EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
Publisher: VST
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Chapter 3, Problem 50E
The smallest atoms can themselves exhibit
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3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Show the mechanism for these reactions
Chapter 3 Solutions
EBK CHEMISTRY
Ch. 3 - Which wavelength of light has the highest...Ch. 3 - Which kind of electromagnetic radiation contains...Ch. 3 - How much energy (in J ) is contained in 1.00 mole...Ch. 3 - Light from three different lasers (A, B, and C),...Ch. 3 - Calculate the wavelength of an electron traveling...Ch. 3 - Which set of three quantum numbers does not...Ch. 3 - Calculate the wavelength of light emitted when an...Ch. 3 - Which electron transition produces light of the...Ch. 3 - How much time (in seconds) does it take light to...Ch. 3 - Which figure represents a d orbital? None of the...
Ch. 3 - Why is the quantum-mechanical model of the atom...Ch. 3 - What is light? How fast does it travel in a...Ch. 3 - Define the wavelength and amplitude of a wave.Ch. 3 - Define the frequency of electromagnetic radiation....Ch. 3 - What determines the color of light? Describe the...Ch. 3 - What determines the color of a colored object?...Ch. 3 - Give an approximate range of wavelengths for each...Ch. 3 - Explain the wave behavior known as interference....Ch. 3 - Explain the wave behavior known as diffraction....Ch. 3 - Describe the photoelectric effect. How did...Ch. 3 - How did the photoelectric effect lead Einstein to...Ch. 3 - What is a photon? How is the energy of a photon...Ch. 3 - What is an emission spectrum? How does an emission...Ch. 3 - Describe the Bohr model for the atom. How did the...Ch. 3 - Explain electron diffraction.Ch. 3 - What is the de Broglie wavelength of an electron?...Ch. 3 - What are complementary properties? How does...Ch. 3 - Explain Heisenberg’s uncertainty principle. What...Ch. 3 - What is a trajectory? What kind of information do...Ch. 3 - Why does the uncertainty principle make it...Ch. 3 - Newton’s laws of motion are deterministic. Explain...Ch. 3 - An electron behaves in ways that are at least...Ch. 3 - What is a probability distribution map?Ch. 3 - For each solution to the Schrödinger equation,...Ch. 3 - What is a quantum-mechanical orbital?Ch. 3 - What is the Schrödinger equation? What is a wave...Ch. 3 - What are the possible values of the principal...Ch. 3 - What are the possible values of the angular...Ch. 3 - What are the possible values of the magnetic...Ch. 3 - Explain the difference between a plot showing the...Ch. 3 - Sketch the general shapes of the s, p, and d...Ch. 3 - List the four different sublevels. Given that only...Ch. 3 - Why are atoms usually portrayed as spheres when...Ch. 3 - The distance from the sun to Earth is 1.496108 km....Ch. 3 - The nearest star to our sun is Proxima Centauri,...Ch. 3 - List these types of electromagnetic radiation in...Ch. 3 - List these types of electromagnetic radiation in...Ch. 3 - Calculate the frequency of each wavelength of...Ch. 3 - Calculate the wavelength of each frequency of...Ch. 3 - Calculate the energy of a photon of...Ch. 3 - Calculate the energy of a photon of...Ch. 3 - A laser pulse with wavelength 532 nm contains 3.85...Ch. 3 - A heat lamp produces 32.8 watts of power at a...Ch. 3 - Determine the energy of 1 mol of photons for each...Ch. 3 - How much energy is contained in 1 mol of each?...Ch. 3 - Sketch the interference pattern that results from...Ch. 3 - What happens to the interference pattern described...Ch. 3 - The resolution limit of a microscope is roughly...Ch. 3 - The smallest atoms can themselves exhibit...Ch. 3 - What is the de Broglie wavelength of an electron...Ch. 3 - A proton in a linear accelerator has a de Broglie...Ch. 3 - Prob. 53ECh. 3 - A 0.22-caliber handgun fires a 27-g bullet at a...Ch. 3 - An electron has an uncertainty in its position of...Ch. 3 - An electron traveling at [1.35 \times {10^5}\] m/s...Ch. 3 - Which electron is, on average, closer to the...Ch. 3 - Which electron is, on average, further from the...Ch. 3 - What are the possible values of I for each given...Ch. 3 - What are the possible values of m1 for each given...Ch. 3 - Which set of quantum numbers cannot occur together...Ch. 3 - Which combinations of n and I represent real...Ch. 3 - Prob. 63ECh. 3 - Sketch the 3d orbitals. How do the 4d orbitals...Ch. 3 - An electron in a hydrogen atom is excited with...Ch. 3 - Determine whether each transition in the hydrogen...Ch. 3 - According to the quantum-mechanical model for the...Ch. 3 - According to the quantum-mechanical model for the...Ch. 3 - Calculate the wavelength of the light emitted when...Ch. 3 - Calculate the frequency of the light emitted when...Ch. 3 - Prob. 71ECh. 3 - An electron in a hydrogen atom relaxes to the [n =...Ch. 3 - Ultraviolet radiation and radiation of shorter...Ch. 3 - The human eye contains a molecule called...Ch. 3 - An argon ion laser puts out 5.0 W of continuous...Ch. 3 - A green leaf has a surface area of 2.50 cm2. If...Ch. 3 - Prob. 77ECh. 3 - An X-ray photon of wavelength 0.989 nm strikes a...Ch. 3 - Prob. 79ECh. 3 - The energy required to ionize sodium is 496...Ch. 3 - Prob. 81ECh. 3 - Suppose that, in an alternate universe, the...Ch. 3 - Prob. 83ECh. 3 - Prob. 84ECh. 3 - The binding energy of electrons in a metal is 193...Ch. 3 - In order for a thermonuclear fusion reaction of...Ch. 3 - Prob. 87ECh. 3 - Prob. 88ECh. 3 - The iodine molecule can be photodissociated...Ch. 3 - A sample of naphthalene in hexane contains 5.00104...Ch. 3 - Prob. 91ECh. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - The energy of a vibrating molecule is quantized...Ch. 3 - The wave functions for the 1s and 2s orbitals are...Ch. 3 - Before quantum mechanics was developed, Johannes...Ch. 3 - Find the velocity of an electron emitted by a...Ch. 3 - Water is exposed to infrared radiation of...Ch. 3 - Prob. 99ECh. 3 - A metal with a threshold frequency of 6.711014s1...Ch. 3 - Find the longest wavelength of a wave that can...Ch. 3 - The amount of heat to melt ice is 0.333 kJ/g. Find...Ch. 3 - Explain the difference between the Bohr model for...Ch. 3 - The light emitted from one of the following...Ch. 3 - Determine whether an interference pattern is...Ch. 3 - Which transition in the hydrogen atom results in...
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- Draw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forward
- Draw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forward
- What are the IUPAC Names of all the compounds in the picture?arrow_forward1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forward
- Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forwardProvide the correct IUPAC name for the compound shown here. Reset cis- 5- trans- ☑ 4-6- 2- 1- 3- di iso tert- tri cyclo sec- oct but hept prop hex pent yl yne ene anearrow_forward
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