Sodium borohydride, NaBH 4 , a substance used in the synthesis of many pharmaceutical agents, can be prepared reaction of NaH with B 2 H 6 according to the equation 2 NaH + B 2 H 6 → 2 NaBH 4 (a) How many grams of NaBH 4 can be prepared by reaction between 8.55 g of Nail and 6.75 g of B 2 H 6 ? (b) Which reactant is limiting, and how many grams of the excess reactant will be left over?
Sodium borohydride, NaBH 4 , a substance used in the synthesis of many pharmaceutical agents, can be prepared reaction of NaH with B 2 H 6 according to the equation 2 NaH + B 2 H 6 → 2 NaBH 4 (a) How many grams of NaBH 4 can be prepared by reaction between 8.55 g of Nail and 6.75 g of B 2 H 6 ? (b) Which reactant is limiting, and how many grams of the excess reactant will be left over?
Solution Summary: The author explains that the limiting reactant limits the amount of product formed in a reaction. The percentage yield is related to the actual yield and theoretical yield.
Sodium borohydride,
NaBH
4
, a substance used in the synthesis of many pharmaceutical agents, can be prepared reaction of NaH with
B
2
H
6
according to the equation
2
NaH
+
B
2
H
6
→
2
NaBH
4
(a) How many grams of
NaBH
4
can be prepared by reaction between 8.55 g of Nail and 6.75 g of
B
2
H
6
? (b) Which reactant is limiting, and how many grams of the excess reactant will be left over?
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ
Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions
about this system:
?
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
0.035 atm
✓
G
00.
18
Ar
Highlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area.
HO-
HO-
-0
OH
OH
HO
NG
HO-
HO-
OH
OH
OH
OH
NG
OH
€
+
Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn
it into the product of the reaction.
Also, write the name of the product molecule under the drawing area.
Name: ☐
H
C=0
X
H-
OH
HO-
H
HO-
-H
CH₂OH
×
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