(a)
Interpretation: A skeletal structure of the anabolic steroid
Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as
(b)
Interpretation: The addition of all wedges and dashed wedges for all stereogenic centers to steroid
Concept introduction: Steroids, a group of tetracyclic lipids composed of one five-membered ring and three six-membered rings. These rings are lettered by A, B, C, and D. Most of the steroids contain two angular methyl groups. These methyl groups are numbered as
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ORGANIC CHEM W/BIOLOGICAL TOP. ACCESS
- (4) Write the structure of the following compounds from their IUPAC names. (a) ethanamide (b) methylethanoate (c) propanoic acid (d) 2-butanone (5) Write the structure of the following ethers and amines from their common names (a) methyl propyl (b) trimethylamine (6) Decide whether the following alcohols are polar or nonpolar (a) CH3CH2CH2CH2CH2CH2CH2OH (b) CH3CH2OHarrow_forwardDraw structures corresponding to the following IUPAC names: (a) cis-1,2-Cyclohexanedicarboxylic acid (b) Heptanedioic acid (c) 2-Hexen-4-ynoic acidarrow_forwardDraw the structural formulas for the following compounds. Include all the bonds to hydrogen atoms. Be sure to answer both parts. (a) 1,2,4-trimethylbenzene: (b) chlorobenzene:arrow_forward
- (1) Draw the LINE-ANGLE structure of 2, 2-diiodopentane. (2) Convert this achiral compound to one chiral compound by simply changing the position of 2 atoms (or groups) in the structure.arrow_forwardThe structural formula for the open-chain form of galactose is CH Н—ҫ—ОН Но—С—н НО—С—Н Н—ҫ—ОН CH-ОН (a) Is this molecule a sugar? (b) How many chiral carbons are present in the molecule? (C) Draw the structure of the six-member-ring form of this molecule.arrow_forwardThe melting points and boiling points of two isomeric alkanes are as follows: CH3(CH2)6CH3, mp = -57 °C and bp = 126 °C; (CH3)3CC(CH3)3, mp = 102 °C and bp = 106 °C. (a) Explain why one isomer has a lower melting point but higher boiling point. (b) Explain why there is a small difference in the boiling points of the two compounds, but a huge difference in their melting points.arrow_forward
- Q1Carrow_forwardwhat is the structure of hexane / ethyl acetate 1: 1?arrow_forwardAcetyl chloride, CH3COCl, reacts with the hydroxyl groupsof alcohols to form ester groups with the elimination ofHCl. When an unknown compound X with formulaC4H8O3 reacted with acetyl chloride, a new compound Ywith formula C8H12O5 was formed.(a) How many hydroxyl groups were there in X?(b) Assume that X is an aldehyde. Write a possible structure for X and a possible structure for Y consistent with your structure for X.arrow_forward
- Palmitoleic acid, a fatty acid with various pharmaceutical applications, is mainly obtained from macadamia nuts. The condensed structural formula for a triacylglycerol containing three palmitoleic acid units is provided below. Which of the following statements is NOT true regarding this triacylglycerol? O || CH,−O−C–(CH,)–CH=CH—(CH2)5–CH3 O || CH−O−C−(CH2)–CH=CH–(CH,)5–CH3 O CH,−O−C−(CH,)–CH=CH–(CH,)5–CH, O Its name is glyceryl tripalmitate or tripalmitin. O It is most likely to be liquid at room temperature. O It is an oil (not a fat). O It contains 3 molecules of the same unsaturated fatty acid.arrow_forwardCortisone is a compound that is used as an anti-inflammatory drug to treat 2) diseases like arthritis. Cortisone is a steroid which contains four rings (A, B, C and D), and has the following structure: он "OH Cortisone Provide the data to complete each of the following statements: The total number of chiral carbons (stereocentres) in Cortisone is The maximum number of stereoisomers possible is: The degree of unsaturation (IHD) of Cortisone is The total number of 2° hydrogens is The ring fusion between rings B and C is trans or cis? The absolute configuration of the carbon with * in the structure is The total number of n bonds isarrow_forwardDraw the structures for the following compounds.(a) 3-benzyl-4-bromohexane , 4,4-dimethylcyclohexene(b) trans-4,5-dibromohex-2-ene , cis-1,1-dibromo-2-ethyl-2,3-dimethylcyclobutanearrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning