Introductory Chemistry: Foundation - Text (Looseleaf)
9th Edition
ISBN: 9781337399623
Author: ZUMDAHL
Publisher: Cengage
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Chapter 3, Problem 29QAP
Classify the following asmixturesorpure substances.
- the vegetable soup you had for lunch
- the fertilizer your dad spreads on the front lawn in the spring
- the salt you sprinkle on your French fries
- the hydrogen peroxide you cleaned a cut linger with
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 3 Solutions
Introductory Chemistry: Foundation - Text (Looseleaf)
Ch. 3.2 - Exercise 3.1 Which of the following are physical...Ch. 3.2 - Prob. 3.2SCCh. 3.4 - Exercise 3.3 Classify each of the following as a...Ch. 3.5 - The scanning tunneling microscope allows us to...Ch. 3 - When water boils, you can see bubbles rising to...Ch. 3 - If you place a glass rod over a burning candle,...Ch. 3 - The boiling of water is a physical change because...Ch. 3 - Is there a difference between a homogeneous...Ch. 3 - Sketch a magnified view (showing atoms and/or...Ch. 3 - Are all physical changes accompanied by chemical...
Ch. 3 - Why would a chemist find fault with the phrase...Ch. 3 - Are separations of mixtures physical or chemical...Ch. 3 - Explain the termselement, afoul, and compound....Ch. 3 - Mixtures can be classified as either homogeneous...Ch. 3 - Prob. 11ALQCh. 3 - Look at Table 2.8 in your text. How do the...Ch. 3 - Label of the following as an atomic element, a...Ch. 3 - Match each description below with the following...Ch. 3 - Prob. 1QAPCh. 3 - What is the chief factor that determines...Ch. 3 - Of the three stales of matter, and are not very...Ch. 3 - has a definite volume hut takes the shape of its...Ch. 3 - Compare and contrast the ease with which molecules...Ch. 3 - Matter in the __________ state has no shape and...Ch. 3 - What similarities are there between the solid and...Ch. 3 - A sample of matter that is “rigid” has...Ch. 3 - Consider three 10-g samples of water: one as ice,...Ch. 3 - ¡n a sample of a gaseous substance, more than 99%...Ch. 3 - Elemental bromine is a dense, dark-red,...Ch. 3 - Is the process represented below a physical or...Ch. 3 - From the information given above, indicate...Ch. 3 - Prob. 14QAPCh. 3 - You want to cook some raw noodles to make a pasta...Ch. 3 - Which of the following is/are examples of a...Ch. 3 - Classify each of the following as a physical or...Ch. 3 - Classify each of the following as aphysical or...Ch. 3 - Prob. 19QAPCh. 3 - What is acompound? What are compounds composed of?...Ch. 3 - Certain elements have special affinities for other...Ch. 3 - _________ can he broken down into the component...Ch. 3 - The composition of a given pure compound is always...Ch. 3 - Which of the following are considered compounds...Ch. 3 - If iron filings are placed with excess powdered...Ch. 3 - If the combination of iron filings and sulfur in...Ch. 3 - Prob. 27QAPCh. 3 - Which of the following substances is(are)...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following mixtures...Ch. 3 - Read the “Chemistry in Focus” segmentConcrete—An...Ch. 3 - Prob. 33QAPCh. 3 - Describe how the process offiltrationcould be used...Ch. 3 - In a common laboratory experiment in general...Ch. 3 - During a filtration or distillation experiment, we...Ch. 3 - Prob. 37APCh. 3 - Classify each of the following as a(n) element,...Ch. 3 - 1f a piece of hard, white blackboard chalk is...Ch. 3 - During a very cold winter, the temperature may...Ch. 3 - Prob. 41APCh. 3 - True or false? Salad dressing (such as oil and...Ch. 3 - Prob. 43APCh. 3 - Which of (he following are true? P4 is considered...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - The processes of melting and evaporation involve...Ch. 3 - A(n) always has the same composition.Ch. 3 - Classify each of the following as...Ch. 3 - Which of the following contains an element, a...Ch. 3 - Classify the following mixtures...Ch. 3 - Which of the following best describes the air...Ch. 3 - Give three examples each ofheterogeneousmixtures...Ch. 3 - True or false? Mixtures always result in a...Ch. 3 - Choose an element or compound with which you are...Ch. 3 - Prob. 56APCh. 3 - Give an example of each of the following: a...Ch. 3 - Prob. 58APCh. 3 - Sketch the apparatus commonly used for simple...Ch. 3 - Prob. 60APCh. 3 - Which of the following best describes the...Ch. 3 - Prob. 62CPCh. 3 - Which of the following describes a chemical...Ch. 3 - Prob. 64CPCh. 3 - Prob. 1CRCh. 3 - Prob. 2CRCh. 3 - You have learned the basic way in which scientists...Ch. 3 - Many college students would not choose to take a...Ch. 3 - Prob. 5CRCh. 3 - Prob. 6CRCh. 3 - Prob. 7CRCh. 3 - Prob. 8CRCh. 3 - Prob. 9CRCh. 3 - What ismatter? What is matter composed of? What...Ch. 3 - Prob. 11CRCh. 3 - Prob. 12CRCh. 3 - Prob. 13CRCh. 3 - Prob. 14CRCh. 3 - Prob. 15CRCh. 3 - Prob. 16CRCh. 3 - Prob. 17CRCh. 3 - a. Given that 1100. mL of ethyl alcohol weighs...Ch. 3 - Which of the following represent physical...
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