Laboratory Manual Chemistry in Context
8th Edition
ISBN: 9780073518121
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 3.8, Problem 3.20CT
Interpretation Introduction
Interpretation:
The level of methane is reduced in recent years or not have to be given.
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It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
▸ View Available Hint(s)
VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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Previous Answers
?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
Chapter 3 Solutions
Laboratory Manual Chemistry in Context
Ch. 3.1 - Prob. 3.3YTCh. 3.1 - You Decide Evaporating Coal Mines Writing in the...Ch. 3.2 - Prob. 3.6SCCh. 3.3 - Prob. 3.9YTCh. 3.4 - Prob. 3.10CTCh. 3.6 - Skill Building Isotopes of Nitrogen Nitrogen (N2)...Ch. 3.6 - You Decide Marshmallows and Pennies Avogadros...Ch. 3.7 - You Decide Checking Carbon from Cars A...Ch. 3.8 - Prob. 3.19YTCh. 3.8 - Prob. 3.20CT
Ch. 3.8 - Prob. 3.21CTCh. 3.9 - Prob. 3.22CTCh. 3.9 - Prob. 3.23YTCh. 3.9 - Prob. 3.24CTCh. 3.10 - Prob. 3.26CTCh. 3.10 - Prob. 3.27CTCh. 3.11 - Prob. 3.29CTCh. 3.11 - Prob. 3.30YTCh. 3.11 - Prob. 3.31YTCh. 3.11 - Prob. 3.32CTCh. 3.11 - You Decide Climate Change Insurance? Mitigation of...Ch. 3.11 - Prob. 3.34SCCh. 3.11 - Prob. 3.35CTCh. 3 - Prob. 3.1CTCh. 3 - The chapter concluded with a quote from John...Ch. 3 - Prob. 2QCh. 3 - Prob. 3QCh. 3 - Prob. 5QCh. 3 - a. It is estimated that 29 megajoules per square...Ch. 3 - Consider Figure 4.23. a. How does the present...Ch. 3 - Understanding Earths energy balance is essential...Ch. 3 - Explain each of these observations. a. A car...Ch. 3 - Prob. 10QCh. 3 - Draw the Lewis structure and name the molecular...Ch. 3 - Draw the Lewis structure and name the molecular...Ch. 3 - a. Draw the Lewis structure for methanol (wood...Ch. 3 - a. Draw the Lewis structure for ethene (ethylene),...Ch. 3 - Prob. 15QCh. 3 - Prob. 16QCh. 3 - Prob. 17QCh. 3 - Prob. 18QCh. 3 - Termites possess enzymes that allow them to break...Ch. 3 - Consider Figure 4.4. a. Which sector has the...Ch. 3 - Silver has an atomic number of 47. a. Give the...Ch. 3 - Silver only has two naturally occurring isotopes:...Ch. 3 - a. Calculate the average mass in grams of an...Ch. 3 - Prob. 24QCh. 3 - Prob. 25QCh. 3 - The total mass of carbon in living systems is...Ch. 3 - Prob. 27QCh. 3 - Prob. 28QCh. 3 - Prob. 29QCh. 3 - Prob. 30QCh. 3 - The Arctic has been called our canary in the coal...Ch. 3 - Do you think the comment made in the cartoon is...Ch. 3 - Prob. 33QCh. 3 - Prob. 34QCh. 3 - Over the last 20 years, about 120 billion tons of...Ch. 3 - Prob. 36QCh. 3 - Prob. 37QCh. 3 - Prob. 38QCh. 3 - Ethanol, C2H5OH, can be produced from sugars and...Ch. 3 - Prob. 40QCh. 3 - Prob. 41QCh. 3 - Prob. 42QCh. 3 - Prob. 43QCh. 3 - Prob. 44QCh. 3 - Prob. 45QCh. 3 - Prob. 46QCh. 3 - Prob. 47QCh. 3 - Prob. 48QCh. 3 - Prob. 49QCh. 3 - Prob. 50QCh. 3 - Former vice president Al Gore writes in his 2006...Ch. 3 - Prob. 52QCh. 3 - Prob. 53QCh. 3 - Data taken over time reveal an increase in CO2 in...Ch. 3 - In the energy industry, 1 standard cubic foot...Ch. 3 - Prob. 56QCh. 3 - A solar oven is a low-tech, low-cost device for...Ch. 3 - In 2005, the European Union adopted a...Ch. 3 - The world community responded differently to the...
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- 5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forwardThe mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward
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