Chemistry: A Molecular Approach, Books a la Carte Edition (4th Edition)
4th Edition
ISBN: 9780134113593
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 3, Problem 80E
(a)
Interpretation Introduction
To write: The ratio of molar amount of each element in the given model.
(b)
Interpretation Introduction
To write: The ratio of molar amount of each element in the given model.
(c)
Interpretation Introduction
To write: The ratio of molar amount of each element in the given model.
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Check out a sample textbook solutionStudents have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 3 Solutions
Chemistry: A Molecular Approach, Books a la Carte Edition (4th Edition)
Ch. 3 - What is the empirical formula of a compound with...Ch. 3 - Prob. 2SAQCh. 3 - Prob. 3SAQCh. 3 - Prob. 4SAQCh. 3 - Prob. 5SAQCh. 3 - Prob. 6SAQCh. 3 - Q7. Name the compound .
a) phosphorus iodide b)...Ch. 3 - Prob. 8SAQCh. 3 - Prob. 9SAQCh. 3 - Prob. 10SAQ
Ch. 3 - Q11. Determine the mass of potassium in 35.5 g of...Ch. 3 - Prob. 12SAQCh. 3 - Prob. 13SAQCh. 3 - Prob. 14SAQCh. 3 - Prob. 15SAQCh. 3 - 1. How do the properties of compounds compare to...Ch. 3 - Prob. 2ECh. 3 - Prob. 3ECh. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Prob. 11ECh. 3 - Prob. 12ECh. 3 - Prob. 13ECh. 3 - Prob. 14ECh. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - Prob. 21ECh. 3 - 22. Write a generic formula for each of the...Ch. 3 - 23. Determine the number of each type of atom in...Ch. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - 26. Write a chemical formula for each molecular...Ch. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - 29. Classify each compound as ionic or...Ch. 3 - 30. Classify each compound as ionic or...Ch. 3 - 31. Based on the molecular views, classify each...Ch. 3 - 32. Based on the molecular views, classify each...Ch. 3 - 33. Write a formula for the ionic compound that...Ch. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - Prob. 37ECh. 3 - 38. Name each ionic compound.
a. SnCl4
b. PbI2
c....Ch. 3 - 39. Give each ionic compound an appropriate...Ch. 3 - 40. Give each ionic compound an appropriate...Ch. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - Prob. 43ECh. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Prob. 46ECh. 3 - Prob. 47ECh. 3 - 48. Name each molecular compound.
a. SO3
b. SO2
c....Ch. 3 - Prob. 49ECh. 3 - 50. Write the formula for each molecular...Ch. 3 - Prob. 51ECh. 3 - 52. Name each acid.
a. HCl(aq)
b. HClO2(aq)
c....Ch. 3 - Prob. 53ECh. 3 - 54. Write the formula for each acid.
a. phosphoric...Ch. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - 58. Refer to the nomenclature flowchart (Figure...Ch. 3 - 59. Calculate the formula mass for each...Ch. 3 - Prob. 60ECh. 3 - 61. Calculate the number of moles in each...Ch. 3 - 62. Calculate the mass of each sample.
a. 15.7 mol...Ch. 3 - 63. Determine the number of moles (of molecules or...Ch. 3 - Prob. 64ECh. 3 - Prob. 65ECh. 3 - 66. How many molecules (or formula units) are in...Ch. 3 - 67. Calculate the mass (in g) of each sample.
