Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
5th Edition
ISBN: 9781260170405
Author: SMITH
Publisher: MCG
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Chapter 30, Problem 30.58P
Melmac, a thermosetting
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Poly(vinyl alcohol) is a polymer used to make fibers and adhesives. It is synthesized by hydrolysis or alcoholysis of the polymer obtained from polymerization of vinyl acetate as shown below. a. Why is poly(vinyl alcohol) not prepared by polymerizing vinyl alcohol? b. Is poly(vinyl acetate) a polyester?
What polymer is formed when methyl α-methylacrylate [CH 2 C(CH 3)CO2CH 3] is polymerized? This polymer is used in Lucite and Plexiglas, transparent materials that are lighter but more impact resistant than glass.
Identify the class of polymer for each structure.
Doct
Structure A:
Structure A is a:
O polycarbonate
polyester
O polyurethane
O polyamide
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Structure B:
Structure B is a:
CH3
O polycarbonate
O polyurethane
polyamide
O polyester
Chapter 30 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
Ch. 30 - Prob. 30.1PCh. 30 - Prob. 30.2PCh. 30 - Prob. 30.3PCh. 30 - Draw the mechanism for the radical polymerization...Ch. 30 - Prob. 30.5PCh. 30 - Prob. 30.6PCh. 30 - Prob. 30.7PCh. 30 - Prob. 30.8PCh. 30 - Prob. 30.9PCh. 30 - Prob. 30.10P
Ch. 30 - Prob. 30.11PCh. 30 - Problem 30.12
What polymer is formed by anionic...Ch. 30 - Prob. 30.13PCh. 30 - Prob. 30.14PCh. 30 - Problem 30.15
What polyamide is formed from each...Ch. 30 - Prob. 30.16PCh. 30 - Prob. 30.17PCh. 30 - Prob. 30.18PCh. 30 - Prob. 30.19PCh. 30 - Prob. 30.20PCh. 30 - Prob. 30.21PCh. 30 - Prob. 30.22PCh. 30 - Prob. 30.23PCh. 30 - Prob. 30.24PCh. 30 - Prob. 30.25PCh. 30 - 30.26 Draw the structure of the polymer formed by...Ch. 30 - Prob. 30.27PCh. 30 - Prob. 30.28PCh. 30 - Prob. 30.29PCh. 30 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 30 - Prob. 30.31PCh. 30 - Prob. 30.32PCh. 30 - Prob. 30.33PCh. 30 - Prob. 30.34PCh. 30 - Prob. 30.35PCh. 30 - Prob. 30.36PCh. 30 - Prob. 30.37PCh. 30 - Prob. 30.38PCh. 30 - 30.39 Draw a stepwise mechanism for the...Ch. 30 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 30 - Prob. 30.41PCh. 30 - Prob. 30.42PCh. 30 - 30.43 Although styrene undergoes both cationic and...Ch. 30 - 30.44 Rank the following compounds in order of...Ch. 30 - Prob. 30.45PCh. 30 - Prob. 30.46PCh. 30 - 30.47 Draw a stepwise mechanism for the following...Ch. 30 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 30 - 30.49 Draw the products of each reaction.
a. e....Ch. 30 - Prob. 30.50PCh. 30 - Prob. 30.51PCh. 30 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 30 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 30 - Prob. 30.54PCh. 30 - Prob. 30.55PCh. 30 - 30.56 Compound A is a novel poly (ester amide)...Ch. 30 - 30.57 Researchers at Rutgers University have...Ch. 30 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 30 - 30.59 Although chain branching in radical...Ch. 30 - Prob. 30.60P
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- Nomex, another aromatic polyamide (compare aramid), is prepared by polymerization of 1,3-benzenediamine and the diacid chloride of 1,3-benzenedicarboxylic acid. The physical properties of the polymer make it suitable for high-strength, high-temperature applications such as parachute cords and jet aircraft tires. Draw a structural formula for the repeating unit of Nomex. H,N. NH2 CI polymerization Nomex 1,3-Benzenediamine 1,3-Benzene- dicarbonyl chloridearrow_forward12 Draw the structure of polymer formed using the following monomer. `CH=CH2 Give the reagent that can initiate the polymerizationarrow_forwardMelmac, a thermosetting polymer formed from melamine and formaldehyde (CH2 = O), is used to make dishes and countertops. Draw a stepwise mechanism for the condensation of one mole of formaldehyde with two motes of melamine. which begins the synthesis of Melmacarrow_forward
- 5. Ethanedioic (oxalic) acid is found in certain vegetables, such as spinach. Ethane-1,2-diol is a toxic synthetic compound better known as ethylene glycol. 0 0 10-C-C-OH ethanedioic acid OH OH HC-CH ethane-1,2-diol Draw three units of the polymer made from ethanedioic acid and ethane-1,2-diol.arrow_forwardWhat product is formed when attached compound is treated with either Ag2O, NH4OH or Na2Cr2O7, H2SO4, H2O?arrow_forwardA в 00 Give the organic product: Мискориа NaBH4 which ? H+ heat C D OHarrow_forward
- Draw the structures of missing reactant, reagent, or major organic product(s)arrow_forwardHow ethyl isopropyl is prepared ?arrow_forwardAspirin is an anti-inflammatory agent because it inhibits the conversion of arachidonic acid to prostaglandins by the transfer of its acetyl group (CH3CO –) to an OH group at the active site of an enzyme (Section 19.6). This reaction, called transesterification, results in the conversion of one ester to another by a nucleophilic acyl substitution reaction. Draw a stepwise mechanism for the given transesterification.arrow_forward
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