ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
3rd Edition
ISBN: 9781119477617
Author: Klein
Publisher: WILEY
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Chapter 27.6, Problem 20CC
Interpretation Introduction

Interpretation:

Which type of polyethylene is used to make Ziploc bags and folding tables.

Concept introduction:

When ethylene undergoes polymerization polyethylene is formed.  In absence of Ziegler-Natta catalyst ethylene polymerizes to give polyethylene that has about 20 branches per thousand carbon atoms.  This has relatively low density giving rise to low-density polyethylene (LDPE).  In presence of Ziegler-Natta catalyst ethylene polymerizes to give polyethylene that has about five branches per thousand carbon atoms.  This has relatively high density giving rise to high-density polyethylene (HDPE).  The density difference makes the polyethylene useful for making many materials.

To identify: To identify which polyethylene will be used to make Ziploc bags and folding tables.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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