a....Ch. 3 - Prob. 68ECh. 3 - 69. A sugar crystal contains approximately 1.8 ×...Ch. 3 - Prob. 70ECh. 3 - 71. Calculate the mass percent composition of...Ch. 3 - Prob. 72ECh. 3 - Prob. 73ECh. 3 - 74. Iron in the earth is in the form of iron ore....Ch. 3 - 75. Copper(II) fluoride contains 37.42% F by mass....Ch. 3 - Prob. 76ECh. 3 - 77. The iodide ion is a dietary mineral essential...Ch. 3 - 78. The American Dental Association recommends...Ch. 3 - 79. Write a ratio showing the relationship between...Ch. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - 84. Calculate the mass (in kilograms) of chlorine...Ch. 3 - Prob. 85ECh. 3 - Prob. 86ECh. 3 - 87. A chemist decomposes samples of several...Ch. 3 - 88. A chemist decomposes samples of several...Ch. 3 - 89. Calculate the empirical formula for each...Ch. 3 - 90. Calculate the empirical formula for each...Ch. 3 - 91. The elemental mass percent composition of...Ch. 3 - 92. The elemental mass percent composition of...Ch. 3 - 93. A 0.77-mg sample of nitrogen reacts with...Ch. 3 - 94. A 45.2-mg sample of phosphorus reacts with...Ch. 3 - 95. From the given empirical formula and molar...Ch. 3 - 96. From the given molar mass and empirical...Ch. 3 - 97. Combustion analysis of a hydrocarbon produces...Ch. 3 - Prob. 98ECh. 3 - Prob. 99ECh. 3 - 100. Tartaric acid is the white, powdery substance...Ch. 3 - Prob. 101ECh. 3 - Prob. 102ECh. 3 - Prob. 103ECh. 3 - 104. When iron rusts, solid iron reacts with...Ch. 3 - Prob. 105ECh. 3 - Prob. 106ECh. 3 - Prob. 107ECh. 3 - 108. Write the balanced chemical equation for each...Ch. 3 - Prob. 109ECh. 3 - Prob. 110ECh. 3 - 111. Balance each chemical equation.
a. CO2(g) +...Ch. 3 - 112. Balance each chemical equation.
a. Na2S(aq) +...Ch. 3 - Prob. 113ECh. 3 - Prob. 114ECh. 3 - Prob. 115ECh. 3 - Prob. 116ECh. 3 - Prob. 117ECh. 3 - Prob. 118ECh. 3 - Prob. 119ECh. 3 - Prob. 120ECh. 3 - 121. How many molecules of ethanol (C2H5OH) (the...Ch. 3 - 122. A drop of water has a volume of approximately...Ch. 3 - 123. Determine the chemical formula of each...Ch. 3 - 124. Determine the chemical formula of each...Ch. 3 - Prob. 125ECh. 3 - Prob. 126ECh. 3 - 127. A metal (M) forms a compound with the formula...Ch. 3 - Prob. 128ECh. 3 - 129. Estradiol is a female sexual hormone that is...Ch. 3 - 130. Fructose is a common sugar found in fruit....Ch. 3 - 131. Combustion analysis of a 13.42-g sample of...Ch. 3 - 132. Estrone, which contains only carbon,...Ch. 3 - 133. Epsom salts is a hydrated ionic compound with...Ch. 3 - 134. A hydrate of copper(II) chloride has the...Ch. 3 - Prob. 135ECh. 3 - Prob. 136ECh. 3 - Prob. 137ECh. 3 - Prob. 138ECh. 3 - Prob. 139ECh. 3 - Prob. 140ECh. 3 - Prob. 141ECh. 3 - 142. A phosphorus compound that contains 34.00%...Ch. 3 - Prob. 143ECh. 3 - 144. Phosphorus is obtained primarily from ores...Ch. 3 - Prob. 145ECh. 3 - Prob. 146ECh. 3 - Prob. 147ECh. 3 - Prob. 148ECh. 3 - 149. Because of increasing evidence of damage to...Ch. 3 - Prob. 150ECh. 3 - 151. Lead is found in Earth's crust as several...Ch. 3 - Prob. 152ECh. 3 - 153. A compound of molar mass 229 g/mol contains...Ch. 3 - Prob. 154ECh. 3 - Prob. 155ECh. 3 - Prob. 156ECh. 3 - 157. When molecules are represented by molecular...Ch. 3 - Prob. 158ECh. 3 - Prob. 159ECh. 3 - Prob. 160ECh. 3 - 161. Without doing any calculations, arrange the...Ch. 3 - Prob. 162ECh. 3 - Prob. 163QGWCh. 3 - Prob. 164QGWCh. 3 - Prob. 165QGWCh. 3 - 166. A compound isolated from the rind of lemons...Ch. 3 - Prob. 167QGWCh. 3 -
168. Since the 1800s, the concentration of carbon...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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