EBK ORGANIC CHEMISTRY AS A SECOND LANGU
3rd Edition
ISBN: 9781118203774
Author: Klein
Publisher: YUZU
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Question
Chapter 27.4, Problem 8ATS
Interpretation Introduction
Interpretation:
Arrange the given monomers in order of reactivity toward anionic
Concept introduction:
Polymerization is a reaction when monomer molecules are reacted to form a
- Cationic polymerization
- Radical polymerization
- Anionic polymerization
Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups. In this method cationic initiator transfers charge to the monomer which becomes active and further propogates with another molecules.
Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups). In this polymerization carbanion is the active species.
Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.
To arrange: To arrange the given set of monomer in order of reactivity towards anionic polymerization
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Curved arrows are used to illustrate the flow of electrons. Using the provided
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the following reaction or mechanistic step(s).
Be sure to account for all bond-breaking and bond-making steps.
+
Drawing Arrows
CH3ONA, CH3OH
heat
: Br:O
Na →
H
H
Br
Na +
H
H
H
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:0:
.H
+
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What is the reaction mechanism for this?
20.19 Predict the structure of the major 1,2-addition product formed by reaction of one mole
of Cl₂ with 3-methylenecyclohexene. Also predict the structure of the 1,4-addition
product formed under these conditions.
20.20 Which of the two molecules shown do you expect to be the major product formed
by 1,2-addition of HCI to cyclopentadiene? Explain.
Cyclopentadiene
+ HC
3-Chlorocyclopentene
(racemic)
or
4-Chlorocyclopentene
(racemic)
Chapter 27 Solutions
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
Ch. 27.2 - Prob. 1CCCh. 27.2 - Prob. 2CCCh. 27.3 - Prob. 3CCCh. 27.3 - Prob. 4CCCh. 27.3 - Prob. 5CCCh. 27.4 - Prob. 1LTSCh. 27.4 - Prob. 6PTSCh. 27.4 - Prob. 7ATSCh. 27.4 - Prob. 8ATSCh. 27.4 - Prob. 9ATS
Ch. 27.4 - Prob. 10ATSCh. 27.4 - Prob. 11CCCh. 27.4 - Prob. 12CCCh. 27.4 - Prob. 2LTSCh. 27.4 - Prob. 13PTSCh. 27.4 - Prob. 14PTSCh. 27.4 - Prob. 15ATSCh. 27.4 - Prob. 16ATSCh. 27.5 - Prob. 17CCCh. 27.5 - Prob. 18CCCh. 27.6 - Prob. 19CCCh. 27.6 - Prob. 20CCCh. 27.8 - Prob. 21CCCh. 27 - Prob. 22PPCh. 27 - Prob. 23PPCh. 27 - Prob. 24PPCh. 27 - Prob. 25PPCh. 27 - Prob. 26PPCh. 27 - Prob. 27PPCh. 27 - Prob. 28PPCh. 27 - Prob. 29PPCh. 27 - Prob. 30PPCh. 27 - Prob. 31PPCh. 27 - Prob. 32PPCh. 27 - Prob. 33PPCh. 27 - Prob. 34PPCh. 27 - Prob. 35PPCh. 27 - Prob. 36PPCh. 27 - Prob. 37PPCh. 27 - Prob. 38PPCh. 27 - Prob. 39PPCh. 27 - Prob. 40PPCh. 27 - Prob. 41PPCh. 27 - Prob. 42PPCh. 27 - Prob. 43IPCh. 27 - Prob. 44IPCh. 27 - Prob. 45IPCh. 27 - Prob. 46IPCh. 27 - Prob. 47IPCh. 27 - Prob. 48IPCh. 27 - Prob. 49CPCh. 27 - Prob. 50CPCh. 27 - Prob. 51CP
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