Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 3, Problem 3C.3ST
Interpretation Introduction

Interpretation:

The residual entropy of the given solid has to be calculated.

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Could you crystallize one enantiomer of mandelic acid from a racemic mixture (using the typical achiral solvents found in our lab) without preparing a diastereomeric salt? Why or why not? No, because both enantiomers have the same solubility in achiral solvents. than the other. ооо Yes, because one enantiomer has a higher melting point No, because both enantiomers are liquids. Yes, because one enantiomer is more crystalline than the other.
If the literature value of specific rotation for a chiral compound is -53.6°, what is the enantiomeric excess of a compound with a measured specific rotation of -40.5°?
The process to determine the configuration, starts by placing the lowest priority substituent toward the back. If the substituents pointing forward decrease in priority in a clockwise order, the configuration is S. If the substituents decrease in priority in a counterclockwise order, the configuration is R. True False
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