EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
Question
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Chapter 3, Problem 3.14P

(a)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)+2.6(±0.1)]=?

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

  Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

  Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3, the uncertainty (e4) in addition and subtraction can be calculated as follows,

  e4=e12+e22+e32

Percent relative uncertainty:

  Percent relative uncertainty = 100 × relative uncertainty

(b)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)]÷2.6(±0.1)=?

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)×108]÷[2.6(±0.1)×103]=?.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)2.6(±0.1)]×3.4(±0.2)=?.

Concept Introduction: Refer part (a).

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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