Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Textbook Question
Chapter 3, Problem 61E
Why does Avogadro’s number have such an odd value? Why not pick a nice round number like
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
Ar
Chapter 3 Solutions
Chemistry In Focus
Ch. 3 - Determining the Number of Protons and Electrons in...Ch. 3 - Prob. 3.2YTCh. 3 - Determining Protons, Neutrons, and Electrons How...Ch. 3 - Calculating Atomic Mass Magnesium has three...Ch. 3 - The Mole Concept A diamond, which is pure carbon,...Ch. 3 - The Mole Concept II Calculate the number of atoms...Ch. 3 - Your friend tells you about an article that he...Ch. 3 - Prob. 2SCCh. 3 - Prob. 3SCCh. 3 - Copper is composed of two naturally occurring...
Ch. 3 - Prob. 5SCCh. 3 - Which pair of elements do you expect to be most...Ch. 3 - Which statement is true of the quantum mechanical...Ch. 3 - Why is it important to understand atoms?Ch. 3 - Prob. 2ECh. 3 - What defines an element? How many naturally...Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Explain the quantum mechanical model for the atom....Ch. 3 - Give two examples of each: a. alkali metal b....Ch. 3 - Which elements exist as diatomic molecules?Ch. 3 - Explain the difference and similarity between...Ch. 3 - Prob. 15ECh. 3 - Determine the charge of each of the following: a...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Give the atomic number (Z) and the mass number (A)...Ch. 3 - Prob. 20ECh. 3 - The following isotopes have applications in...Ch. 3 - The following isotopes are important in nuclear...Ch. 3 - 14C is used in carbon dating of artifacts....Ch. 3 - 40K is used to measure the age of Earth. Determine...Ch. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Give electron configurations according to the Bohr...Ch. 3 - Give electron configurations according to the Bohr...Ch. 3 - Prob. 29ECh. 3 - How many valence electrons are in each element of...Ch. 3 - Prob. 31ECh. 3 - Draw electron configurations for each of the...Ch. 3 - Which two of the following elements would you...Ch. 3 - Group the following elements into three similar...Ch. 3 - We have seen that the reactivity of an element is...Ch. 3 - What is the electron configuration of Mg2+? How...Ch. 3 - Classify each of the following elements as a...Ch. 3 - Classify each of the following as a metal, a...Ch. 3 - Calculate the atomic mass of neon (Ne), which is...Ch. 3 - An element has two naturally occurring isotopes....Ch. 3 - A fictitious element has two naturally occurring...Ch. 3 - Copper has two naturally occurring isotopes. Cu-63...Ch. 3 - How many moles of titanium are present in 124 g of...Ch. 3 - Prob. 44ECh. 3 - How many moles are there in each sample? a. 45 mg...Ch. 3 - How many moles are there in each sample? a. 55.0 g...Ch. 3 - What is the mass of each sample? a.1.8 mol S...Ch. 3 - What is the mass of each sample? a.2.75 mol Fe...Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - How many Ag atoms are present in a piece of pure...Ch. 3 - How many platinum atoms are in a pure platinum...Ch. 3 - A pure gold necklace has a volume of 1.8cm3. How...Ch. 3 - A titanium bicycle component has a volume of...Ch. 3 - An iron sphere has a radius of 3.4 cm. How many...Ch. 3 - Calculate the number of atoms in the universe. The...Ch. 3 - The introduction to this chapter states that...Ch. 3 - Suppose the absolute value of the charge of the...Ch. 3 - When we refer to doughnuts or cookies, we often...Ch. 3 - Prob. 60ECh. 3 - Why does Avogadros number have such an odd value?...Ch. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Here are three fictitious elements and a molecular...Ch. 3 - Prob. 66ECh. 3 - Gather any two of the following items, measure...
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- Homework 13 (Ch17) Question 4 of 4 (1 point) | Question Attempt: 2 of 2 ✓ 1 ✓ 2 = 3 4 Time Remaining: 4:25:54 Using the thermodynamic information in the ALEKS Data tab, calculate the standard reaction free energy of the following chemical reaction: 2CH3OH (g)+302 (g) → 2CO2 (g) + 4H₂O (g) Round your answer to zero decimal places. ☐ kJ x10 ☐ Subm Check 2020 Hill LLC. All Rights Reserved. Terms of Use | Privacy Cearrow_forwardIdentifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forward
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