Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Chapter 3, Problem 3.77E
An atom that has five
a.
b.
c.
d.
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 3 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 3 - Identify the group and period to which each of the...Ch. 3 - Identify the group and period to which each of the...Ch. 3 - Write the symbol and name for the elements located...Ch. 3 - Write the symbol and name for the elements located...Ch. 3 - a. How many elements are located in group VIIB (7)...Ch. 3 - a. How many elements are located in group VIIB (7)...Ch. 3 - The following statements either define or are...Ch. 3 - The following statements either define or are...Ch. 3 - According to the Bohr theory, which of the...Ch. 3 - What particles in the nucleus cause the nucleus to...
Ch. 3 - What is the maximum number of electrons that can...Ch. 3 - What is the maximum number of electrons that can...Ch. 3 - How many orbitals are found in the fourth shell?...Ch. 3 - How many orbitals are found in the second shell?...Ch. 3 - Prob. 3.15ECh. 3 - How many orbitals are found in a 4f subshell? What...Ch. 3 - Identify the subshells found in the fourth shell;...Ch. 3 - Look at the periodic table and tell how many...Ch. 3 - Look at the periodic table and tell how many...Ch. 3 - What period 6 element has chemical properties most...Ch. 3 - Prob. 3.21ECh. 3 - Prob. 3.22ECh. 3 - Prob. 3.23ECh. 3 - Write an electronic configuration for each of the...Ch. 3 - Prob. 3.25ECh. 3 - Write electronic configuration and answer the...Ch. 3 - Write electronic configuration and answer the...Ch. 3 - Prob. 3.28ECh. 3 - Prob. 3.29ECh. 3 - Prob. 3.30ECh. 3 - Prob. 3.31ECh. 3 - Prob. 3.32ECh. 3 - Prob. 3.33ECh. 3 - Classify each of the following elements into the...Ch. 3 - Classify each of the following elements into the...Ch. 3 - Prob. 3.36ECh. 3 - Prob. 3.37ECh. 3 - Classify the following as metals, nonmetals, or...Ch. 3 - Prob. 3.39ECh. 3 - Prob. 3.40ECh. 3 - Prob. 3.41ECh. 3 - Use trends within the periodic table and indicate...Ch. 3 - Prob. 3.43ECh. 3 - Use trends within the periodic table and indicate...Ch. 3 - Prob. 3.45ECh. 3 - How would you expect the chemical properties of...Ch. 3 - Prob. 3.47ECh. 3 - What would be the mass in mg of 3.01020atoms that...Ch. 3 - Prob. 3.49ECh. 3 - A 10.02-g sample of an element contains 0.250mol...Ch. 3 - Prob. 3.51ECh. 3 - Prob. 3.52ECh. 3 - Prob. 3.53ECh. 3 - Calcium metal reacts with cold water as follows:...Ch. 3 - Prob. 3.55ECh. 3 - Prob. 3.56ECh. 3 - The arrangement of the modern periodic table is...Ch. 3 - The horizontal rows of the periodic table are...Ch. 3 - Prob. 3.59ECh. 3 - Which two elements have chemical properties that...Ch. 3 - Prob. 3.61ECh. 3 - Prob. 3.62ECh. 3 - What does the number 36 represent on the periodic...Ch. 3 - Prob. 3.64ECh. 3 - Prob. 3.65ECh. 3 - Prob. 3.66ECh. 3 - From the periodic table, which of K and Br is...Ch. 3 - Prob. 3.68ECh. 3 - Prob. 3.69ECh. 3 - Which of the following has the largest first...Ch. 3 - Which elements conduct electricity? a. metals b....Ch. 3 - What term describes the electrons in the outermost...Ch. 3 - If the electron configuration of an element is...Ch. 3 - Identify the two atoms with the same number of...Ch. 3 - The number of unpaired electrons in the outer...Ch. 3 - How many valence electrons are needed to complete...Ch. 3 - An atom that has five 3p electrons in its ground...
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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