
Study Guide for Chemistry: The Central Science
14th Edition
ISBN: 9780134554075
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, James C. Hill
Publisher: PEARSON
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Question
Chapter 3.4, Problem 3.8.1PE
Interpretation Introduction
Interpretation:
The
Concept introduction:
The number of atoms of sulfur in the given sample is calculated by using the formula,
(a)
To determine:
The number of sulfur atoms in the sample containing
Interpretation Introduction
(b)
To determine:
The number of sulfur atoms in the sample containing
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
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HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 3 Solutions
Study Guide for Chemistry: The Central Science
Ch. 3.1 - In the following diagram, the white spheres...Ch. 3.1 - In the following digram, the white spheres...Ch. 3.1 - The unbalanced equation for the reaction between...Ch. 3.1 - Balance these equations by providing the missing...Ch. 3.2 - Which of the following reactions is the balanced...Ch. 3.2 - Write a balanced equation for (a) solid...Ch. 3.2 - Write the balanced equation for the reaction that...Ch. 3.2 - Prob. 3.4.2PECh. 3.3 - Which of the following is the correct formula...Ch. 3.3 - Prob. 3.5.2PE
Ch. 3.3 - What is the percentage of nitrogen, by mass, in...Ch. 3.3 - Calculate the percentage of potassium by mass in...Ch. 3.4 - Which of the following samples contains the fewest...Ch. 3.4 - Without using a calculator, arrange these samples...Ch. 3.4 -
How many sulfur are in (a) 0.45 mol BaSo4 and (b)...Ch. 3.4 -
How many oxygen atoms are in (a) 0.25 mol...Ch. 3.4 - A sample of an ionic compound containing iron and...Ch. 3.4 - Calculate the molar mass of Ca(NO3)2Ch. 3.4 - A 508-g sample of sodium bicarbonate (NaHCO3)...Ch. 3.4 - Prob. 3.10.2PECh. 3.4 - What is the mass, in grams, of 6.33 mol of NaHC03...Ch. 3.4 - What is the mass, in grams, of (a) 0.50 mol of...Ch. 3.4 - How many chlorine atoms are in 12.2 g of CCL4? a....Ch. 3.4 -
a. How many nitric acid molecules are in 4.20 g...Ch. 3.5 - A 2.144-g sample of phosgene, a compound used as a...Ch. 3.5 - A 5.325-g sample of methyl benzoate, a compound...Ch. 3.5 -
Cyclohexane a commonly used organic solvent, is...Ch. 3.5 - Prob. 3.14.2PECh. 3.5 -
The compound dioxane, which is used as a solvent...Ch. 3.5 -
a. Caproic acid, responsible for the odor of...Ch. 3.6 - Sodium hydroxide reacts with carbon dioxide to...Ch. 3.6 - Decomposition of KCIO3 is sometimes used to...Ch. 3.6 - Propane, C3 H8 (Figure 3.8), is a common fuel used...Ch. 3.6 -
Methanol, CH3OH, reacts with oxygen from air in a...Ch. 3.7 - When 24 mol of methanol and 15 mol of oxygen...Ch. 3.7 - a. When 1.50 mol of Al and 3.00 mol of Cl2 combine...Ch. 3.7 - Molten gallium reacts with arsenic to form the...Ch. 3.7 -
When a 2.00-g strip of zinc metal is placed in...Ch. 3.7 - If 3.00 g of titanium metal is reacted with 6.00 g...Ch. 3.7 - Imagine you are working on ways to improve the...Ch. 3 - The reaction between reactant A (blue spheres) and...Ch. 3 - The following diagram shows the combination...Ch. 3 -
3.3 The following diagram represents the...Ch. 3 -
3.4 The following diagram represents the...Ch. 3 - Glycine, an amino acid used by organisms to make...Ch. 3 - The following diagram represents a...Ch. 3 -
3.7 Nitrogen (N2) and hydrogen (H2) react to form...Ch. 3 -
3.8 Nitrogen monoxide and oxygen react to form...Ch. 3 - Write "true" or "false" for each statement. a. We...Ch. 3 - A key step in balancing chemical equations is...Ch. 3 - Balance the following equations: a. CO(g)...Ch. 3 - Balance the following equations 3. Li(s) + N2(g)...Ch. 3 -
3.13 Balance the following equations:
A14C3(s) +...Ch. 3 -
3.14 Balance the following equations:
a. Ca3P2(s)...Ch. 3 -
3.15 Write balanced chemical equations...Ch. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 -
318
a. When a compound containing C, H, and O is...Ch. 3 - Write a balanced chemical equation for the...Ch. 3 -
3.20 Write a balanced chemical equation for the...Ch. 3 - Balance the following equations and indicate...Ch. 3 - Balance the following equations and indicate...Ch. 3 - Determine the formula weights of each of the...Ch. 3 - 3.24 Determine the formula weights of each of the...Ch. 3 - Calculate the percentage by mass of oxygen in the...Ch. 3 - Calculate the percentage by mass of the indicated...Ch. 3 - Based on the following structural formulas,...Ch. 3 - Calculate the percentage of carbon by mass In each...Ch. 3 - Write "true' or 'Yalse' for each statement a- A...Ch. 3 - a. What is the mass, in grams, of one mole of 12C?...Ch. 3 - Without doing any detailed calculations (but using...Ch. 3 - Without doing any detailed calculations {but using...Ch. 3 - What is the mass, m Iqlograms, of an Avogadro“s...Ch. 3 - If Avogadro’s number of pennies is divided equally...Ch. 3 - Calculate the following quantities: a. mass, in...Ch. 3 - Calculate the following quantities: a. mass, in...Ch. 3 - a. What is the mass, in grams, of 2.50 x 10-3 mol...Ch. 3 - a. What is the mass, in grams, of 1.223 mol of...Ch. 3 -
