Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337671323
Author: ZUMDAHL
Publisher: Cengage
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Chapter 3, Problem 1QAP
Interpretation Introduction
Interpretation:
The two characteristic properties of matter should be determined.
Concept Introduction:
Anything that has mass, volume and occupies space is known as matter. There are three
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 3 Solutions
Introductory Chemistry: A Foundation
Ch. 3.2 - Exercise 3.1 Which of the following are physical...Ch. 3.2 - Prob. 3.2SCCh. 3.4 - Exercise 3.3 Classify each of the following as a...Ch. 3.5 - The scanning tunneling microscope allows us to...Ch. 3 - When water boils, you can see bubbles rising to...Ch. 3 - If you place a glass rod over a burning candle,...Ch. 3 - The boiling of water is a physical change because...Ch. 3 - Is there a difference between a homogeneous...Ch. 3 - Sketch a magnified view (showing atoms and/or...Ch. 3 - Are all physical changes accompanied by chemical...
Ch. 3 - Why would a chemist find fault with the phrase...Ch. 3 - Are separations of mixtures physical or chemical...Ch. 3 - Explain the termselement, afoul, and compound....Ch. 3 - Mixtures can be classified as either homogeneous...Ch. 3 - Prob. 11ALQCh. 3 - Look at Table 2.8 in your text. How do the...Ch. 3 - Label of the following as an atomic element, a...Ch. 3 - Match each description below with the following...Ch. 3 - Prob. 1QAPCh. 3 - What is the chief factor that determines...Ch. 3 - Of the three stales of matter, and are not very...Ch. 3 - has a definite volume hut takes the shape of its...Ch. 3 - Compare and contrast the ease with which molecules...Ch. 3 - Matter in the __________ state has no shape and...Ch. 3 - What similarities are there between the solid and...Ch. 3 - A sample of matter that is “rigid” has...Ch. 3 - Consider three 10-g samples of water: one as ice,...Ch. 3 - ¡n a sample of a gaseous substance, more than 99%...Ch. 3 - Elemental bromine is a dense, dark-red,...Ch. 3 - Is the process represented below a physical or...Ch. 3 - From the information given above, indicate...Ch. 3 - Prob. 14QAPCh. 3 - You want to cook some raw noodles to make a pasta...Ch. 3 - Which of the following is/are examples of a...Ch. 3 - Classify each of the following as a physical or...Ch. 3 - Classify each of the following as aphysical or...Ch. 3 - Prob. 19QAPCh. 3 - What is acompound? What are compounds composed of?...Ch. 3 - Certain elements have special affinities for other...Ch. 3 - _________ can he broken down into the component...Ch. 3 - The composition of a given pure compound is always...Ch. 3 - Which of the following are considered compounds...Ch. 3 - If iron filings are placed with excess powdered...Ch. 3 - If the combination of iron filings and sulfur in...Ch. 3 - Prob. 27QAPCh. 3 - Which of the following substances is(are)...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following mixtures...Ch. 3 - Read the “Chemistry in Focus” segmentConcrete—An...Ch. 3 - Prob. 33QAPCh. 3 - Describe how the process offiltrationcould be used...Ch. 3 - In a common laboratory experiment in general...Ch. 3 - During a filtration or distillation experiment, we...Ch. 3 - Prob. 37APCh. 3 - Classify each of the following as a(n) element,...Ch. 3 - 1f a piece of hard, white blackboard chalk is...Ch. 3 - During a very cold winter, the temperature may...Ch. 3 - Prob. 41APCh. 3 - True or false? Salad dressing (such as oil and...Ch. 3 - Prob. 43APCh. 3 - Which of (he following are true? P4 is considered...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - The processes of melting and evaporation involve...Ch. 3 - A(n) always has the same composition.Ch. 3 - Classify each of the following as...Ch. 3 - Which of the following contains an element, a...Ch. 3 - Classify the following mixtures...Ch. 3 - Which of the following best describes the air...Ch. 3 - Give three examples each ofheterogeneousmixtures...Ch. 3 - True or false? Mixtures always result in a...Ch. 3 - Choose an element or compound with which you are...Ch. 3 - Prob. 56APCh. 3 - Give an example of each of the following: a...Ch. 3 - Prob. 58APCh. 3 - Sketch the apparatus commonly used for simple...Ch. 3 - Prob. 60APCh. 3 - Which of the following best describes the...Ch. 3 - Prob. 62CPCh. 3 - Which of the following describes a chemical...Ch. 3 - Prob. 64CPCh. 3 - Prob. 1CRCh. 3 - Prob. 2CRCh. 3 - You have learned the basic way in which scientists...Ch. 3 - Many college students would not choose to take a...Ch. 3 - Prob. 5CRCh. 3 - Prob. 6CRCh. 3 - Prob. 7CRCh. 3 - Prob. 8CRCh. 3 - Prob. 9CRCh. 3 - What ismatter? What is matter composed of? What...Ch. 3 - Prob. 11CRCh. 3 - Prob. 12CRCh. 3 - Prob. 13CRCh. 3 - Prob. 14CRCh. 3 - Prob. 15CRCh. 3 - Prob. 16CRCh. 3 - Prob. 17CRCh. 3 - a. Given that 1100. mL of ethyl alcohol weighs...Ch. 3 - Which of the following represent physical...
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