Chemistry: An Atoms-Focused Approach (Second Edition)
2nd Edition
ISBN: 9780393614053
Author: Thomas R. Gilbert, Rein V. Kirss, Stacey Lowery Bretz, Natalie Foster
Publisher: W. W. Norton & Company
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Shown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H.
Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem.
A strong band was observed in the IR at 1717 cm-1
Predict the major products of the organic reaction below.
: ☐
+
Х
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OH
1. NaH
2. CH₂Br
Click and drag to start
drawing a structure.
NG
NC
15Show all the steps you would use to synthesize the following products shown below using
benzene and any organic reagent 4 carbons or less as your starting material in addition to
any inorganic reagents that you have learned.
NO 2
NC
SO3H
NO2
OH
Chapter 3 Solutions
Chemistry: An Atoms-Focused Approach (Second Edition)
Ch. 3 - Prob. 3.01VPCh. 3 - Prob. 3.02VPCh. 3 - Prob. 3.03VPCh. 3 - Prob. 3.04VPCh. 3 - Prob. 3.05VPCh. 3 - Prob. 3.06VPCh. 3 - Prob. 3.07VPCh. 3 - Prob. 3.08VPCh. 3 - Prob. 3.09VPCh. 3 - Prob. 3.10VP
Ch. 3 - Prob. 3.11VPCh. 3 - Prob. 3.12VPCh. 3 - Prob. 3.13QACh. 3 - Prob. 3.14QACh. 3 - Prob. 3.15QACh. 3 - Prob. 3.16QACh. 3 - Prob. 3.17QACh. 3 - Prob. 3.18QACh. 3 - Prob. 3.19QACh. 3 - Prob. 3.20QACh. 3 - Prob. 3.21QACh. 3 - Prob. 3.22QACh. 3 - Prob. 3.23QACh. 3 - Prob. 3.24QACh. 3 - Prob. 3.25QACh. 3 - Prob. 3.26QACh. 3 - Prob. 3.27QACh. 3 - Prob. 3.28QACh. 3 - Prob. 3.29QACh. 3 - Prob. 3.30QACh. 3 - Prob. 3.31QACh. 3 - Prob. 3.32QACh. 3 - Prob. 3.33QACh. 3 - Prob. 3.34QACh. 3 - Prob. 3.35QACh. 3 - Prob. 3.36QACh. 3 - Prob. 3.37QACh. 3 - Prob. 3.38QACh. 3 - Prob. 3.39QACh. 3 - Prob. 3.40QACh. 3 - Prob. 3.41QACh. 3 - Prob. 3.42QACh. 3 - Prob. 3.43QACh. 3 - Prob. 3.44QACh. 3 - Prob. 3.45QACh. 3 - Prob. 3.46QACh. 3 - Prob. 3.47QACh. 3 - Prob. 3.48QACh. 3 - Prob. 3.49QACh. 3 - Prob. 3.50QACh. 3 - Prob. 3.51QACh. 3 - Prob. 3.52QACh. 3 - Prob. 3.53QACh. 3 - Prob. 3.54QACh. 3 - Prob. 3.55QACh. 3 - Prob. 3.56QACh. 3 - Prob. 3.57QACh. 3 - Prob. 3.58QACh. 3 - Prob. 3.59QACh. 3 - Prob. 3.60QACh. 3 - Prob. 3.61QACh. 3 - Prob. 3.62QACh. 3 - Prob. 3.63QACh. 3 - Prob. 3.64QACh. 3 - Prob. 3.65QACh. 3 - Prob. 3.66QACh. 3 - Prob. 3.67QACh. 3 - Prob. 3.68QACh. 3 - Prob. 3.69QACh. 3 - Prob. 3.70QACh. 3 - Prob. 3.71QACh. 3 - Prob. 3.72QACh. 3 - Prob. 3.73QACh. 3 - Prob. 3.74QACh. 3 - Prob. 3.75QACh. 3 - Prob. 3.76QACh. 3 - Prob. 3.77QACh. 3 - Prob. 3.78QACh. 3 - Prob. 3.79QACh. 3 - Prob. 3.80QACh. 3 - Prob. 3.81QACh. 3 - Prob. 3.82QACh. 3 - Prob. 3.83QACh. 3 - Prob. 3.84QACh. 3 - Prob. 3.85QACh. 3 - Prob. 3.86QACh. 3 - Prob. 3.87QACh. 3 - Prob. 3.88QACh. 3 - Prob. 3.89QACh. 3 - Prob. 3.90QACh. 3 - Prob. 3.91QACh. 3 - Prob. 3.92QACh. 3 - Prob. 3.93QACh. 3 - Prob. 3.94QACh. 3 - Prob. 3.95QACh. 3 - Prob. 3.96QACh. 3 - Prob. 3.97QACh. 3 - Prob. 3.98QACh. 3 - Prob. 3.99QACh. 3 - Prob. 3.100QACh. 3 - Prob. 3.101QACh. 3 - Prob. 3.102QACh. 3 - Prob. 3.103QACh. 3 - Prob. 3.104QACh. 3 - Prob. 3.105QACh. 3 - Prob. 3.106QACh. 3 - Prob. 3.107QACh. 3 - Prob. 3.108QACh. 3 - Prob. 3.109QACh. 3 - Prob. 3.110QACh. 3 - Prob. 3.111QACh. 3 - Prob. 3.112QACh. 3 - Prob. 3.113QACh. 3 - Prob. 3.114QACh. 3 - Prob. 3.115QACh. 3 - Prob. 3.116QACh. 3 - Prob. 3.117QACh. 3 - Prob. 3.118QACh. 3 - Prob. 3.119QACh. 3 - Prob. 3.120QACh. 3 - Prob. 3.121QACh. 3 - Prob. 3.122QACh. 3 - Prob. 3.123QACh. 3 - Prob. 3.124QACh. 3 - Prob. 3.125QACh. 3 - Prob. 3.126QACh. 3 - Prob. 3.127QACh. 3 - Prob. 3.128QACh. 3 - Prob. 3.129QACh. 3 - Prob. 3.130QACh. 3 - Prob. 3.131QACh. 3 - Prob. 3.132QACh. 3 - Prob. 3.133QACh. 3 - Prob. 3.134QA
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