
Chemistry with Access Code, Hybrid Edition
9th Edition
ISBN: 9781285188492
Author: Steven S. Zumdahl
Publisher: CENGAGE L
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Chapter 3, Problem 2RQ
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Students have asked these similar questions
On the next page is an LC separation of the parabens found in baby wash. Parabens are
suspected in a link to breast cancer therefore an accurate way to quantitate them is desired.
a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for
all the terms in your calculation.
b. Is this a "good" value for a capacity factor? Explain.
c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly
what values you used in your calculation.
MAU
| Methyl paraben
40
20
0
-2
Ethyl paraben n-Propyl paraben
n-Butyl paraben
App ID 22925
6
8
min
d. In Figure 4, each stationary phase shows some negative correlation between plate count
and retention factor. In other words, as k' increases, N decreases. Explain this relationship
between k' and N.
Plate Count (N)
4000
3500
2500
2000
1500
1000
Figure 4. Column efficiency (N) vs retention factor (k') for 22
nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000
Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain
k' less than 15, which was achieved for most solutes as follows: FMS
(30/70 A/W), PGC (60/40), COZ (80/20). Slightly different
compositions were used for the most highly retained solutes. All
columns were 50 mm × 4.6 mm id and packed with 5 um particles,
except for COZ, which was packed with 3 um particles. All other
chromatographic conditions were constant: column length 5 cm,
column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C,
and injection volume 0.5 μL
Log(k'x/K'ethylbenzene)
FMS
1.5
1.0
0.5
0.0
ཐྭ ཋ ཤྩ བྷྲ ;
500
0
5
10…
f. Predict how the van Deemter curve in Figure 7
would change if the temperature were raised
from 40 °C to 55 °C.
Figure 7. van Desmter curves in reduced coordinates for four
nitroalkane homologues (nitropropane, black; nitrobutane, red;
nitropentane, blue; and nitrohexane, green) separated on the FMS
phase. Chromatographic conditions: column dimensions 50 mm × 4.6
mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection
volume 0.5 and column temperature 40 °C. No corrections to the
plate heights have been made to account for extracolumn dispersion.
Reduced Plate Height (h)
°
20
40
60
Reduced Velocity (v)
8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and
standard are spiked with a fixed amount of toluene as an internal standard. The following data are
obtained:
Ppb benzene
Peak area benzene
Peak area toluene
10.0
252
376
Sample
533
368
What is the concentration of benzene in the sample?
Chapter 3 Solutions
Chemistry with Access Code, Hybrid Edition
Ch. 3 - Prob. 1RQCh. 3 - Atomic masses are relative masses. What does this...Ch. 3 - The atomic mass of boron (B) is given in the...Ch. 3 - What three conversion factors and in what order...Ch. 3 - Fig. 5-5 illustrates a schematic diagram of a...Ch. 3 - What is the difference between the empirical and...Ch. 3 - Consider the hypothetical reaction between A2 and...Ch. 3 - Prob. 8RQCh. 3 - Consider the following mixture of SO2(g) and...Ch. 3 - Why is the actual yield of a reaction often less...
Ch. 3 - The following are actual student responses to the...Ch. 3 - What information do we get from a chemical...Ch. 3 - You are making cookies and are missing a key...Ch. 3 - Nitrogen gas (N2) and hydrogen gas (H2) react to...Ch. 3 - For the preceding question, which of the following...Ch. 3 - You know that chemical A reacts with chemical B....Ch. 3 - Prob. 7ALQCh. 3 - Consider an iron bar on a balance as shown. As the...Ch. 3 - You may have noticed that water sometimes drips...Ch. 3 - Prob. 10ALQCh. 3 - What is true about the chemical properties of the...Ch. 3 - Is there a difference between a homogeneous...Ch. 3 - Chlorine exists mainly as two isotopes, 37Cl and...Ch. 3 - The average mass of a carbon atom is 12.011....Ch. 3 - Can the subscripts in a chemical formula be...Ch. 3 - Consider the equation 2A + B . A2B. 