EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 3, Problem 3.6P
Interpretation Introduction

(a)

Interpretation:

The resonance structure for allyl cation is to be stated using the curved-arrow notation.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. The delocalization of electrons results in the formation of resonance structure. The curved-arrow notation traces the flow of the electrons in a compound. This notation is used to derive the resonance structure.

Interpretation Introduction

(b)

Interpretation:

The resonance structure for allyl anion is to be stated using the curved-arrow notation.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. The delocalization of electrons results in the formation of resonance structure. The curved-arrow notation traces the flow of the electrons in a compound. This notation is used to derive the resonance structure.

Interpretation Introduction

(c)

Interpretation:

The resonance structure for benzene is to be stated using the curved-arrow notation.

Concept introduction:

Most of the organic structures cannot be represented using single Lewis structure. Therefore, there exists more than one Lewis structure for representing a molecule or ion. These structures are known as resonance structures. These are the hypothetical structures and do not specify the exact structure. The delocalization of electrons results in the formation of resonance structure. The curved-arrow notation traces the flow of the electrons in a compound. This notation is used to derive the resonance structure.

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A. B. b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion and B. is a neutral molecule. One of these molecules is a highly reactive compound first characterized in frozen noble gas matrices, that self-reacts rapidly at temperatures above liquid nitrogen temperature. The other compound was isolated at room temperature in the early 1960s, and is a stable ligand used in organometallic chemistry. Which molecule is the more stable molecule, and why?
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