Pearson eText -- Physics for Scientists and Engineers with Modern Physics -- Instant Access (Pearson+)
5th Edition
ISBN: 9780137488179
Author: Douglas Giancoli
Publisher: PEARSON+
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6. We used the constant volume heat capacity, Cv, when we talked about
thermodynamic cycles. It acts as a proportionality constant between energy and
temperature: dU = C₁dT.
You can also define a heat capacity for constant pressure processes, Cp. You can think
of enthalpy playing a similar role to energy, but for constant pressure processes
δαρ
C = (37) - Sup
Ср
ат
P
=
ат
Starting from the definition of enthalpy, H = U + PV, find the relationship between Cy
and Cp for an ideal gas.
Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt
= 41°C. Reversible melting experiments indicate that
at Tm
AHm=37.7 kJ mol-1. Calculate:
A. The entropy of melting, ASm-
B. The Gibbs free energy of melting, AGm-
C. Does the membrane become more or less ordered upon melting?
D. There are 32 rotatable CH2
CH2 bonds in each molecule that can rotate more freely if the
membrane melts. What is the increase in multiplicity on melting a mole of bonds?
5. Heat capacity often has a temperature dependence for real molecules, particularly if
you go over a large temperature range. The heat capacity for liquid n-butane can be
fit to the equation
Cp(T) = a + bT
where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K)
to its boiling point (T₁ = 270 K).
A. Compute AH for heating butane from 170 K to 270 K.
B. Compute AS for the same temperature range.
Chapter 3 Solutions
Pearson eText -- Physics for Scientists and Engineers with Modern Physics -- Instant Access (Pearson+)
Ch. 3.2 - Prob. 1AECh. 3.3 - What does the incorrect vector in Fig. 36c...Ch. 3.8 - Prob. 1DECh. 3.8 - The maximum range of a projectile is found to be...Ch. 3 - One car travels due east at 40 km/h. and a second...Ch. 3 - Can you conclude that a car is not accelerating if...Ch. 3 - Prob. 3QCh. 3 - Can the displacement vector for a particle moving...Ch. 3 - During baseball practice, a batter hits a very...Ch. 3 - If V=V1+V2, is V necessarily greater than V1...
Ch. 3 - Prob. 7QCh. 3 - Can two vectors, of unequal magnitude, add up to...Ch. 3 - Can the magnitude of a vector ever (a) equal, or...Ch. 3 - Can a particle with constant speed be...Ch. 3 - Prob. 11QCh. 3 - In archery, should the arrow be aimed directly at...Ch. 3 - Prob. 13QCh. 3 - Prob. 14QCh. 3 - Prob. 15QCh. 3 - A projectile is launched at an upward angle of 30...Ch. 3 - A projectile has the least speed at what point in...Ch. 3 - Two cannonballs, A and B, are fired from the...Ch. 3 - A person sitting in an enclosed train car, moving...Ch. 3 - If you are riding on a train that speeds past...Ch. 3 - Two rowers, who can row at the same speed in still...Ch. 3 - If you stand motionless under an umbrella in a...Ch. 3 - Prob. 1MCQCh. 3 - Prob. 2MCQCh. 3 - Prob. 3MCQCh. 3 - Prob. 4MCQCh. 3 - Prob. 6MCQCh. 3 - Prob. 7MCQCh. 3 - Prob. 8MCQCh. 3 - Prob. 10MCQCh. 3 - Prob. 12MCQCh. 3 - Prob. 13MCQCh. 3 - Prob. 14MCQCh. 3 - Prob. 15MCQCh. 3 - Prob. 1PCh. 3 - Prob. 3PCh. 3 - (II) Graphically determine the resultant of the...Ch. 3 - Prob. 5PCh. 3 - Prob. 6PCh. 3 - Prob. 7PCh. 3 - Prob. 8PCh. 3 - Prob. 9PCh. 3 - Prob. 10PCh. 3 - (II) (a) Given the vectors A and B shown in Fig....Ch. 3 - (II) Determine the vector AC, given the vectors A...Ch. 3 - Prob. 13PCh. 3 - Prob. 14PCh. 3 - Prob. 15PCh. 3 - Prob. 16PCh. 3 - Prob. 17PCh. 3 - Prob. 18PCh. 3 - Prob. 19PCh. 3 - (I) What was the average velocity of the particle...Ch. 3 - Prob. 21PCh. 3 - (II) At t = 0, a particle starts from rest at x =...Ch. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Prob. 30PCh. 3 - Prob. 31PCh. 3 - Prob. 32PCh. 3 - Prob. 33PCh. 3 - Prob. 34PCh. 3 - Prob. 35PCh. 3 - Prob. 36PCh. 3 - (II) A fire hose held near the ground shoots water...Ch. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Prob. 41PCh. 3 - Prob. 42PCh. 3 - Prob. 43PCh. 3 - Prob. 44PCh. 3 - Prob. 45PCh. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48PCh. 3 - Prob. 49PCh. 3 - Prob. 50PCh. 3 - Prob. 51PCh. 3 - Prob. 52PCh. 3 - (II) (a) A long jumper leaves the ground at 45...Ch. 3 - Prob. 54PCh. 3 - Prob. 55PCh. 3 - Prob. 56PCh. 3 - Prob. 57PCh. 3 - Prob. 58PCh. 3 - (II) Suppose the kick in Example 3-7 is attempted...Ch. 3 - Prob. 60PCh. 3 - Prob. 61PCh. 3 - Prob. 62PCh. 3 - (I) Huck Finn walks at a speed of 0.70m/s across...Ch. 3 - (II) Determine the speed of the boat with respect...Ch. 3 - Prob. 65PCh. 3 - (II) A passenger on a boat moving at 1.70 m/s on a...Ch. 3 - Prob. 67PCh. 3 - (II) In what direction should the pilot aim the...Ch. 3 - Prob. 69PCh. 3 - Prob. 70PCh. 3 - (II) A swimmer is capable of swimming 0.60 m/s in...Ch. 3 - (II) A swimmer is capable of swimming 0.60m/s in...Ch. 3 - Prob. 73PCh. 3 - Prob. 74PCh. 3 - Prob. 75PCh. 3 - Prob. 76GPCh. 3 - Prob. 77GPCh. 3 - Prob. 78GPCh. 3 - Prob. 79GPCh. 3 - (II) Here is something to try at a sporting event....Ch. 3 - Prob. 82GPCh. 3 - Prob. 83GPCh. 3 - Prob. 84GPCh. 3 - Prob. 85GPCh. 3 - Prob. 86GPCh. 3 - Prob. 87GPCh. 3 - Prob. 88GPCh. 3 - Prob. 89GPCh. 3 - Prob. 90GPCh. 3 - Prob. 91GPCh. 3 - Prob. 93GPCh. 3 - Prob. 95GPCh. 3 - The speed of a boat in still water is v. The boat...Ch. 3 - At t = 0 a batter hits a baseball with an initial...Ch. 3 - Prob. 98GPCh. 3 - Prob. 99GPCh. 3 - Prob. 100GPCh. 3 - Prob. 101GPCh. 3 - Prob. 102GP
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