GENERAL, ORGANIC,BIO CHP.10-23-ACCESS>I
10th Edition
ISBN: 9781260506099
Author: Denniston
Publisher: MCG CUSTOM
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Chapter 3, Problem 5MCP
Interpretation Introduction
Interpretation:
The resonance forms of the carbonate ion have to be drawn and the conclusion obtained from the stability of the carbonate ion has to be given.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 3 Solutions
GENERAL, ORGANIC,BIO CHP.10-23-ACCESS>I
Ch. 3.1 - Draw the Lewis symbol for oxygen, and indicate the...Ch. 3.1 - Prob. 3.2PPCh. 3.1 - Prob. 3.3PPCh. 3.2 - Prob. 3.4PPCh. 3.2 - Prob. 3.5PPCh. 3.2 - Prob. 3.1QCh. 3.2 - Prob. 3.2QCh. 3.2 - Prob. 3.6PPCh. 3.2 - Prob. 3.7PPCh. 3.2 - Prob. 3.8PP
Ch. 3.2 - Prob. 3.9PPCh. 3.4 - Prob. 3.10PPCh. 3.4 - Prob. 3.11PPCh. 3.4 - Prob. 3.12PPCh. 3.4 - Prob. 3.13PPCh. 3.4 - Prob. 3.3QCh. 3.4 - Prob. 3.4QCh. 3.4 - Prob. 3.14PPCh. 3.4 - Prob. 3.5QCh. 3.4 - Prob. 3.6QCh. 3.4 - Prob. 3.16PPCh. 3.4 - Prob. 3.7QCh. 3.4 - Prob. 3.8QCh. 3.4 - Prob. 3.9QCh. 3 - Prob. 3.13QPCh. 3 - Draw the appropriate Lewis symbol for each of the...Ch. 3 - Draw the appropriate Lewis symbol for each of the...Ch. 3 - Prob. 3.16QPCh. 3 - Describe the differences between covalent bonding...Ch. 3 - Describe the difference between nonpolar covalent...Ch. 3 - What is the periodic trend of electronegativity?
Ch. 3 - What role does electronegativity play in...Ch. 3 - Use electronegativity values to classify the bonds...Ch. 3 - Use electronegativity values to classify the bonds...Ch. 3 - When there is a reaction between each of these...Ch. 3 - Prob. 3.24QPCh. 3 - Explain, using Lewis symbols and the octet rule,...Ch. 3 - Explain, using Lewis symbols and the octet rule,...Ch. 3 - Prob. 3.27QPCh. 3 - Prob. 3.28QPCh. 3 - Name each of the following ions:
Na+
Cu+
Mg2+
Ch. 3 - Name each of the following ions:
Cu2+
Fe2+
Fe3+
Ch. 3 - Name each of the following ions:
HCO3–
H3O+
CO32−
Ch. 3 - Prob. 3.32QPCh. 3 - Prob. 3.33QPCh. 3 - Write the formula for each of the following...Ch. 3 - Prob. 3.35QPCh. 3 - Prob. 3.36QPCh. 3 - Prob. 3.37QPCh. 3 - Predict the formula of a compound formed...Ch. 3 - Prob. 3.39QPCh. 3 - Prob. 3.40QPCh. 3 - Prob. 3.41QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Prob. 3.43QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Prob. 3.45QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Write a suitable formula for:
sodium...Ch. 3 - Write a suitable formula for:
aluminum...Ch. 3 - Prob. 3.49QPCh. 3 - Prob. 3.50QPCh. 3 - Prob. 3.51QPCh. 3 - Prob. 3.52QPCh. 3 - Write a suitable formula for:
silicon...Ch. 3 - Prob. 3.54QPCh. 3 - Contrast ionic and covalent compounds with respect...Ch. 3 - Prob. 3.56QPCh. 3 - Prob. 3.57QPCh. 3 - Prob. 3.58QPCh. 3 - Prob. 3.59QPCh. 3 - Prob. 3.60QPCh. 3 - Prob. 3.61QPCh. 3 - Prob. 3.62QPCh. 3 - Prob. 3.63QPCh. 3 - Prob. 3.64QPCh. 3 - Prob. 3.65QPCh. 3 - Prob. 3.66QPCh. 3 - How is the positive charge of a polyatomic cation...Ch. 3 - Prob. 3.68QPCh. 3 - Prob. 3.69QPCh. 3 - Prob. 3.70QPCh. 3 - Prob. 3.71QPCh. 3 - Prob. 3.72QPCh. 3 - Prob. 3.73QPCh. 3 - Prob. 3.74QPCh. 3 - Prob. 3.75QPCh. 3 - Prob. 3.76QPCh. 3 - Prob. 3.77QPCh. 3 - Prob. 3.78QPCh. 3 - Prob. 3.79QPCh. 3 - Prob. 3.80QPCh. 3 - Prob. 3.81QPCh. 3 - Prob. 3.82QPCh. 3 - Prob. 3.83QPCh. 3 - Prob. 3.84QPCh. 3 - Prob. 3.85QPCh. 3 - Prob. 3.86QPCh. 3 - Prob. 3.87QPCh. 3 - Prob. 3.88QPCh. 3 - Prob. 3.89QPCh. 3 - Prob. 3.90QPCh. 3 - Prob. 3.91QPCh. 3 - Prob. 3.93QPCh. 3 - Prob. 3.94QPCh. 3 - Prob. 3.95QPCh. 3 - Prob. 3.96QPCh. 3 - Prob. 3.97QPCh. 3 - Prob. 3.98QPCh. 3 - Prob. 3.99QPCh. 3 - Prob. 3.100QPCh. 3 - Prob. 3.101QPCh. 3 - Prob. 3.102QPCh. 3 - Prob. 3.103QPCh. 3 - Prob. 3.104QPCh. 3 - Prob. 3.107QPCh. 3 - Prob. 3.108QPCh. 3 - Prob. 3.109QPCh. 3 - Prob. 3.110QPCh. 3 - Prob. 3.112QPCh. 3 - Prob. 1MCPCh. 3 - Prob. 2MCPCh. 3 - Prob. 3MCPCh. 3 - Prob. 4MCPCh. 3 - Prob. 5MCPCh. 3 - Prob. 6MCPCh. 3 - Prob. 7MCPCh. 3 - Prob. 8MCPCh. 3 - Prob. 9MCPCh. 3 - Prob. 10MCP
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