ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 3, Problem 3.11P
Interpretation Introduction

(a)

Interpretation:

The nucleophile, the nucleophilic center, the electrophile, the electrophilic center, and the leaving group are to be stated for the given reaction, the analogous Brønsted acid-base reaction, the Brønsted acid and the Brønsted base of the final product and conjugate acid-base pairs for the given reaction are to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. They are also known as proton acceptor. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. They are also known as proton donor. Acid loses a proton and forms conjugate base. The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow. Bronsted acid-base reactions are those reactions in which electron pair displacement takes place and electrophilic center is a proton.

Interpretation Introduction

(b)

Interpretation:

The nucleophile, the nucleophilic center, the electrophile, the electrophilic center, and the leaving group are to be stated for the given reaction. The analogous Brønsted acid-base reaction. the Brønsted acid and the Brønsted base of the final product and conjugate acid-base pairs for the given reaction are to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. They are also known as proton acceptor. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. They are also known as proton donor. Acid loses a proton and forms conjugate base. The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow. Bronsted acid-base reactions are those reactions in which electron pair displacement takes place and electrophilic center is a proton.

Interpretation Introduction

(c)

Interpretation:

The nucleophile, the nucleophilic center, the electrophile, the electrophilic center, and the leaving group are to be stated for the given reaction. The analogous Brønsted acid-base reaction. the Brønsted acid and the Brønsted base of the final product and conjugate acid-base pairs for the given reaction are to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. They are also known as proton acceptor. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. They are also known as proton donor. Acid loses a proton and forms conjugate base. The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow. Bronsted acid-base reactions are those reactions in which electron pair displacement takes place and electrophilic center is a proton.

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== Vid4Q2 Unanswered ☑ Provide IUPAC name of product in the reaction below A 3,4-dimethylcyclohexene B 1,2-dimethylcyclohexane C 1,2-dimethylcyclohexene D 3,4-dimethylcyclohexane H₂ Pd
5. Use the MS data to answer the questions on the next page. 14.0 1.4 15.0 8.1 100- MS-IW-5644 26.0 2.8 27.0 6.7 28.0 1.8 29.0 80 4.4 38.0 1.0 39.0 1.5 41.0 1.2 42.0 11.2 43.0 100.0 44.0 4.3 79.0 1.9 80.0 2.6 Relative Intensity 40 81.0 1.9 82.0 2.5 93.0 8.7 20- 95.0 8.2 121.0 2.0 123.0 2.0 136.0 11.8 0 138.0 11.5 20 40 8. 60 a. Br - 0 80 100 120 140 160 180 200 220 m/z Identify the m/z of the base peak and molecular ion. 2 b. Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0, 95.0, 136.0, and 138.0 m/z. C. Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to fragment 43.0 m/z. Be sure to include all electrons and formal charges. 6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium ion (CsH6N) and show your work.
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