Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
3rd Edition
ISBN: 9780321806383
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 3, Problem 107E
(a)
Interpretation Introduction
To balance: The given chemical equation.
(b)
Interpretation Introduction
To balance: The given chemical equation.
(c)
Interpretation Introduction
To balance: The given chemical equation.
(d)
Interpretation Introduction
To balance: The given chemical equation.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 3 Solutions
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
Ch. 3 - What is the empirical formula of a compound with...Ch. 3 - Prob. 2SAQCh. 3 - Prob. 3SAQCh. 3 - Prob. 4SAQCh. 3 - Prob. 5SAQCh. 3 - Prob. 6SAQCh. 3 - Q7. Name the compound .
a) phosphorus iodide b)...Ch. 3 - Prob. 8SAQCh. 3 - Prob. 9SAQCh. 3 - Prob. 10SAQ
Ch. 3 - Q11. Determine the mass of potassium in 35.5 g of...Ch. 3 - Prob. 12SAQCh. 3 - Prob. 13SAQCh. 3 - Prob. 14SAQCh. 3 - Prob. 15SAQCh. 3 - Prob. 1ECh. 3 - Prob. 2ECh. 3 - Prob. 3ECh. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Prob. 11ECh. 3 - Prob. 12ECh. 3 - Prob. 13ECh. 3 - Prob. 14ECh. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - Prob. 21ECh. 3 - 22. Write a generic formula for each of the...Ch. 3 - 23. Determine the number of each type of atom in...Ch. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - 26. Write a chemical formula for each molecular...Ch. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - 29. Classify each compound as ionic or...Ch. 3 - 30. Classify each compound as ionic or...Ch. 3 - 31. Based on the molecular views, classify each...Ch. 3 - 32. Based on the molecular views, classify each...Ch. 3 - 33. Write a formula for the ionic compound that...Ch. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - Prob. 37ECh. 3 - 38. Name each ionic compound.
a. SnCl4
b. PbI2
c....Ch. 3 - 39. Give each ionic compound an appropriate...Ch. 3 - 40. Give each ionic compound an appropriate...Ch. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - Prob. 43ECh. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Prob. 46ECh. 3 - Prob. 47ECh. 3 - 48. Name each molecular compound.
a. SO3
b. SO2
c....Ch. 3 - Prob. 49ECh. 3 - 50. Write the formula for each molecular...Ch. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - 54. Write the formula for each acid.
a. phosphoric...Ch. 3 - Prob. 55ECh. 3 - Use the nomenclature flowchart (Figure 3.10) to...Ch. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - 59. Calculate the formula mass for each...Ch. 3 - Prob. 60ECh. 3 - 61. Calculate the number of moles in each...Ch. 3 - 62. Calculate the mass of each sample.
a. 15.7 mol...Ch. 3 - 63. Determine the number of moles (of molecules or...Ch. 3 - Prob. 64ECh. 3 - Prob. 65ECh. 3 - Prob. 66ECh. 3 - 67. Calculate the mass (in g) of each sample.
a....Ch. 3 - Prob. 68ECh. 3 - 69. A sugar crystal contains approximately 1.8 ×...Ch. 3 - Prob. 70ECh. 3 - 71. Calculate the mass percent composition of...Ch. 3 - Prob. 72ECh. 3 - 73. Most fertilizers consist of...Ch. 3 - 74. Iron in the earth is in the form of iron ore....Ch. 3 - 75. Copper(II) fluoride contains 37.42% F by mass....Ch. 3 - Prob. 76ECh. 3 - 77. The iodide ion is a dietary mineral essential...Ch. 3 - 78. The American Dental Association recommends...Ch. 3 - 79. Write a ratio showing the relationship between...Ch. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - 84. Calculate the mass (in kilograms) of chlorine...Ch. 3 - 87. A chemist decomposes samples of several...Ch. 3 - 88. A chemist decomposes samples of several...Ch. 3 - 89. Calculate the empirical formula for each...Ch. 3 - 90. Calculate the empirical formula for each...Ch. 3 - 91. The elemental mass percent composition of...Ch. 3 - 92. The elemental mass percent composition of...Ch. 3 - 93. A 0.77-mg sample of nitrogen reacts with...Ch. 3 - 94. A 45.2-mg sample of phosphorus reacts with...Ch. 3 - The empirical formula and molar mass of several...Ch. 3 - 96. From the given molar mass and empirical...Ch. 3 - 97. Combustion analysis of a hydrocarbon produces...Ch. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - 100. Tartaric acid is the white, powdery substance...Ch. 3 - Prob. 99ECh. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - 104. When iron rusts, solid iron reacts with...Ch. 3 - Prob. 103ECh. 3 - Prob. 104ECh. 3 - Prob. 105ECh. 3 - 108. Write the balanced chemical equation for each...Ch. 3 - Prob. 107ECh. 3 - Prob. 108ECh. 3 - 111. Balance each chemical equation.
a. CO2(g) +...Ch. 3 - 112. Balance each chemical equation.
a. Na2S(aq) +...Ch. 3 - Prob. 111ECh. 3 - Prob. 112ECh. 3 - Prob. 113ECh. 3 - Prob. 114ECh. 3 - Prob. 115ECh. 3 - Prob. 116ECh. 3 - Prob. 117ECh. 3 - Prob. 118ECh. 3 - 121. How many molecules of ethanol (C2H5OH) (the...Ch. 3 - 122. A drop of water has a volume of approximately...Ch. 3 - 123. Determine the chemical formula of each...Ch. 3 - 124. Determine the chemical formula of each...Ch. 3 - Prob. 123ECh. 3 - Prob. 124ECh. 3 - 127. A metal (M) forms a compound with the formula...Ch. 3 - Prob. 126ECh. 3 - 129. Estradiol is a female sexual hormone that is...Ch. 3 - 130. Fructose is a common sugar found in fruit....Ch. 3 - 131. Combustion analysis of a 13.42-g sample of...Ch. 3 - 132. Estrone, which contains only carbon,...Ch. 3 - 133. Epsom salts is a hydrated ionic compound with...Ch. 3 - 134. A hydrate of copper(II) chloride has the...Ch. 3 - Prob. 133ECh. 3 - Prob. 134ECh. 3 - Prob. 135ECh. 3 - Prob. 136ECh. 3 - Prob. 137ECh. 3 - Prob. 138ECh. 3 - Prob. 139ECh. 3 - 142. A phosphorus compound that contains 34.00%...Ch. 3 - Prob. 141ECh. 3 - 144. Phosphorus is obtained primarily from ores...Ch. 3 - Prob. 143ECh. 3 - Prob. 144ECh. 3 - Prob. 145ECh. 3 - Prob. 146ECh. 3 - Prob. 147ECh. 3 - Prob. 148ECh. 3 - 151. Lead is found in Earth's crust as several...Ch. 3 - 152150. A 2.52-g sample of a compound containing...Ch. 3 - 153. A compound of molar mass 229 g/mol contains...Ch. 3 - Prob. 152ECh. 3 - Prob. 153ECh. 3 - Prob. 154ECh. 3 - 157. When molecules are represented by molecular...Ch. 3 - Prob. 156ECh. 3 - Prob. 157ECh. 3 - Prob. 158ECh. 3 - 161. Without doing any calculations, arrange the...Ch. 3 - Q60. Element A is an atomic element, and element...
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