Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 30, Problem 30.11NP

(a)

Interpretation Introduction

Interpretation:The sets have the same energy should be demonstrated.

Concept Introduction:

The formula for calculation total energy is given as:

  E =nεn an ....

Whereas εn is the energy of the nth energy state level.

(b)

Interpretation Introduction

Interpretation:The set which is most probable should be determined

Concept Introduction:Stirling's approximation is an approximate formula, for  n! = 1×2×3× … ×n (n factorial) with weight configuration formula.

Those sets having large value of weight configuration of mass such set is most probable set among all sets.

  W=N!aa! a1.....an!  whereas W is the weight  configuration of mass of set,N is total numbers of oscilator for components and a is occupation number of set configuration.

(c)

Interpretation Introduction

Interpretation: For the most probable set whether the distribution of energy is consistent with the Boltzmann distribution should be determined.

Concept Introduction:

The occupation gap between the energy levels of set C.

  The occupation number is as follows,an=e-PnqWhereas q is the partition function ,an is the occupation number,Pn Probablity of energy levels.

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Г C-RSA CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.0 b.092 0.797 1.088 1.813 C-RSA CHROMATOPAC CH=1 Report No. =13 ** CALCULATION REPORT ** DATA=1: @CHRM1.000 11/03/05 08:09:52 CH PKNO TIME 1 2 0.797 3 1.088 4 1.813 AREA 1508566 4625442 2180060 HEIGHT 207739 701206 V 287554 V MK IDNO CONC NAME 18.1447 55.6339 26.2213 TOTAL 8314067 1196500 100 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0. 0 087 337. 0.841 1.150 C-R8A CHROMATOPAC CH=1 Report No. =14 DATA=1: @CHRM1.000 11/03/05 08:12:40 ** CALCULATION REPORT ** CH PKNO TIME AREA 1 3 0.841 1099933 41.15 4039778 HEIGHT MK IDNO 170372 649997¯¯¯ CONC NAME 21.4007 78.5993 TOTAL 5139711 820369 100 3 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.100 0:652 5.856 3 1.165 C-RSA CHROMATOPAC CH-1 Report No. =15 DATA=1: @CHRM1.000 11/03/05 08:15:26 ** CALCULATION REPORT ** CH PKNO TIME AREA HEIGHT MK IDNO CONC NAME 1 3 3 0.856 4 1.165 TOTAL 1253386 4838738 175481 708024 V 20.5739 79.4261 6092124…

Chapter 30 Solutions

Physical Chemistry

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