Chemistry and Chemical Reactivity - AP Edition
10th Edition
ISBN: 9781337399203
Author: Kotz
Publisher: CENGAGE L
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Chapter 3, Problem 93IL
The Tolien’s test for the presence of reducing sugars (say, in a urine sample) involves treating the sample with silver ions in aqueous ammonia. The result is the formation of a silver mirror within the reaction vessel if a reducing sugar is present. Using glucose, C6H12O6, to illustrate this test, the
C6H12O6 (aq) + 2 Ag+(aq) + 2OH–(aq) → C6H12O7(aq) + 2 Ag(s) + H2O(ℓ) What has been oxidized, and what has been reduced? What is the oxidizing agent, and what is the reducing agent?
Tolien's test. The reaction of silver ions with a sugar such as glucose produces metallic silver. (a) The set-up for the reaction. (b) The silvered test tube
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Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
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Explanation
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2025 McGraw Hill LLC. All Rights Reserved. Ter
Q14. Fill this chart: (please refer to ppt notes/browser to answer these questions)
What alcohol is also called wood alcohol?
What is the common name of ethanol?
Draw the structure of phenol and thiophene?
Are bigger chain alcohol like heptanol and octanol
are soluble or insoluble in water and explain it ?
Are ethers soluble or insoluble in water?
What suffix and prefix are used for alcohol while
naming alcohol and ether?
What the process called when we add water to any
alkene to make alcohol?
Q16. Draw the diagram of following aromatic compound (practice from previous module)
Aniline
Phenol
Benzoic acid
Methyl benzoate
Q17. a. Write the oxidation reactions for the 2 propanol.
b. Write the oxidation reaction of the ethanol.
Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Chapter 3 Solutions
Chemistry and Chemical Reactivity - AP Edition
Ch. 3.2 - (a) Butane gas, C4H10, can burn completely in air...Ch. 3.4 - Predict whether each of the following ionic...Ch. 3.5 - In each of the following cases, does a...Ch. 3.5 - In each of the following cases, aqueous solutions...Ch. 3.6 - Prob. 3.5CYUCh. 3.6 - Prob. 3.6CYUCh. 3.7 - Prob. 3.7CYUCh. 3.8 - Assign an oxidation number to the underlined atom...Ch. 3.8 - Prob. 3.9CYUCh. 3.9 - Prob. 3.10CYU
Ch. 3.9 - Prob. 1.1ACPCh. 3.9 - Prob. 1.2ACPCh. 3.9 - Prob. 1.3ACPCh. 3.9 - Prob. 1.4ACPCh. 3.9 - Prob. 1.5ACPCh. 3.9 - Prob. 2.1ACPCh. 3.9 - Prob. 2.2ACPCh. 3.9 - Prob. 3.1ACPCh. 3.9 - Prob. 3.2ACPCh. 3 - The equation for the oxidation of phosphorus in...Ch. 3 - Write an equation from the following description:...Ch. 3 - The equation for the reaction of phosphorus and...Ch. 3 - The equation for the reaction of aluminum and...Ch. 3 - Oxidation of 1.00 g of carbon monoxide, CO,...Ch. 3 - A 0.20 mol sample of magnesium burns in air to...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Prob. 9PSCh. 3 - Prob. 10PSCh. 3 - Prob. 11PSCh. 3 - Balance the following equations, and name each...Ch. 3 - Prob. 13PSCh. 3 - Prob. 14PSCh. 3 - Equal amounts of two acidsHCl and HCO2H (formic...Ch. 3 - Prob. 16PSCh. 3 - What is an electrolyte? How can you differentiate...Ch. 3 - Name and give the formulas of two acids that are...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - Decide whether each of the following is...Ch. 3 - Decide whether each of the following is...Ch. 3 - Balance the equation for the following...Ch. 3 - Balance the equation for the following...Ch. 3 - Predict the products of each precipitation...Ch. 3 - Prob. 28PSCh. 3 - Write a balanced equation for the ionization of...Ch. 3 - Write a balanced equation for the ionization of...Ch. 3 - Prob. 31PSCh. 3 - Phosphoric add can supply one, two, or three H3O+...Ch. 3 - Prob. 33PSCh. 3 - Prob. 34PSCh. 3 - Prob. 35PSCh. 3 - Prob. 36PSCh. 3 - Prob. 37PSCh. 3 - Prob. 38PSCh. 3 - Write an equation that describes the equilibrium...Ch. 3 - Write an equation that describes the equilibrium...Ch. 3 - Prob. 41PSCh. 3 - Write two chemical equations, one in which H2PO4...