Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 3, Problem 61E
Why does Avogadro’s number have such an odd value? Why not pick a nice round number like
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The data for the potential difference of a battery and its temperature are given in the table. Calculate the entropy change in J mol-1 K-1 (indicate the formulas used).Data: F = 96485 C mol-1
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Using the Arrhenius equation, it is possible to establish the relationship between the rate constant (k) of a chemical reaction and the temperature (T), in Kelvin (K), the universal gas constant (R), the pre-exponential factor (A) and the activation energy (Ea). This equation is widely applied in studies of chemical kinetics, and is also widely used to determine the activation energy of reactions. In this context, the following graph shows the variation of the rate constant with the inverse of the absolute temperature, for a given chemical reaction that obeys the Arrhenius equation. Based on the analysis of this graph and the concepts acquired about the kinetics of chemical reactions, analyze the following statements:
I. The activation energy (Ea) varies with the temperature of the system.
II. The activation energy (Ea) varies with the concentration of the reactants.
III. The rate constant (K) varies proportionally with temperature.
IV. The value of the…
Chapter 3 Solutions
Chemistry In Focus
Ch. 3 - Determining the Number of Protons and Electrons in...Ch. 3 - Prob. 3.2YTCh. 3 - Determining Protons, Neutrons, and Electrons How...Ch. 3 - Calculating Atomic Mass Magnesium has three...Ch. 3 - The Mole Concept A diamond, which is pure carbon,...Ch. 3 - The Mole Concept II Calculate the number of atoms...Ch. 3 - Your friend tells you about an article that he...Ch. 3 - Prob. 2SCCh. 3 - Prob. 3SCCh. 3 - Copper is composed of two naturally occurring...
Ch. 3 - Prob. 5SCCh. 3 - Which pair of elements do you expect to be most...Ch. 3 - Which statement is true of the quantum mechanical...Ch. 3 - Why is it important to understand atoms?Ch. 3 - Prob. 2ECh. 3 - What defines an element? How many naturally...Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Explain the quantum mechanical model for the atom....Ch. 3 - Give two examples of each: a. alkali metal b....Ch. 3 - Which elements exist as diatomic molecules?Ch. 3 - Explain the difference and similarity between...Ch. 3 - Prob. 15ECh. 3 - Determine the charge of each of the following: a...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Give the atomic number (Z) and the mass number (A)...Ch. 3 - Prob. 20ECh. 3 - The following isotopes have applications in...Ch. 3 - The following isotopes are important in nuclear...Ch. 3 - 14C is used in carbon dating of artifacts....Ch. 3 - 40K is used to measure the age of Earth. Determine...Ch. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Give electron configurations according to the Bohr...Ch. 3 - Give electron configurations according to the Bohr...Ch. 3 - Prob. 29ECh. 3 - How many valence electrons are in each element of...Ch. 3 - Prob. 31ECh. 3 - Draw electron configurations for each of the...Ch. 3 - Which two of the following elements would you...Ch. 3 - Group the following elements into three similar...Ch. 3 - We have seen that the reactivity of an element is...Ch. 3 - What is the electron configuration of Mg2+? How...Ch. 3 - Classify each of the following elements as a...Ch. 3 - Classify each of the following as a metal, a...Ch. 3 - Calculate the atomic mass of neon (Ne), which is...Ch. 3 - An element has two naturally occurring isotopes....Ch. 3 - A fictitious element has two naturally occurring...Ch. 3 - Copper has two naturally occurring isotopes. Cu-63...Ch. 3 - How many moles of titanium are present in 124 g of...Ch. 3 - Prob. 44ECh. 3 - How many moles are there in each sample? a. 45 mg...Ch. 3 - How many moles are there in each sample? a. 55.0 g...Ch. 3 - What is the mass of each sample? a.1.8 mol S...Ch. 3 - What is the mass of each sample? a.2.75 mol Fe...Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - How many Ag atoms are present in a piece of pure...Ch. 3 - How many platinum atoms are in a pure platinum...Ch. 3 - A pure gold necklace has a volume of 1.8cm3. How...Ch. 3 - A titanium bicycle component has a volume of...Ch. 3 - An iron sphere has a radius of 3.4 cm. How many...Ch. 3 - Calculate the number of atoms in the universe. The...Ch. 3 - The introduction to this chapter states that...Ch. 3 - Suppose the absolute value of the charge of the...Ch. 3 - When we refer to doughnuts or cookies, we often...Ch. 3 - Prob. 60ECh. 3 - Why does Avogadros number have such an odd value?...Ch. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Here are three fictitious elements and a molecular...Ch. 3 - Prob. 66ECh. 3 - Gather any two of the following items, measure...
