Physics: Principles with Applications
Physics: Principles with Applications
7th Edition
ISBN: 9780321625922
Author: Douglas C. Giancoli
Publisher: Addison-Wesley
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Chapter 29, Problem 45GP
To determine

The energy gap of the semiconductor.

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10. Imagine you have a system in which you have 54 grams of ice. You can melt this ice and then vaporize it all at 0 C. The melting and vaporization are done reversibly into a balloon held at a pressure of 0.250 bar. Here are some facts about water you may wish to know. The density of liquid water at 0 C is 1 g/cm³. The density of ice at 0 C is 0.917 g/cm³. The enthalpy of vaporization of liquid water is 2.496 kJ/gram and the enthalpy of fusion of solid water is 333.55 J/gram.
Consider 1 mole of supercooled water at -10°C. Calculate the entropy change of the water when the supercooled water freezes at -10°C and 1 atm. Useful data: Cp (ice) = 38 J mol-1 K-1 Cp (water) 75J mol −1 K -1 Afus H (0°C) 6026 J mol −1 Assume Cp (ice) and Cp (water) to be independent of temperature.
The molar enthalpy of vaporization of benzene at its normal boiling point (80.09°C) is 30.72 kJ/mol. Assuming that AvapH and AvapS stay constant at their values at 80.09°C, calculate the value of AvapG at 75.0°C, 80.09°C, and 85.0°C. Hint: Remember that the liquid and vapor phases will be in equilibrium at the normal boiling point.

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Physics: Principles with Applications

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