GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
10th Edition
ISBN: 9781260699227
Author: Denniston
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 3.4, Problem 3.9Q

(a)

Interpretation Introduction

Interpretation:

The molecule given is polar or not has to be predicted, if it is polar by using a vector the direction in the electrons are pulled has to be indicated.

(a)

Expert Solution
Check Mark

Explanation of Solution

The given molecule is CS2.

The geometry of the molecule has to be determined first.  To determine the polarity, draw the Lewis structure.

  SkeletalStructureCountValenceElectrons1C×4e-=4e-S  CS2S×6e-=12e-------------------16e-

Distribute valence electron:

    GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  1

Vectors can be used to determine the polarity of this compound.  The vectors should point in the direction of each electronegative sulfur atom.  Since the dipole moment cancels each other, the molecule is not polar.

    GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The molecule NF3 is polar or not has to be predicted, if it is polar by using a vector the direction in the electrons are pulled has to be indicated.

(b)

Expert Solution
Check Mark

Explanation of Solution

The given molecule is NF3.

The geometry of the molecule has to be determined first.  To determine the polarity, draw the Lewis structure.

  SkeletalStructureCountValenceElectrons1N×5e-=5e-FNF3F×7e-=21e-F------------------26e-

Distribute valence electron:

    GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  3

Vectors can be used to determine the polarity of this compound.  The vectors should point in the direction of electronegative fluorine atom.  The given compound is polar.

    GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The molecule given is polar or not has to be predicted, if it is polar by using a vector the direction in the electrons are pulled has to be indicated.

(c)

Expert Solution
Check Mark

Explanation of Solution

The given molecule is HCl.

The geometry of the molecule has to be determined first.  To determine the polarity, draw the Lewis structure.

  SkeletalStructureCountValenceElectrons1H×1e-=1e-HCl1Cl×7e-=7e-------------------8e-

Distribute valence electron:

    GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  5

The given molecule is polar because there is an electronegativity difference between two atoms.

GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  6

(d)

Interpretation Introduction

Interpretation:

The molecule given is polar or not has to be predicted, if it is polar by using a vector the direction in the electrons are pulled has to be indicated.

(d)

Expert Solution
Check Mark

Explanation of Solution

The given molecule is SiCl4.

The geometry of the molecule has to be determined first.  To determine the polarity, draw the Lewis structure.

  SkeletalStructureCountValenceElectronsCl1S×6e-=6e-ClSi  Cl4Cl×7e-=28e-Cl------------------34e-

Distribute valence electron:

    GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  7

Vectors can be used to determine the polarity of this compound.  The vectors should point in the direction of each electronegative chlorine atom.  Since the dipole moment cancels each other, the molecule is non-polar.

    GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG  , Chapter 3.4, Problem 3.9Q , additional homework tip  8

