Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Introductory Chemistry (6th Edition)
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Chapter 3, Problem 59E
Interpretation Introduction

Interpretation: Calculate the excess nutritional energy consumed by the adult per day in kilojoules and number of days it will take to gain 1 lb.

Concept introduction: The difference between the total energy consumed by the adult and the energy used by the individual gives the excess nutritional energy in calories. Convert this energy into kilojoules. Then, the number of days that the person takes to gain 1 lb is determined.

To determine: The excess nutritional energy consumed by an adult per day and the number of days that the person takes to gain 1 lb.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 3 Solutions

Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Introductory Chemistry (6th Edition)

Ch. 3 - Define matter and list some examples.Ch. 3 - Prob. 2ECh. 3 - What are the three states of matter?Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - 9. What is a mixture? Ch. 3 - 10. What is the difference between a homogeneous...Ch. 3 - What is a pure substance?Ch. 3 - What is an element? A compound?Ch. 3 - What is the difference between a mixture and a...Ch. 3 - Prob. 14ECh. 3 - 15. What is the difference between a physical...Ch. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - What is chemical energy? List some examples of...Ch. 3 - Prob. 21ECh. 3 - 22. What is an exothermic reaction? Which has...Ch. 3 - 23. What is an endothermic reaction? Which has...Ch. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - 26. How do the three temperature scales differ? Ch. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - The following equation can be used to convert...Ch. 3 - Prob. 30ECh. 3 - Classify each pure substance as an element or a...Ch. 3 - 32. Classify each pure substance as an element or...Ch. 3 - 33. Classify each mixture as homogeneous or...Ch. 3 - 34. Classify each mixture as homogeneous or...Ch. 3 - 35. Classify each substance as a pure substance or...Ch. 3 - 36. Classify each substance as a pure substance or...Ch. 3 - Classify each property as physical or chemical. a....Ch. 3 - Classify each property as physical or chemical. a....Ch. 3 - Which of the following properties of ethylene(a...Ch. 3 - Which of the following properties of ozone (a...Ch. 3 - 41. Classify each change as physical or...Ch. 3 - 42. Classify each change as physical or...Ch. 3 - A block of aluminum is (a) ground into aluminum...Ch. 3 - 44. Several pieces of graphite from a mechanical...Ch. 3 - 45. An automobile gasoline tank holds 42 kg of...Ch. 3 - In the explosion of a hydrogen-filled balloon,...Ch. 3 - 47. Are these data sets on chemical changes...Ch. 3 - 48. Are these data sets on chemical changes...Ch. 3 - Prob. 49ECh. 3 - 50. A 56-g sample of iron reacts with 24 g of...Ch. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - 61 A common type of handwarmer contains Iron...Ch. 3 - 62. In a chemical cold pack, two substances are...Ch. 3 - 63. Classify each process as exothermic or...Ch. 3 - Classify each process as exothermic or...Ch. 3 - Perform each temperature conversion. a.212 F to...Ch. 3 - Prob. 66ECh. 3 - The coldest temperature ever measured in the...Ch. 3 - 68. The warmest temperature ever measured in the...Ch. 3 - 69. Vodka does not freeze in the freezer because...Ch. 3 - Liquid helium boils at 4.2 K. Convert this...Ch. 3 - 71. The temperature in the South Pole during the...Ch. 3 - Prob. 72ECh. 3 - Prob. 73ECh. 3 - Prob. 74ECh. 3 - 75. Calculate the amount of heat required to raise...Ch. 3 - 76. Calculate the amount of heat required to raise...Ch. 3 - Calculate the amount of heat required to heat a...Ch. 3 - 78. Calculate the amount of heat required to heat...Ch. 3 - If 89 J of heat are added to a pure gold coin with...Ch. 3 - If 57 J heat are added to an aluminum can with a...Ch. 3 - An iron nail with a mass of 12 g absorbs 15 J of...Ch. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - 84. A lead fishing weight with a mass of 57 g...Ch. 3 - An unknown metal with a mass of 28 g absorbs 58 J...Ch. 3 - When 2.8 J of heat are added to 5.6 g of an...Ch. 3 - When 56 J of heat are added to 11 g of a liquid,...Ch. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - How much energy (In J) lost when a sample of iron...Ch. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - A pure gold ring with a volume of 1.57 cm3 is...Ch. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - 99. What is the temperature change (ΔT) in Celsius...Ch. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Prob. 102ECh. 3 - A backpacker wants to carry enough fuel to heat...Ch. 3 - 104. A cook wants to heat 1.35 kg of water from...Ch. 3 - Evaporating sweat cools the body because...Ch. 3 - Prob. 106ECh. 3 - A 15.7-g aluminum block is warmed to 53.2C and...Ch. 3 - A 25.0-mL sample of ethanol (density = 0.789g/mL)...Ch. 3 - The wattage of an appliance indicates its average...Ch. 3 - Prob. 110ECh. 3 - What temperature is the same whether it is...Ch. 3 - What temperature on the Celsius scale is equal to...Ch. 3 - 113. Classify each as pure substance or a...Ch. 3 - Classify each as a pure substance or a mixture. If...Ch. 3 - This molecular drawing shows images of acetone...Ch. 3 - This molecular drawing shows of methane molecules...Ch. 3 - Prob. 117ECh. 3 - Global warming refers to the rise in average...Ch. 3 - 119. Examine the data for the maximum and minimum...Ch. 3 - Using white and black circles to represent...Ch. 3 - Prob. 121QGWCh. 3 - 122. A friend asks you to invest in a new...Ch. 3 - Prob. 123QGW
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