general solubility rules given...Ch. 4 - On the basis of the general solubility rules given...Ch. 4 - When the following solutions are mixed together,...Ch. 4 - When the following solutions are mixed together,...Ch. 4 - For the reactions in Exercise 47, write the...Ch. 4 - For the reactions in Exercise 48, write the...Ch. 4 - Write the balanced formula and net ionic equation...Ch. 4 - Give an example how each of the following...Ch. 4 - Write net ionic equations for the reaction, if...Ch. 4 - Write net ionic equations for the reaction, if...Ch. 4 - Separate samples of a solution of an unknown...Ch. 4 - A sample may contain any or all of the following...Ch. 4 - What mass of Na2CrO4 is required to precipitate...Ch. 4 - What volume of 0.100 M Na3PO4 is required to...Ch. 4 - What mass of iron(III) hydroxide precipitate can...Ch. 4 - What mass of silver chloride can be prepared by...Ch. 4 - A 100.0-mL aliquot of 0.200 M aqueous potassium...Ch. 4 - A 1.42-g sample of a pure compound, with formula...Ch. 4 - You are given a 1.50-g mixture of sodium nitrate...Ch. 4 - Write the balanced formula, complete ionic, and...Ch. 4 - Write the balanced formula, complete ionic, and...Ch. 4 - Write the balanced formula equation for the...Ch. 4 - Prob. 68ECh. 4 - What volume of each of the following acids will...Ch. 4 - Prob. 70ECh. 4 - Hydrochloric acid (75.0 mL of 0.250 M) is added to...Ch. 4 - A student mixes four reagents together, thinking...Ch. 4 - A 25.00-mL sample of hydrochloric acid solution...Ch. 4 - A 10.00-mL sample of vinegar, an aqueous solution...Ch. 4 - What volume of 0.0200 M calcium hydroxide is...Ch. 4 - A 30.0-mL sample of an unknown strong base is...Ch. 4 - A student titrates an unknown amount of potassium...Ch. 4 - The concentration of a certain sodium hydroxide...Ch. 4 - Assign oxidation states for all atoms in each of...Ch. 4 - Assign the oxidation state for nitrogen in each of...Ch. 4 - Assign oxidatioo numbers to all the atoms in each...Ch. 4 - Specify which of the following are...Ch. 4 - Specify which of the following equations represent...Ch. 4 - Consider the reaction between sodium metal and...Ch. 4 - Consider the reaction between oxygen (O2) gas and...Ch. 4 - Balance each of the following oxidationreduction...Ch. 4 - Balance each of the following oxidationreduction...Ch. 4 - You wish to prepare 1 L of a 0.02-M potassium...Ch. 4 - The figures below are molecular-level...Ch. 4 - Prob. 91AECh. 4 - Prob. 92AECh. 4 - Using the general solubility rules given in Table...Ch. 4 - Consider a 1.50-g mixture of magnesium nitrate and...Ch. 4 - A 1.00-g sample of an alkaline earth metal...Ch. 4 - A mixture contains only NaCl and Al2(SO4)3. A...Ch. 4 - A mixture contains only NaCl and Fe(NO3)3. 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Solution...
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