Bundle: Chemistry In Focus: A Molecular View Of Our World, 7th + Owlv2 With Mindtap Reader, 1 Term (6 Months) Printed Access Card
7th Edition
ISBN: 9781337812221
Author: Nivaldo J. Tro
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 1E
Why is it important to understand atoms?
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 3 Solutions
Bundle: Chemistry In Focus: A Molecular View Of Our World, 7th + Owlv2 With Mindtap Reader, 1 Term (6 Months) Printed Access Card
Ch. 3 - Determining the Number of Protons and Electrons in...Ch. 3 - Prob. 3.2YTCh. 3 - Determining Protons, Neutrons, and Electrons How...Ch. 3 - Calculating Atomic Mass Magnesium has three...Ch. 3 - The Mole Concept A diamond, which is pure carbon,...Ch. 3 - The Mole Concept II Calculate the number of atoms...Ch. 3 - Your friend tells you about an article that he...Ch. 3 - Prob. 2SCCh. 3 - Prob. 3SCCh. 3 - Copper is composed of two naturally occurring...
Ch. 3 - Prob. 5SCCh. 3 - Which pair of elements do you expect to be most...Ch. 3 - Which statement is true of the quantum mechanical...Ch. 3 - Why is it important to understand atoms?Ch. 3 - Prob. 2ECh. 3 - What defines an element? How many naturally...Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Explain the quantum mechanical model for the atom....Ch. 3 - Give two examples of each: a. alkali metal b....Ch. 3 - Which elements exist as diatomic molecules?Ch. 3 - Explain the difference and similarity between...Ch. 3 - Prob. 15ECh. 3 - Determine the charge of each of the following: a...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Give the atomic number (Z) and the mass number (A)...Ch. 3 - Prob. 20ECh. 3 - The following isotopes have applications in...Ch. 3 - The following isotopes are important in nuclear...Ch. 3 - 14C is used in carbon dating of artifacts....Ch. 3 - 40K is used to measure the age of Earth. Determine...Ch. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Give electron configurations according to the Bohr...Ch. 3 - Give electron configurations according to the Bohr...Ch. 3 - Prob. 29ECh. 3 - How many valence electrons are in each element of...Ch. 3 - Prob. 31ECh. 3 - Draw electron configurations for each of the...Ch. 3 - Which two of the following elements would you...Ch. 3 - Group the following elements into three similar...Ch. 3 - We have seen that the reactivity of an element is...Ch. 3 - What is the electron configuration of Mg2+? How...Ch. 3 - Classify each of the following elements as a...Ch. 3 - Classify each of the following as a metal, a...Ch. 3 - Calculate the atomic mass of neon (Ne), which is...Ch. 3 - An element has two naturally occurring isotopes....Ch. 3 - A fictitious element has two naturally occurring...Ch. 3 - Copper has two naturally occurring isotopes. Cu-63...Ch. 3 - How many moles of titanium are present in 124 g of...Ch. 3 - Prob. 44ECh. 3 - How many moles are there in each sample? a. 45 mg...Ch. 3 - How many moles are there in each sample? a. 55.0 g...Ch. 3 - What is the mass of each sample? a.1.8 mol S...Ch. 3 - What is the mass of each sample? a.2.75 mol Fe...Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - How many Ag atoms are present in a piece of pure...Ch. 3 - How many platinum atoms are in a pure platinum...Ch. 3 - A pure gold necklace has a volume of 1.8cm3. How...Ch. 3 - A titanium bicycle component has a volume of...Ch. 3 - An iron sphere has a radius of 3.4 cm. How many...Ch. 3 - Calculate the number of atoms in the universe. The...Ch. 3 - The introduction to this chapter states that...Ch. 3 - Suppose the absolute value of the charge of the...Ch. 3 - When we refer to doughnuts or cookies, we often...Ch. 3 - Prob. 60ECh. 3 - Why does Avogadros number have such an odd value?...Ch. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Here are three fictitious elements and a molecular...Ch. 3 - Prob. 66ECh. 3 - Gather any two of the following items, measure...
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