Chemical Principles in the Laboratory
Chemical Principles in the Laboratory
11th Edition
ISBN: 9781305264434
Author: Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher: Brooks Cole
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Chapter 3, Problem 1ASA

Using Figure 3.1, determine

a. the number of grams of CuSO 4 5H 2 O that will dissolve in 100  g of H 2 O at 100 ° C .

_ _ _ _ _ _ _ _ _   g CuSO 4 5H 2 O

b. the number of grams of water required to dissolve 4. 0 g of CuSO 4 5H 2 O at 100 ° C . (Hint: your answer to Problem 1(a) gives you the needed conversion factor for g CuSO 4 5H 2 O to g H 2 O .)

_ _ _ _ _ _ _ _ _   g H 2 O

c. the number of grams of water required to dissolve 18 g KNO 3 at 100 ° C .

_ _ _ _ _ _ _ _ _   g H 2 O

d. the number of grams of water required to dissolve a mixture containing 18 g KNO 3 and 4. 0 g CuSO 4 5H 2 O , assuming that the solubility of one substance is not affected by the presence of another.

_ _ _ _ _ _ _ _ _   g H 2 O

Expert Solution
Check Mark
Interpretation Introduction

(a)

Interpretation:

The number of grams of CuSO45H2O that dissolves in 100 g of H2O at 100°C is to be stated.

Concept introduction:

Solution is a homogenous mixture of two or more components. A sample taken from any part of the solution will have the same composition as the rest of the solution. Many chemical reactions occur in water solutions.

Answer to Problem 1ASA

The number of grams of CuSO45H2O that dissolves in 100 g of H2O at 100°C is about 180g.

Explanation of Solution

The given illustration of the graph is shown below.

Chemical Principles in the Laboratory, Chapter 3, Problem 1ASA , additional homework tip  1

Figure 1

According to the above graph, the number of grams of CuSO45H2O that dissolves in 100 g of H2O at 100°C is about 180g.

Conclusion

The number of grams of CuSO45H2O that dissolves in 100 g of H2O at 100°C is about 180g.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation:

The number of grams of water required to dissolve 4.0 g of CuSO45H2O at 100°C is to be stated.

Concept introduction:

Solution is a homogenous mixture of two or more components. A sample taken from any part of the solution will have the same composition as the rest of the solution. Many chemical reactions occur in water solutions.

Answer to Problem 1ASA

The number of grams of water required to dissolve 4.0 g of CuSO45H2O at 100°C is 2.2gH2O.

Explanation of Solution

The given illustration of the graph is shown below.

Chemical Principles in the Laboratory, Chapter 3, Problem 1ASA , additional homework tip  2

Figure 1

According to the above graph, the number of grams of CuSO45H2O that dissolves in 100 g of H2O at 100°C is about 200g. So, to dissolve 1g of CuSO45H2O in 100 g of H2O, the expression required is 1.0 g×100gH2O180gCuSO4.

Thus, water required to dissolve 4.0 g of CuSO45H2O is 4.0 g×100gH2O180gCuSO4=2.2gH2O.

Conclusion

The number of grams of water required to dissolve 4.0 g of CuSO45H2O at 100°C is 2.2gH2O.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation:

The number of grams of water required to dissolve 18 g KNO3 at 100°C is to be stated.

Concept introduction:

Solution is a homogenous mixture of two or more components. A sample taken from any part of the solution will have the same composition as the rest of the solution. Many chemical reactions occur in water solutions.

Answer to Problem 1ASA

The number of grams of water required to dissolve 18 g KNO3 at 100°C is 6.67gH2O.

Explanation of Solution

The given illustration of the graph is shown below.

Chemical Principles in the Laboratory, Chapter 3, Problem 1ASA , additional homework tip  3

Figure 1

According to the above graph, the number of grams of KNO3 that dissolves in 100 g of H2O at 100°C is about 270g. So, to dissolve 1g of KNO3 in 100 g of H2O, the expression required is 1.0 g×100gH2O270gKNO3.

Thus, the water required to dissolve 18.0 g of KNO3 is 18.0 g×100gH2O270gKNO3=6.67gH2O.

Conclusion

The number of grams of water required to dissolve 18 g KNO3 at 100°C is 6.67gH2O.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation:

The number of grams of water required to dissolve a mixture containing 18 g KNO3 and 4.0 g CuSO45H2O is to be stated.

Concept introduction:

Solution is a homogenous mixture of two or more components. A sample taken from any part of the solution will have the same composition as the rest of the solution. Many chemical reactions occur in water solutions.

Answer to Problem 1ASA

The number of grams of water required to dissolve a mixture containing 18 g KNO3 and 4.0 g CuSO45H2O is 8.87g.

Explanation of Solution

The given illustration of the graph is shown below.

Chemical Principles in the Laboratory, Chapter 3, Problem 1ASA , additional homework tip  4

Figure 1

The amount of water required to dissolve 18.0 g of KNO3 is 6.67gH2O.

The amount of water required to dissolve 4.0 g of CuSO45H2O is 2.2gH2O.

Therefore, the total amount of water required to dissolve a mixture containing 18 g KNO3 and 4.0 g CuSO45H2O is 6.67g+2.2g=8.87g

Conclusion

The number of grams of water required to dissolve a mixture containing 18 g KNO3 and 4.0 g CuSO45H2O is 8.87g.

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If the 3.21 g of NH4NO3 in the given problem were dissolved in 100.0 g of water under the same conditions, how much would the temperature change? Explain your answer.

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Chemical Principles in the Laboratory

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