Essential University Physics
4th Edition
ISBN: 9780134988566
Author: Wolfson, Richard
Publisher: Pearson Education,
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Question
Chapter 35, Problem 22E
To determine
The system’s classical oscillation frequency.
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Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt
= 41°C. Reversible melting experiments indicate that
at Tm
AHm=37.7 kJ mol-1. Calculate:
A. The entropy of melting, ASm-
B. The Gibbs free energy of melting, AGm-
C. Does the membrane become more or less ordered upon melting?
D. There are 32 rotatable CH2
CH2 bonds in each molecule that can rotate more freely if the
membrane melts. What is the increase in multiplicity on melting a mole of bonds?
5. Heat capacity often has a temperature dependence for real molecules, particularly if
you go over a large temperature range. The heat capacity for liquid n-butane can be
fit to the equation
Cp(T) = a + bT
where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K)
to its boiling point (T₁ = 270 K).
A. Compute AH for heating butane from 170 K to 270 K.
B. Compute AS for the same temperature range.
4. How much energy must be transferred as heat to cause the quasi-static isothermal
expansion of one mole of an ideal gas at 300 K from PA = 1 bar to PB = 0.5 bar?
A. What is VA?
B. What is VB?
C. What is AU for the process?
D. What is AH for the process?
E. What is AS for the process?
Chapter 35 Solutions
Essential University Physics
Ch. 35.1 - Prob. 35.1GICh. 35.2 - Prob. 35.2GICh. 35.3 - Prob. 35.3GICh. 35.3 - Prob. 35.4GICh. 35.3 - Prob. 35.5GICh. 35.4 - Prob. 35.6GICh. 35 - Prob. 1FTDCh. 35 - Prob. 2FTDCh. 35 - Prob. 3FTDCh. 35 - Prob. 4FTD
Ch. 35 - Prob. 5FTDCh. 35 - Prob. 6FTDCh. 35 - Prob. 7FTDCh. 35 - What did Einstein mean by his re maxi, loosely...Ch. 35 - Prob. 9FTDCh. 35 - Prob. 11ECh. 35 - Prob. 12ECh. 35 - Prob. 13ECh. 35 - Prob. 14ECh. 35 - Prob. 15ECh. 35 - Prob. 16ECh. 35 - Prob. 17ECh. 35 - Prob. 18ECh. 35 - Prob. 19ECh. 35 - Prob. 20ECh. 35 - Prob. 21ECh. 35 - Prob. 22ECh. 35 - Prob. 23ECh. 35 - Prob. 24ECh. 35 - Prob. 28ECh. 35 - Prob. 29ECh. 35 - Prob. 30ECh. 35 - Prob. 31ECh. 35 - Prob. 32ECh. 35 - Prob. 33ECh. 35 - Prob. 34ECh. 35 - Prob. 35ECh. 35 - Prob. 36PCh. 35 - Prob. 37PCh. 35 - Prob. 38PCh. 35 - Prob. 39PCh. 35 - Prob. 40PCh. 35 - Prob. 41PCh. 35 - Prob. 42PCh. 35 - Prob. 43PCh. 35 - Prob. 44PCh. 35 - Prob. 45PCh. 35 - Prob. 46PCh. 35 - Prob. 47PCh. 35 - Prob. 48PCh. 35 - Prob. 49PCh. 35 - Prob. 50PCh. 35 - Prob. 51PCh. 35 - Prob. 52PCh. 35 - Prob. 53PCh. 35 - Prob. 54PCh. 35 - Prob. 55PCh. 35 - Prob. 56PCh. 35 - Prob. 57PCh. 35 - Prob. 58PCh. 35 - Prob. 59PCh. 35 - Prob. 60PCh. 35 - Prob. 61PCh. 35 - Prob. 62PPCh. 35 - Prob. 63PPCh. 35 - Prob. 64PPCh. 35 - Prob. 65PP
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