SeCl 6 2 − , TeCl 6 2 − , and CIF 6 − are all octahedral, but SeF 6 2 − and IF 6 − are distorted, with a lonepair on the central atom apparently influencing the shape. Suggest a reason for the difference inshape of these two groups of ions. (See J. Pilmé, E. A. Robinson, R. J. Gillespie,Inorg. Chem.,2006, 45, 6198.)
SeCl 6 2 − , TeCl 6 2 − , and CIF 6 − are all octahedral, but SeF 6 2 − and IF 6 − are distorted, with a lonepair on the central atom apparently influencing the shape. Suggest a reason for the difference inshape of these two groups of ions. (See J. Pilmé, E. A. Robinson, R. J. Gillespie,Inorg. Chem.,2006, 45, 6198.)
Solution Summary: The author explains the reason for distorted geometry of SeF_62-, whereas the valence-shell-electron-pair repulsion theory is ab
SeCl
6
2
−
,
TeCl
6
2
−
, and
CIF
6
−
are all octahedral, but
SeF
6
2
−
and
IF
6
−
are distorted, with a lonepair on the central atom apparently influencing the shape. Suggest a reason for the difference inshape of these two groups of ions. (See J. Pilmé, E. A. Robinson, R. J. Gillespie,Inorg. Chem.,2006, 45, 6198.)
#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un-
cyclize. Undo the ring into all possible molecules. (2pts, no partial credit)
hv
Don't used Ai solution
I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Group Theory - Learn like Expert with 3D animation | Introduction for Beginners | ONE Chemistry; Author: One Chemistry;https://www.youtube.com/watch?v=Lz2ih8fkgDs;License: Standard YouTube License, CC-BY