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Prob. 45PSCh. 3 - Balance each of the following equations, and then...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Siderite is a mineral consisting largely of...Ch. 3 - The mineral rhodothrosite is manganese()...Ch. 3 - Prob. 51PSCh. 3 - Prob. 52PSCh. 3 - Determine the oxidation number of each element in...Ch. 3 - Determine the oxidation number of each element in...Ch. 3 - Prob. 55PSCh. 3 - Which two of the following reactions are...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - Balance the following equations, and then classify...Ch. 3 - Prob. 60PSCh. 3 - Classify each of the following reactions as a...Ch. 3 - Prob. 62PSCh. 3 - Balance each of the following equations, and...Ch. 3 - Complete and balance the equations below, and...Ch. 3 - Prob. 65PSCh. 3 - Prob. 66PSCh. 3 - Balance the following equations: (a) for the...Ch. 3 - Balance the following equations: (a) for the...Ch. 3 - Prob. 69GQCh. 3 - Give the formula for each of the following...Ch. 3 - Prob. 71GQCh. 3 - Name two anions that combine with Al3+ ion to...Ch. 3 - Write the net ionic equation and identify the...Ch. 3 - Identify and name the water-insoluble product in...Ch. 3 - Bromine is obtained from sea water by the...Ch. 3 - Identify each of the blowing substances as a...Ch. 3 - The mineral dolomite contains magnesium...Ch. 3 - Aqueous solutions of ammonium sulfide, (NH4)2S,...Ch. 3 - Prob. 79GQCh. 3 - Prob. 80GQCh. 3 - Balance equations for these reactions that occur...Ch. 3 - Prob. 82GQCh. 3 - You are given mixtures containing the following...Ch. 3 - Identify, from each list below, the compound or...Ch. 3 - Prob. 85GQCh. 3 - Prob. 86GQCh. 3 - Gas evolution was observed when a solution of Na2S...Ch. 3 - Prob. 89ILCh. 3 - Prob. 90ILCh. 3 - Prob. 91ILCh. 3 - A Suggest a laboratory method for preparing barium...Ch. 3 - The Toliens test for the presence of reducing...Ch. 3 - There are many ionic compounds that dissolve in...Ch. 3 - Most naturally occurring acids are weak acids....Ch. 3 - You want to prepare barium chloride, BaC12, using...Ch. 3 - Prob. 97SCQCh. 3 - A Describe how to prepare zinc chloride by (a) an...Ch. 3 - A common method for analyzing for the nickel...Ch. 3 - The presence of arsenic in a sample that may also...
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- Organic Chemistry Esterification reactions 1. Write the steps to prepare ester. 2. Write complete reaction of ethanol and acetic acid to make ester. 3. What does ester smell like? What are the uses of ester. 4. What the role of sulfuric acid in the esterification reactionarrow_forward11. Complete the following esterification reaction with names of all the reactants and products under. Hint: Remove the water and end up with ester R-C-OH + ROH R-C-OR + H₂O A carboxylic acid An alcohol An ester Water BYJU'S H-C-C O-H Нин C-C-C-H HAAA H O-C-C-C-H AAA Ethanoic acid Propanol Water Propyl ethanoate By com CH3COOH + CH3CH2CH2CH₂CH₂OH → Practice for alcohols aldehydes and ketones: 12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone: a. 4-methyl cyclohexanone b. 3-methyl-2-pentenal c. 2,3-dimethylcyclohexanone d. 1,3propanediol or Propane 1,3 diol 13. Write systematic names for the following compounds identify functional group: a. b. (CH3)2CH-C OH c) CH(CH₂)-- OH -,-,arrow_forwardmay you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward
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- Part A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forwardPredict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forward
- b) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forwardDraw the formula of the compound 4-cyclohexyl butanamide?arrow_forward
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