ORGANIC CHEMISTRY-PRINT MULTI TERM
ORGANIC CHEMISTRY-PRINT MULTI TERM
4th Edition
ISBN: 9781119832614
Author: Klein
Publisher: WILEY
Question
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Chapter 27.4, Problem 6PTS

(a)

Interpretation Introduction

Interpretation:

The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain.  Polymerization can occur via three ways,

  • Cationic polymerization
  • Radical polymerization
  • Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups.  In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups).  In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To identify: whether the given polymer can be achieved best via cationic addition or anionic addition

(b)

Interpretation Introduction

Interpretation:

The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain.  Polymerization can occur via three ways,

  • Cationic polymerization
  • Radical polymerization
  • Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups.  In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups).  In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To identify: To identify whether the given polymer can be achieved best via cationic addition or anionic addition

(c)

Interpretation Introduction

Interpretation:

The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain.  Polymerization can occur via three ways,

  • Cationic polymerization
  • Radical polymerization
  • Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups.  In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups).  In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To identify: whether the given polymer can be achieved best via cationic addition or anionic addition

(d)

Interpretation Introduction

Interpretation:

The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain.  Polymerization can occur via three ways,

  • Cationic polymerization
  • Radical polymerization
  • Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups.  In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups).  In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To identify : whether the given polymer can be achieved best via cationic addition or anionic addition

(e)

Interpretation Introduction

Interpretation:

The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain.  Polymerization can occur via three ways,

  • Cationic polymerization
  • Radical polymerization
  • Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups.  In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups).  In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To identify: whether the given polymer can be achieved best via cationic addition or anionic addition

(f)

Interpretation Introduction

Interpretation:

The synthesis of given set of polymers can be achieved best via cationic addition or anionic addition should be determined.

Concept introduction:

Polymerization is a reaction when monomer molecules are reacted to form a polymer chain.  Polymerization can occur via three ways,

  • Cationic polymerization
  • Radical polymerization
  • Anionic polymerization

Cationic polymerization is the polymerization of the monomer (vinyl) with strong electron donating groups.  In this method cationic initiator transfers charge to the monomer which becomes active and further propagates with another molecules.

Anionic polymerization is the polymerization of the monomer (vinyl) with strong electron attracting groups (electronegative groups).  In this polymerization carbanion is the active species.

Radical polymerization is a type of polymerization where the reaction occurs by successive addition of free-radicals.

To identify : To identify whether the given polymer can be achieved best via cationic addition or anionic addition

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