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Chapter 3 Solutions

GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG

Ch. 3.2 - Prob. 3.9PPCh. 3.4 - Prob. 3.10PPCh. 3.4 - Prob. 3.11PPCh. 3.4 - Prob. 3.12PPCh. 3.4 - Prob. 3.13PPCh. 3.4 - Prob. 3.3QCh. 3.4 - Prob. 3.4QCh. 3.4 - Prob. 3.14PPCh. 3.4 - Prob. 3.5QCh. 3.4 - Prob. 3.6QCh. 3.4 - Prob. 3.16PPCh. 3.4 - Prob. 3.7QCh. 3.4 - Prob. 3.8QCh. 3.4 - Prob. 3.9QCh. 3 - Prob. 3.13QPCh. 3 - Draw the appropriate Lewis symbol for each of the...Ch. 3 - Draw the appropriate Lewis symbol for each of the...Ch. 3 - Prob. 3.16QPCh. 3 - Describe the differences between covalent bonding...Ch. 3 - Describe the difference between nonpolar covalent...Ch. 3 - What is the periodic trend of electronegativity? Ch. 3 - What role does electronegativity play in...Ch. 3 - Use electronegativity values to classify the bonds...Ch. 3 - Use electronegativity values to classify the bonds...Ch. 3 - When there is a reaction between each of these...Ch. 3 - Prob. 3.24QPCh. 3 - Explain, using Lewis symbols and the octet rule,...Ch. 3 - Explain, using Lewis symbols and the octet rule,...Ch. 3 - Prob. 3.27QPCh. 3 - Prob. 3.28QPCh. 3 - Name each of the following ions: Na+ Cu+ Mg2+ Ch. 3 - Name each of the following ions: Cu2+ Fe2+ Fe3+ Ch. 3 - Name each of the following ions: HCO3– H3O+ CO32− Ch. 3 - Prob. 3.32QPCh. 3 - Prob. 3.33QPCh. 3 - Write the formula for each of the following...Ch. 3 - Prob. 3.35QPCh. 3 - Prob. 3.36QPCh. 3 - Prob. 3.37QPCh. 3 - Predict the formula of a compound formed...Ch. 3 - Prob. 3.39QPCh. 3 - Prob. 3.40QPCh. 3 - Prob. 3.41QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Prob. 3.43QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Prob. 3.45QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Write a suitable formula for: sodium...Ch. 3 - Write a suitable formula for: aluminum...Ch. 3 - Prob. 3.49QPCh. 3 - Prob. 3.50QPCh. 3 - Prob. 3.51QPCh. 3 - Prob. 3.52QPCh. 3 - Write a suitable formula for: silicon...Ch. 3 - Prob. 3.54QPCh. 3 - Contrast ionic and covalent compounds with respect...Ch. 3 - Prob. 3.56QPCh. 3 - Prob. 3.57QPCh. 3 - Prob. 3.58QPCh. 3 - Prob. 3.59QPCh. 3 - Prob. 3.60QPCh. 3 - Prob. 3.61QPCh. 3 - Prob. 3.62QPCh. 3 - Prob. 3.63QPCh. 3 - Prob. 3.64QPCh. 3 - Prob. 3.65QPCh. 3 - Prob. 3.66QPCh. 3 - How is the positive charge of a polyatomic cation...Ch. 3 - Prob. 3.68QPCh. 3 - Prob. 3.69QPCh. 3 - Prob. 3.70QPCh. 3 - Prob. 3.71QPCh. 3 - Prob. 3.72QPCh. 3 - Prob. 3.73QPCh. 3 - Prob. 3.74QPCh. 3 - Prob. 3.75QPCh. 3 - Prob. 3.76QPCh. 3 - Prob. 3.77QPCh. 3 - Prob. 3.78QPCh. 3 - Prob. 3.79QPCh. 3 - Prob. 3.80QPCh. 3 - Prob. 3.81QPCh. 3 - Prob. 3.82QPCh. 3 - Prob. 3.83QPCh. 3 - Prob. 3.84QPCh. 3 - Prob. 3.85QPCh. 3 - Prob. 3.86QPCh. 3 - Prob. 3.87QPCh. 3 - Prob. 3.88QPCh. 3 - Prob. 3.89QPCh. 3 - Prob. 3.90QPCh. 3 - Prob. 3.91QPCh. 3 - Prob. 3.93QPCh. 3 - Prob. 3.94QPCh. 3 - Prob. 3.95QPCh. 3 - Prob. 3.96QPCh. 3 - Prob. 3.97QPCh. 3 - Prob. 3.98QPCh. 3 - Prob. 3.99QPCh. 3 - Prob. 3.100QPCh. 3 - Prob. 3.101QPCh. 3 - Prob. 3.102QPCh. 3 - Prob. 3.103QPCh. 3 - Prob. 3.104QPCh. 3 - Prob. 3.107QPCh. 3 - Prob. 3.108QPCh. 3 - Prob. 3.109QPCh. 3 - Prob. 3.110QPCh. 3 - Prob. 3.112QPCh. 3 - Prob. 1MCPCh. 3 - Prob. 2MCPCh. 3 - Prob. 3MCPCh. 3 - Prob. 4MCPCh. 3 - Prob. 5MCPCh. 3 - Prob. 6MCPCh. 3 - Prob. 7MCPCh. 3 - Prob. 8MCPCh. 3 - Prob. 9MCPCh. 3 - Prob. 10MCP
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