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Cr(s) + S8(s) ...Ch. 3 - Silicon is produced for the chemical and...Ch. 3 - Glass is a mixture of several compounds, but a...Ch. 3 - Over the years, the thermite reaction has been...Ch. 3 - The reaction between potassium chlorate and red...Ch. 3 - The reusable booster rockets of the U.S. space...Ch. 3 - One of relatively few reactions that takes place...Ch. 3 - Elixirs such as Atka-Seltzer use the reaction of...Ch. 3 - Aspirin (C9H8O4) is synthesized by reacting...Ch. 3 - Bacterial digestion is an economical method of...Ch. 3 - Phosphorus can be prepared from calcium phosphate...Ch. 3 - Coke is an impure form of carbon that is often...Ch. 3 - The space shuttle environmental control system...Ch. 3 - Consider the reaction between NO(g) and O2(g)...Ch. 3 - Consider the following reaction:...Ch. 3 - Ammonia is produced from the reaction of nitrogen...Ch. 3 - Consider the following unbalanced equation:...Ch. 3 - Hydrogen peroxide is used as a cleansing agent in...Ch. 3 - Silver sulfadiazine bum-treating cream creates a...Ch. 3 - Hydrogen cyanide is produced industrially from the...Ch. 3 - Acrylonitrile C3H3N) is the starting material for...Ch. 3 - The reaction of ethane gas (C2H6) with chlorine...Ch. 3 - DDT, an insecticide harmful to fish, birds, and...Ch. 3 - Bornite (Cu3FeS3) is a copper ore used in the...Ch. 3 - Prob. 126ECh. 3 - In using a mass spectrometer, a chemist sees a...Ch. 3 - Boron consists of two isotopes, 10B and 11B....Ch. 3 - A given sample of a xenon fluoride compound...Ch. 3 - Aspartame is an artificial sweetener that is 160...Ch. 3 - Anabolic steroids are performance enhancement...Ch. 3 - Many cereals are made with high moisture content...Ch. 3 - The compound adrenaline contains 56.79% C, 6.56%...Ch. 3 - Adipic acid is an organic compound composed of...Ch. 3 - Vitamin B12, cyanocobalamin, is essential for...Ch. 3 - Some bismuth tablets, a medication used to treat...Ch. 3 - The empirical formula of styrene is CH; the molar...Ch. 3 - Terephthalic acid is an important chemical used in...Ch. 3 - A sample of a hydrocarbon (a compound consisting...Ch. 3 - A binary compound between an unknown element E and...Ch. 3 - A 0.755-g sample of hydrated copper(II) sulfate...Ch. 3 - ABS plastic is a tough, hard plastic used in...Ch. 3 - A sample of LSD (D-lysergic acid diethylamide,...Ch. 3 - Methane (CH4) is the main component of marsh gas....Ch. 3 - A potential fuel for rockets is a combination of...Ch. 3 - A 0.4230-g sample of impure sodium nitrate was...Ch. 3 - Prob. 147AECh. 3 - Commercial brass, an alloy of Zn and Cu, reacts...Ch. 3 - Vitamin A has a molar mass of 286.4 g/mol and a...Ch. 3 - You have seven closed containers, each with equal...Ch. 3 - A substance X2Z has the composition (by mass) of...Ch. 3 - Consider samples of phosphine (PH3), water (H2O),...Ch. 3 - Calculate the number of moles for each compound in...Ch. 3 - Arrange the following substances in order of...Ch. 3 - Para-cresol, a substance used as a disinfectant...Ch. 3 - A compound with molar mass 180.1 g/mol has the...Ch. 3 - Prob. 157CWPCh. 3 - Consider the following unbalanced chemical...Ch. 3 - Sulfur dioxide gas reacts with sodium hydroxide to...Ch. 3 - Gallium arsenide, GaAs, has gained widespread use...Ch. 3 - Consider the following data for three binary...Ch. 3 - Natural rubidium has the average mass of 85.4678 u...Ch. 3 - A compound contains only carbon, hydrogen,...Ch. 3 - Nitric acid is produced commercially by the...Ch. 3 - When the supply of oxygen is limited, iron metal...Ch. 3 - A 9.780-g gaseous mixture contains ethane (C2H6)...Ch. 3 - Zinc and magnesium metal each reacts with...Ch. 3 - A gas contains a mixture of NH3(g) and N2H4(g),...Ch. 3 - Consider a gaseous binary compound with a molar...Ch. 3 - A 2.25-g sample of scandium metal is reacted with...Ch. 3 - Prob. 171CPCh. 3 - The aspirin substitute, acetaminophen (C8H9O2N),...Ch. 3 - An element X forms both a dichloride (XCl2) and a...Ch. 3 - When M2S3(s) is heated in air, it is converted to...Ch. 3 - When aluminum metal is heated with an element from...Ch. 3 - Consider a mixture of potassium chloride and...Ch. 3 - Ammonia reacts with O2 to form either NO(g) or...Ch. 3 - You take 1.00 g of an aspirin tablet (a compound...Ch. 3 - With the advent of techniques such as scanning...Ch. 3 - Tetrodotoxin is a toxic chemical found in fugu...Ch. 3 - An iortic compound MX3 is prepared according to...Ch. 3 - The compound As2I4 is synthesized by reaction of...Ch. 3 - A 2.077-g sample of an element, which has an...Ch. 3 - Consider the following balanced chemical equation:...
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