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- In an electrolytic cell, indicate the formula that relates E0 to the temperature T.arrow_forward-- 14:33 A Candidate Identification docs.google.com 11. Compound A can transform into compound B through an organic reaction. From the structures below, mark the correct one: HO A تھے۔ די HO B ○ A) Compounds A and B are isomers. B) Both have the same number of chiral carbons. C) Compound A underwent an addition reaction of Cl2 and H2O to form compound B. D) Compound A underwent a substitution reaction forming the intermediate chlorohydrin to obtain compound B. E) Compound A underwent an addition reaction of Cl2 forming the chloronium ion and then added methanol to obtain compound B. 60arrow_forward-- 14:40 A Candidate Identification docs.google.com 13. The compound 1-bromo-hex-2-ene reacts with methanol to form two products. About this reaction, mark the correct statement: OCH3 CH3OH Br OCH3 + + HBr A B A) The two products formed will have the same percentage of formation. B) Product B will be formed by SN1 substitution reaction with the formation of an allylic carbocation. C) Product A will be formed by SN1 substitution reaction with the formation of a more stable carbocation than product B. D) Product A will be formed by an SN2 substitution reaction occurring in two stages, the first with slow kinetics and the second with fast kinetics. E) The two compounds were obtained by addition reaction, with compound B having the highest percentage of formation. 57arrow_forward
- -- ☑ 14:30 A Candidate Identification docs.google.com 10. Amoxicillin (figure X) is one of the most widely used antibiotics in the penicillin family. The discovery and synthesis of these antibiotics in the 20th century made the treatment of infections that were previously fatal routine. About amoxicillin, mark the correct one: HO NH2 H S -N. HO Figura X. Amoxicilina A) It has the organic functions amide, ester, phenol and amine. B) It has four chiral carbons and 8 stereoisomers. C) The substitution of the aromatic ring is of the ortho-meta type. D) If amoxicillin reacts with an alcohol it can form an ester. E) The structure has two tertiary amides. 62arrow_forwardThe environmental police of a Brazilian state received a report of contamination of a river by inorganic arsenic, due to the excessive use of pesticides on a plantation on the riverbanks. Arsenic (As) is extremely toxic in its many forms and oxidation states. In nature, especially in groundwater, it is found in the form of arsenate (AsO ₄ ³ ⁻ ), which can be electrochemically reduced to As ⁰ and collected at the cathode of a coulometric cell. In this case, Potentiostatic Coulometry (at 25°C) was performed in an alkaline medium (pH = 7.5 throughout the analysis) to quantify the species. What potential (E) should have been selected/applied to perform the analysis, considering that this is an exhaustive electrolysis technique (until 99.99% of all AsO ₄ ³ ⁻ has been reduced to As ⁰ at the electrode, or n( final) = 0.01% n( initial )) and that the concentration of AsO ₄ ³ ⁻ found in the initial sample was 0.15 mmol/L ? Data: AsO ₄ 3 ⁻ (aq) + 2 H ₂ O ( l ) + 2 e ⁻ → A s O ₂ ⁻ ( a…arrow_forward-- 14:17 15. Water-soluble proteins are denatured when there is a change in the pH of the environment in which they are found. This occurs due to the protonation and deprotonation of functional groups present in their structure. Choose the option that indicates the chemical bonds modified by pH in the protein represented in the following figure. E CH2 C-OH CH2 H₂C H₁C CH CH3 CH3 CH CH₂-S-S-CH₂- 910 H B -CH2-CH2-CH2-CH₂-NH3* −0—C—CH₂- ○ A) A, C e D. • В) Вес ○ C) DeE ○ D) B, De E ○ E) A, B e C 68arrow_forward
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- Chloroform, long used as an anesthetic and now considered carcinogenic, has a heat of vaporization of 31.4 kJ/mol. During vaporization, its entropy increases by 94.2 J/mol.K. Therefore, select the alternative that indicates the temperature, in degrees Celsius, at which chloroform begins to boil under a pressure of 1 atm. A) 28 B) 40 C) 52 D) 60 E) 72arrow_forwardIf we assume a system with an anodic overpotential, the variation of n as a function of current density: 1. at low fields is linear 2. at higher fields, it follows Tafel's law Obtain the range of current densities for which the overpotential has the same value when calculated for 1 and 2 cases (maximum relative difference of 5% compared to the behavior for higher fields). To which overpotential range does this correspond? Data: i = 1.5 mA cm², T = 300°C, B = 0.64, R = 8.314 J K1 mol-1 and F = 96485 C mol-1.arrow_forwardAnswer by equation pleasearrow_forward
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