A 0 .500-mol sample of an ideal gas has an initial temperature of 298 K . It is compressed from an initial volume of 13.00 L to 5.00 L by an external pressure of 2 .45 atm , at which point the internal and external pressures are equal. Calculate Δ S sys , Δ S surr , and Δ S univ for the process.
A 0 .500-mol sample of an ideal gas has an initial temperature of 298 K . It is compressed from an initial volume of 13.00 L to 5.00 L by an external pressure of 2 .45 atm , at which point the internal and external pressures are equal. Calculate Δ S sys , Δ S surr , and Δ S univ for the process.
Solution Summary: The author explains that the change in entropy of the system is given by the equation.
A
0
.500-mol
sample of an ideal gas has an initial temperature of
298
K
. It is compressed from an initial volume of
13.00
L
to
5.00
L
by an external pressure of
2
.45
atm
, at which point the internal and external pressures are equal. Calculate
Δ
S
sys
,
Δ
S
surr
,
and
Δ
S
univ
for the process.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 3 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY