Connect 1 Semester Access Card for General Chemistry: The Essential Concepts
7th Edition
ISBN: 9781259692543
Author: Raymond Chang Dr.; Kenneth Goldsby Professor
Publisher: McGraw-Hill Education
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Chapter 3, Problem 3.8QP
Interpretation Introduction
Interpretation:
The conversion of gram into
Concept Introduction:
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 3 Solutions
Connect 1 Semester Access Card for General Chemistry: The Essential Concepts
Ch. 3.1 - Practice Exercises The atomic masses of the two...Ch. 3.1 - There are two stable isotopes of iridium: 191Ir...Ch. 3.2 - Practice Exercise Calculate the number of grams of...Ch. 3.2 - Prob. 2PECh. 3.2 - Prob. 3PECh. 3.2 - Prob. 1RCCh. 3.3 - Practice Exercise What is the molecular mass of...Ch. 3.3 - Prob. 2PECh. 3.3 - Prob. 3PECh. 3.3 - Prob. 1RC
Ch. 3.4 - Review of Concepts
Explain how the mass...Ch. 3.5 - Practice Exercise Calculate the percent...Ch. 3.5 - Prob. 2PECh. 3.5 - Practice Exercise Calculate the number of grams of...Ch. 3.5 - Prob. 1RCCh. 3.6 - Practice Exercise A sample of a compound...Ch. 3.6 - Prob. 1RCCh. 3.7 - Prob. 1PECh. 3.7 - Prob. 1RCCh. 3.8 - Prob. 1PECh. 3.8 - Prob. 2PECh. 3.8 - Prob. 1RCCh. 3.9 - Prob. 1PECh. 3.9 - Consider the following reaction:
Starting with...Ch. 3.10 - Prob. 1PECh. 3.10 - Can the percent yield ever exceed the theoretical...Ch. 3 - Prob. 3.1QPCh. 3 - Prob. 3.2QPCh. 3 - Prob. 3.3QPCh. 3 - Prob. 3.4QPCh. 3 - Prob. 3.5QPCh. 3 - 3.6 The atomic masses of and are 6.0151 amu and...Ch. 3 - Prob. 3.7QPCh. 3 - Prob. 3.8QPCh. 3 - Prob. 3.9QPCh. 3 - 3.10 What is the molar mass of an atom? What are...Ch. 3 - Prob. 3.11QPCh. 3 - Prob. 3.12QPCh. 3 - Prob. 3.13QPCh. 3 - Prob. 3.14QPCh. 3 - Prob. 3.15QPCh. 3 - Prob. 3.16QPCh. 3 - 3.17 What is the mass in grams of a single atom of...Ch. 3 - Prob. 3.18QPCh. 3 - Prob. 3.19QPCh. 3 - Prob. 3.20QPCh. 3 - Prob. 3.21QPCh. 3 - Prob. 3.22QPCh. 3 - Prob. 3.23QPCh. 3 - Prob. 3.24QPCh. 3 - Prob. 3.25QPCh. 3 - Prob. 3.26QPCh. 3 - Prob. 3.27QPCh. 3 - Prob. 3.28QPCh. 3 - Prob. 3.29QPCh. 3 - Prob. 3.30QPCh. 3 - Prob. 3.31QPCh. 3 - Prob. 3.32QPCh. 3 - Prob. 3.33QPCh. 3 - Prob. 3.34QPCh. 3 - Prob. 3.35QPCh. 3 - Prob. 3.36QPCh. 3 - Prob. 3.37QPCh. 3 - Prob. 3.38QPCh. 3 - Prob. 3.39QPCh. 3 - Prob. 3.40QPCh. 3 - Prob. 3.41QPCh. 3 - Prob. 3.42QPCh. 3 - Prob. 3.43QPCh. 3 - 3.44 Peroxyacylnitrate (PAN) is one of the...Ch. 3 - Prob. 3.45QPCh. 3 - Prob. 3.46QPCh. 3 - Prob. 3.47QPCh. 3 - Prob. 3.48QPCh. 3 - Prob. 3.49QPCh. 3 - Prob. 3.50QPCh. 3 - Prob. 3.51QPCh. 3 - 3.52 The empirical formula of a compound is CH. If...Ch. 3 - Prob. 3.53QPCh. 3 - Prob. 3.54QPCh. 3 - Prob. 3.55QPCh. 3 - Prob. 3.56QPCh. 3 - Prob. 3.57QPCh. 3 - Prob. 3.58QPCh. 3 - Prob. 3.59QPCh. 3 - Prob. 3.60QPCh. 3 - Prob. 3.61QPCh. 3 - Prob. 3.62QPCh. 3 - Prob. 3.63QPCh. 3 - 3.64 Which of the following equations best...Ch. 3 - Prob. 3.65QPCh. 3 - Prob. 3.66QPCh. 3 - Prob. 3.67QPCh. 3 - Prob. 3.68QPCh. 3 - Prob. 3.69QPCh. 3 - Prob. 3.70QPCh. 3 - Prob. 3.71QPCh. 3 - Prob. 3.72QPCh. 3 - Prob. 3.73QPCh. 3 - Prob. 3.74QPCh. 3 - 3.75 Limestone (CaCO3) is decomposed by heating to...Ch. 3 - Prob. 3.76QPCh. 3 - Prob. 3.77QPCh. 3 - Prob. 3.78QPCh. 3 - 3.79 Define limiting reagent and excess reagent....Ch. 3 - Prob. 3.80QPCh. 3 - Prob. 3.81QPCh. 3 - Prob. 3.82QPCh. 3 - Prob. 3.83QPCh. 3 - Prob. 3.84QPCh. 3 - Prob. 3.85QPCh. 3 - Prob. 3.86QPCh. 3 - Prob. 3.87QPCh. 3 - Prob. 3.88QPCh. 3 - Prob. 3.89QPCh. 3 - Prob. 3.90QPCh. 3 - Prob. 3.91QPCh. 3 - Prob. 3.92QPCh. 3 - Prob. 3.93QPCh. 3 - Prob. 3.94QPCh. 3 - Prob. 3.95QPCh. 3 - Prob. 3.96QPCh. 3 - Prob. 3.97QPCh. 3 - Prob. 3.98QPCh. 3 - Prob. 3.99QPCh. 3 - Prob. 3.100QPCh. 3 - Prob. 3.101QPCh. 3 - Prob. 3.102QPCh. 3 - Prob. 3.103QPCh. 3 - Prob. 3.104QPCh. 3 - Prob. 3.105QPCh. 3 - Prob. 3.106QPCh. 3 - Prob. 3.107QPCh. 3 - Prob. 3.108QPCh. 3 - Prob. 3.110QPCh. 3 - Prob. 3.111QPCh. 3 - Prob. 3.112QPCh. 3 - Prob. 3.113QPCh. 3 - 3.114 In the total synthesis of a natural product,...Ch. 3 - Prob. 3.115QPCh. 3 - Prob. 3.116SPCh. 3 - Prob. 3.117SPCh. 3 - 3.118 A certain metal M forms a bromide containing...Ch. 3 - Prob. 3.119SPCh. 3 - Prob. 3.120SP
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