339 The molecular formula of allicin, the...Ch. 3 -
3.40 The molecular formula of aspartame, the...Ch. 3 -
3.41 A sample of glucose, C6H12O6, contains 1.250...Ch. 3 - A sample of the male sex hormone testosterone,...Ch. 3 -
343 The allowable concentration level of vinyl...Ch. 3 - At least 25 g oftetrahydrocannabinol (THC), the...Ch. 3 - Give the empirical formula of each of the...Ch. 3 - Determine the empirical formula of each of the...Ch. 3 - Determine the empirical formulas of the compounds...Ch. 3 - Determine the empirical formulas of the compounds...Ch. 3 -
3.49 A compound whose empirical formula is XF3...Ch. 3 - The compound XCL4contains 75.0% CI by mass What is...Ch. 3 -
3.51 What is the molecular formula of each of the...Ch. 3 - What is the molecular formula of each of the...Ch. 3 - Determine the empirical and molecular formulas of...Ch. 3 - Determine the empirical and molecular formulas of...Ch. 3 - a. Combustion analysis of toluene, a common...Ch. 3 - a. The characteristic odor of pineapple is due to...Ch. 3 -
3.57 Valproic acid, used to treat seizures and...Ch. 3 - Propenoic acid, C3H4O2, is a reactive organic...Ch. 3 -
3.59 Washing soda, a compound used to prepare...Ch. 3 -
3.60 Epsom salts, a strong laxative used in...Ch. 3 - f 3461 Hydrofluoric acid, HF(aq), cannot be stored...Ch. 3 - The reaction between potassium superoxide, KO2,...Ch. 3 -
3,63 Several brands of antacids use Al(OH)3 to...Ch. 3 -
3.64 An iron ore sample contains Fe2O3 together...Ch. 3 - Aluminum sulfides reacts with water to form...Ch. 3 - Calcium hydride reacts with water to form calcium...Ch. 3 -
3.67 Automotive air bags infilate when sodium...Ch. 3 - The complete combustion of octane, Cngs, a...Ch. 3 -
3.69 A piece of aluminum foil 1.00 cm2 and...Ch. 3 - Detonation of nitroglycerin proceeds as follows:...Ch. 3 -
3.71 The combustion of one mole of liquid...Ch. 3 - The combustion of one mole of liquid octane,...Ch. 3 - a. Define the terms limiting reactant and excess...Ch. 3 - Define the terms theoretical yield, actual yield,...Ch. 3 -
3-75 Consider the mixture of ethanol, C2H5OH, and...Ch. 3 - Consider the mixture of propane, C3H8, and O2...Ch. 3 -
3-77 Sodium hydroxide reacts with carbon doxidc...Ch. 3 -
3.78 Aluminum hydroxide reacts with sulfuric acid...Ch. 3 - The fizz produced when an Alka-Seltzer tablet is...Ch. 3 - One of the steps in the commercial procas for...Ch. 3 - Solutions of sodium carbonate and silver nitrate...Ch. 3 - Solutions of sulfuric acid and Iead (ll) acetate...Ch. 3 - When benzene (C6H6) reacts with bromine (Br2),...Ch. 3 - When ethane (C6H6) reacts with chlorine (Cl2), the...Ch. 3 -
3.85 Hydrogen sulfide is an impurity in natural...Ch. 3 -
386 When hydrogen sulfide gas is bubbled into a...Ch. 3 -
387 Write the balanced chemical equations for
a....Ch. 3 - If 1.5 mol C2H5OH, 1.5 mol C3H8, and 1.5 mol...Ch. 3 -
3.89 The effectiveness of nitrogen fertilizers...Ch. 3 -
3.90
a. The molecular formula of acetylsalicylic...Ch. 3 - Very small semiconductor crystals, composed of...Ch. 3 - a. One molecule of the antibiotic penicillin G has...Ch. 3 - Serotonin is a compound that conducts nerve...Ch. 3 -
3.94 The koala dines exclusively on eucalyptus...Ch. 3 -
3.95 Vanillin, the dominant flavoring in vanilla,...Ch. 3 -
3.96 An organic compound was found to contain...Ch. 3 -
3.97 A compound, KBrO,, where x is unknown, is...Ch. 3 - 398 An element X forms an iodide (X13) and a...Ch. 3 - A method used by the U.S. Environmental Protection...Ch. 3 -
3.100 A chemical plant uses electrical energy to...Ch. 3 - The fat stored in a camel’s hump is a source of...Ch. 3 -
3.102 When hydrocarbons are burned in a limited...Ch. 3 -
3.103 A mixture of N2(g) and H2(g) reacts in a...Ch. 3 -
3.104 A mixture containing KClO3, K2CO3, KHCO3,...Ch. 3 - When a mixture of 10.0 g of acetylene (C2H2) and...Ch. 3 -
3.106 The semiconductor gallium arsenide, GaAs,...Ch. 3 -
3.107 Paclitaxel, C47H51NO14, is an anticancer...Ch. 3 -
3.108 Consider a sample of calcium carbonate in...Ch. 3 -
3.109
a. You are given a cube of silver metal...Ch. 3 -
3.110
a. If an automobile travels 225 mi with a...Ch. 3 - Prob. 111IECh. 3 -
3.112 A particular coal contains 2.596 sulfur by...Ch. 3 - Hydrogen cyanide, HCN, is a poisonous gas. The...Ch. 3 -
3.114 The source of oxygen that drives he...Ch. 3 -
3.115 The therrnite reaction, Fe2O3 +Al Al2O3 +...Ch. 3 -
3.116 One of the most bizarre reactions in...
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- calculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forwardtrue or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forward
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